Fungicidal compounds, method for the production thereof, and use thereof to combat damaging fungi, and agents comprising the same

ABSTRACT

Compounds of the formula I 
                         
in which the substituents have the meaning given in the description, processes for preparing these compounds, compositions comprising them and their use for controlling harmful fungi.

This application is a National Stage application of InternationalApplication No. PCT/EP2008/063519 filed Oct. 9, 2008, the entirecontents of which is hereby incorporated herein by reference. Thisapplication also claims the benefit under 35 U.S.C. §119 of EuropeanPatent Application No. 07119391.6, filed Oct. 26, 2007, the entirecontents of which is hereby incorporated herein by reference.

DESCRIPTION

The present invention relates to compounds of the formula I

in which the substituents have the following meaning:

-   R¹ is C₁-C₈-alkyl, C₂-C₈-alkenyl, C₂-C₈-alkynyl, C₃-C₈-cycloalkyl,    C₃-C₈-cycloalkenyl, phenyl or a three- to ten-membered saturated,    partially unsaturated or aromatic mono- or bicyclic heterocyclyl    which, in addition to carbon atoms, contains one to four heteroatoms    from the group consisting of O, N and S as ring members;-   R² is amino, C₁-C₈-alkyl, C₂-C₈-alkenyl, C₂-C₈-alkynyl,    C₁-C₈-alkoxy, C₃-C₈-cycloalkyl, C₃-C₈-cycloalkenyl, phenyl or a    three- to ten-membered saturated, partially unsaturated or aromatic    mono- or bicyclic heterocyclyl which, in addition to carbon atoms,    contains one to four heteroatoms from the group consisting of O, N    and S as ring members, where the groups R² may be attached directly    or via a carbonyl group;-   R³,R⁴ independently of one another are hydrogen, C₁-C₈-alkyl,    C₁-C₈-haloalkyl, C₁-C₈-alkylcarbonyl or C₁-C₈-alkoxycarbonyl;-   R⁵,R⁶ independently of one another are C₁-C₈-alkyl, C₁-C₈-haloalkyl,    C₁-C₄-alkoxy or C₃-C₈-cycloalkyl;-   R⁷ is hydrogen, C₁-C₈-alkyl, C₁-C₈-haloalkyl, C₁-C₄-alkoxy or    C₁-C₈-haloalkoxy; and aliphatic and cyclic groups R¹ to R⁶ may carry    one, two, three or up to the maximum possible number of identical or    different groups R^(a) which independently of one another are    selected from:    -   R^(a) is halogen, hydroxyl, oxo, nitro, cyano, carboxyl,        C₁-C₄-alkyl, C₂-C₄-alkenyl, C₂-C₄-alkynyl, C₁-C₄-haloalkyl,        C₁-C₄-alkoxy, C₁-C₄-haloalkoxy, C₃-C₆-cycloalkyl,        C₃-C₈-cycloalkenyl, C₂-C₆-alkenyloxy, C₃-C₆-alkynyloxy,        C₁-C₄-alkoxyimino, C₂-C₈-alkylidene, C₃-C₈-cycloalkylidene,        C₁-C₁₂-alkylamino, C₁-C₄-alkoxycarbonyl, C₁-C₄-alkylcarbonyloxy,        NR^(A)R^(B), C₂-C₈-alkylene, C₂-C₈-oxyalkylene,        C₁-C₈-oxyalkyleneoxy, phenyl, naphthyl or a three- to        ten-membered saturated, partially unsaturated or aromatic mono-        or bicyclic heterocyclyl which, in addition to carbon atoms,        contains one to four heteroatoms from the group consisting of O,        N and S as ring members; where the cyclic groups R^(a) may be        attached directly or via a nitrogen or oxygen atom;    -    where in the divalent groups R^(a) the carbon chains may be        interrupted by one to four heteroatoms from the group consisting        of O, N and S and the free valencies may be attached to the same        atom or to two adjacent atoms; where the aliphatic or cyclic        groups R^(a) for their part may be partially or fully        halogenated and/or may carry one, two, three or up to the        maximum possible number of identical or different groups R^(b):        -   R^(b) is halogen, hydroxyl, nitro, cyano, carboxyl,            C₁-C₄-alkyl, C₂-C₄-alkenyl, C₂-C₈-alkynyl, C₁-C₄-haloalkyl,            C₁-C₄-alkoxy, C₁-C₄-halo-alkoxy, C₁-C₈-alkylcarbonylamino,            phenyl, phenoxy, pyridyl, pyridyl-oxy or            C₃-C₈-cycloalkylcarbonylamino;        -    where the cyclic groups R^(b) for their part may be            partially or fully halogenated and/or may carry one, two,            three or up to the maximum possible number of identical or            different groups R^(c):        -    R^(c) is halogen, hydroxyl, nitro, cyano, carboxyl,            C₁-C₄-alkyl, C₂-C₄-alkenyl, C₂-C₈-alkynyl, C₁-C₄-haloalkyl,            C₁-C₄-alkoxy or C₁-C₄-haloalkoxy;        -   R^(A),R^(B) independently of one another are hydrogen,            C₁-C₈-alkyl, C₁-C₈-halo-alkyl or C₁-C₈-alkylcarbonyl;-   L¹,L²,L³,L⁴ independently of one another are hydrogen, halogen,    C₁-C₄-alkyl, C₁-C₄-haloalkyl, C₁-C₄-alkoxy or C₁-C₄-haloalkoxy;    where R¹ and R² or R¹ and R³ or R² and R³ or R³ and R⁴ and/or R⁵ and    R⁶ in each case together with the atoms linking them may form a    five- to ten-membered saturated or partially unsaturated cyclic    group which, in addition to the carbon atoms, may contain one to    three heteroatoms from the group consisting of N, O and S and/or may    be partially or fully halogenated and/or may carry one, two, three    or up to the maximum possible number of identical or different    groups R^(a);-   X is oxygen or sulfur;    and agriculturally acceptable salts of the compounds of the formula    I.

Moreover, the invention relates to processes for preparing thesecompounds, to compositions comprising them and to their use forcontrolling harmful fungi.

Phenylamidines are known in a general manner from WO 2000/046184.Further phenylamidines are disclosed in WO 2003/093224, WO 2007/031508,WO 2007/031512, WO 2007/031513, WO 2007/031523, WO 2007/031524, WO2007/031526. These compounds are known to be suitable for controllingharmful fungi.

In many cases, in particular at low application rates, the fungicidalactivity of the known compounds is unsatisfactory. Based on this fact,it is an object of the present invention to provide compounds havingimproved activity and/or a broader activity spectrum.

This object has been achieved by the compounds defined at the outset.Furthermore, we have found processes for their preparation, compositionscomprising them and methods for controlling harmful fungi using thecompounds I.

The compounds I according to the invention can be obtained by differentroutes. Advantageously, they are prepared by reacting compounds of theformula II in which Y represents a nucleophilically replaceable groupsuch as halogen, alkylsulfonyloxy and arylsulfonyloxy, preferablychlorine, bromine or iodine, particularly preferably chlorine, withappropriate O-substituted hydroxylamines of the formula III.

This reaction is usually carried out at from −20° C. to 150° C.,preferably at from 0° C. to 120° C., in an inert organic solvent. Withparticular preference, the reaction is carried out in a neutral orslightly acidic medium which, if appropriate, may be prepared byaddition of an acid or, if the salt of the hydroxylamine is used, byaddition of a base.

Suitable solvents are aliphatic hydrocarbons, aromatic hydrocarbons,ethers, such as diethyl ether, diisopropyl ether, tert-butyl methylether, dioxane, anisole and tetrahydrofuran, alcohols, such as methanol,ethanol, n-propanol, isopropanol, n-butanol and tert-butanol, and alsodimethyl sulfoxide, dimethylformamide and dimethylacetamide. Particularpreference is given to methanol, ethanol, propanol, tetrahydrofuran anddioxane. It is also possible to use mixtures of the solvents mentioned.

Suitable bases are, in general, inorganic compounds, such as alkalimetal and alkaline earth metal hydroxides, alkali metal and alkalineearth metal oxides, alkali metal and alkaline earth metal hydrides,alkali metal amides, alkali metal and alkaline earth metal carbonates,such as lithium carbonate, sodium carbonate, potassium carbonate andcalcium carbonate, and also alkali metal bicarbonates, alkali metal andalkaline earth metal alkoxides, moreover organic bases, for exampletertiary amines, such as trimethylamine, triethylamine, tributylamine,diisopropylethylamine and N-methylpiperidine, pyridine, substitutedpyridines, and also bicyclic amines. Particular preference is given tosodium carbonate, potassium carbonate, sodium bicarbonate, and also totertiary amines. The bases are generally employed in catalytic amounts;however, they can also be used in equimolar amounts, in excess or, ifappropriate, as solvents.

Suitable for use as acids and acidic catalysts are inorganic acids, suchas hydrochloric acid, hydrobromic acid, sulfuric acid and perchloricacid, and also organic acids, such as formic acid, acetic acid,propionic acid, oxalic acid, toluenesulfionic acid, benzenesulfonicacid, camphorsulfonic acid, citric acid and trifluoroacetic acid. Theacids are generally employed in catalytic amounts; however, they canalso be used in equimolar amounts, in excess or, if appropriate, assolvents.

The starting materials are generally reacted with one another inequimolar amounts. In terms of yield, it may be advantageous to use thehydroxylamine III in excess, based on the ketone II. This reaction mayalso be carried out in two steps by initially reacting hydroxylamine(formula III where R¹=hydrogen) or a salt thereof under the conditionsdescribed above. The product can then be alkylated to the compound IVusing a known process.

Under basic conditions, the compounds of the formula IV are condensedwith N-4-mercapto- or N-4-hydroxyphenylamidines of the formula V.

This reaction is usually carried out at from −40° C. to 150° C.,preferably from −20° C. to 120° C., in an inert organic solvent in thepresence of a base.

Suitable solvents are aliphatic hydrocarbons, aromatic hydrocarbons,such as toluene, o-, m- and p-xylene, halogenated hydrocarbons, ethers,such as diethyl ether, diisopropyl ether, tert-butyl methyl ether(MTBE), dioxane, anisole and tetrahydrofuran (THF), nitriles, such asacetonitrile and propionitrile, ketones, and also dimethyl sulfoxide(DMSO), dimethylformamide (DMF) and dimethylacetamide. Particularpreference is given to DMSO, DMF and dimethylacetamide, toluene, MTBE,dioxane, acetonitrile, propionitrile and THF. It is also possible to usemixtures of the solvents mentioned.

Suitable bases are, in general, inorganic compounds, such as alkalimetal and alkaline earth metal hydroxides, such as lithium hydroxide,sodium hydroxide, potassium hydroxide and calcium hydroxide, alkalimetal and alkaline earth metal oxides, alkali metal and alkaline earthmetal hydrides, such as lithium hydride, sodium hydride, potassiumhydride and calcium hydride, alkali metal amides, alkali metal andalkaline earth metal carbonates, such as lithium carbonate, sodiumcarbonate, potassium carbonate and calcium carbonate, and also alkalimetal bicarbonates, organometallic compounds, alkylmagnesium halides,and also alkali metal and alkaline earth metal alkoxides, such as sodiummethoxide, sodium ethoxide, potassium ethoxide, potassium tert-butoxideand dimethoxymagnesium, moreover organic bases, for example tertiaryamines, such as trimethylamine, triethylamine, tributylamine,diisopropylethylamine and N-methylpiperidine, pyridine, substitutedpyridines, such as collidine, lutidine and 4-dimethylaminopyridine, andalso bicyclic amines. Particular preference is given to sodiumhydroxide, potassium hydroxide, sodium hydride, potassium hydride,sodium carbonate, potassium carbonate, sodium methoxide, sodiumethoxide, potassium ethoxide, potassium tert-butoxide, and also totertiary amines. The bases are generally employed in equimolar amounts;however, they can also be used in excess or, if appropriate, as solvent.

The starting materials are generally reacted with one another inequimolar amounts.

Alternatively, compounds of the formula I in which R² is CH₂—R^(2a),where R^(2a) is a group R^(a) which is attached via oxygen, can beobtained by condensing compounds of the formula II.1 in which Y¹ and Y²independently of one another are a nucleophilically replaceable group,such as halogen, alkylsulfonyloxy and arylsulfonyloxy, preferablychlorine, bromine and iodine, particularly preferably chlorine, withO-substituted hydroxylamines of the formula III, preferably under theconditions described above for the reaction of compounds of the formulaII with compounds of the formula III.

If advantageous with a view to the total yield of the reactions, thisreaction can also be carried out in two steps by initially reactinghydroxylamine (where R¹ is hydrogen) or a salt thereof under theconditions described above. Using known processes, the product can thenbe alkylated to compound IV.1.

The compounds of the formula IV.I in which Y¹ and Y² are eachindependently of one another a nucleophilically replaceable group, suchas halogen, alkylsulfonyloxy and arylsulfonyloxy, preferably chlorine,bromine or iodine, particularly preferably chlorine, are reacted furtherunder basic conditions with compounds of the formula V. The resultingcompounds correspond to the formula VI.

This reaction is usually carried out at from −40° C. to 150° C.,preferably from −20° C. to 100° C., in an inert organic solvent in thepresence of a base, the other reaction conditions corresponding to thereaction of compounds of the formula IV with compounds of the formula V.

The starting materials are generally reacted with one another inequimolar amounts. In terms of yield, it may be advantageous to use anexcess of the compound IV.1, based on the compound V.

Under basic conditions, the compounds of the formula VI are reactedfurther with compounds of the formula VII, it being preferred to use theconditions described above for reacting compounds of the formula IV.1with compounds of the formula V. The resulting compounds correspond tothe formula I.1.

The starting materials are generally reacted with one another inequimolar amounts. In terms of yield, it may be advantageous to use anexcess of the compound VII, based on the compound VI.

The order of these synthesis steps may also be changed such thatinitially compounds of the formula IV.1 are reacted with compounds ofthe formula VII. By reacting the intermediate with compounds of theformula V, it is then possible to obtain compounds of the formula I.1.To this end, the conditions described above for the reaction ofcompounds of the formula IV.1 with compounds of the formula V may beemployed.

Compounds of the formula I in which R² and R³ together with the atomslinking them form a cyclic group and R² is optionally R^(a)-substitutedC₁-alkyl can be obtained as described above. These compounds correspondto the formula I.2

in which R³¹ together with the a carbon atom of R² and the carbon atomsof the skeleton linking the R² and R³ groups form a five- toten-membered saturated or partially unsaturated cyclic group which, inaddition to the carbon atoms, may contain one to three heteroatoms fromthe group consisting of N, O and S and/or may be partially or fullyhalogenated and/or may carry one, two, three or up to the maximumpossible number of identical or different groups R^(a).

The compounds I.2 can be obtained by condensing compounds of the formulaII.2 in which Y¹ is a nucleophilically replaceable group such ashalogen, alkylsulfonyloxy and arylsulfonyloxy, preferably chlorine,bromine and iodine, particularly preferably chlorine, and Y² is hydrogenor one of the groups mentioned above with O-substituted hydroxylaminesof the formula III.

Under basic conditions, the compounds of the formula IV.2 are reactedfurther with compounds of the formula V. The resulting compoundscorrespond to those of the formula VI.1.

The starting materials are generally reacted with one another inequimolar amounts. In terms of yield, it may be advantageous to employan excess of IV.2, based on V.

If desired, the compounds of the formula VI.1 are reacted under basicconditions with compounds of the formula VIII. The resulting compoundscorrespond to those of the formula I.2.

The starting materials are generally reacted with one another inequimolar amounts. In terms of yield, it may be advantageous to employan excess of the compounds of the formula VIII, based on the compoundsof the formula VI.1.

The order of these synthesis steps may also be changed such thatinitially compounds of the formula IV.2 are reacted with compounds ofthe formula VIII. By reacting the intermediate with compounds of theformula V, it is then possible to obtain compounds of the formula I.2.To this end, the conditions described above for the reaction ofcompounds of the formula IV.1 with compounds of the formula V may beemployed.

The reaction mixtures are worked up in a customary manner, for exampleby mixing with water, separating the phases and, if appropriate,chromatographic purification of the crude products. Some of theintermediates and end products are obtained in the form of colorless orslightly brownish viscous oils which are purified or freed from volatilecomponents under reduced pressure and at moderately elevatedtemperature. If the intermediates and end products are obtained assolids, purification can also be carried out by recrystallization ordigestion.

The starting materials required for preparing the compounds I are knownfrom the literature or can be prepared in accordance with the literaturecited. If individual compounds of the formula I can not be obtained bythe routes described above, they can be prepared by derivatization ofother compounds I.

If the synthesis yields mixtures of isomers, a separation is generallynot necessarily required since in some cases the individual isomers canbe interconverted during preparation for application or duringapplication (for example under the action of light, acid or bases). Suchconversions may also take place after application, for example in thecase of the treatment of plants in the treated plants or in the harmfulfungus to be controlled.

In the definitions of the symbols given in the above formulae,collective terms were used which are generally representative for thefollowing substituents:

halogen: fluorine, chlorine, bromine and iodine;

alkyl: saturated straight-chain or branched hydrocarbon groups having 1to 4, 6 or 8 carbon atoms, for example C₁-C₆-alkyl, such as methyl,ethyl, propyl, 1-methylethyl, butyl, 1-methylpropyl, 2-methylpropyl,1,1-dimethylethyl, pentyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl,2,2-dimethylpropyl, 1-ethylpropyl, 1,1-dimethylpropyl,1,2-dimethylpropyl, hexyl, 1-methylpentyl, 2-methylpentyl,3-methylpentyl, 4-methyl-pentyl, 1,1-dimethylbutyl, 1,2-dimethylbutyl,1,3-dimethylbutyl, 2,2-dimethylbutyl, 2,3-dimethylbutyl,3,3-dimethylbutyl, 1-ethylbutyl, 2-ethylbutyl, 1,1,2-trimethylpropyl,1,2,2-trimethylpropyl, 1-ethyl-1-methylpropyl and1-ethyl-2-methylpropyl;

haloalkyl: straight-chain or branched alkyl groups having 1 to 2, 4 or 6carbon atoms (as mentioned above), where some or all of the hydrogenatoms in these groups may be replaced by halogen atoms as mentionedabove: in particular C₁-C₂-haloalkyl, such as chloromethyl, bromomethyl,dichloromethyl, trichloromethyl, fluoromethyl, difluoromethyl,trifluoromethyl, chlorofluoromethyl, dichlorofluoromethyl,chlorodifluoromethyl, 1-chloroethyl, 1-bromoethyl, 1-fluoroethyl,2-fluoroethyl, 2,2-difluoroethyl, 2,2,2-trifluoroethyl,2-chloro-2-fluoroethyl, 2-chloro-2,2-difluoroethyl,2,2-dichloro-2-fluoroethyl, 2,2,2-trichloroethyl, pentafluoroethyl or1,1,1-trifluoro-prop-2-yl;

alkenyl: unsaturated straight-chain or branched hydrocarbon groupshaving 2 to 4, 6 or 8 carbon atoms and one or two double bonds in anyposition, for example C₂-C₆-alkenyl, such as ethenyl, 1-propenyl,2-propenyl, 1-methylethenyl, 1-butenyl, 2-butenyl, 3-butenyl,1-methyl-1-propenyl, 2-methyl-1-propenyl, 1-methyl-2-propenyl,2-methyl-2-propenyl, 1-pentenyl, 2-pentenyl, 3-pentenyl, 4-pentenyl,1-methyl-1-butenyl, 2-methyl-1-butenyl, 3-methyl-1-butenyl,1-methyl-2-butenyl, 2-methyl-2-butenyl, 3-methyl-2-butenyl,1-methyl-3-butenyl; 2-methyl-3-butenyl, 3-methyl-3-butenyl,1,1-dimethyl-2-propenyl, 1,2-dimethyl-1-propenyl,1,2-dimethyl-2-propenyl, 1-ethyl-1-propenyl, 1-ethyl-2-propenyl,1-hexenyl, 2-hexenyl, 3-hexenyl, 4-hexenyl, 5-hexenyl,1-methyl-1-pentenyl, 2-methyl-1-pentenyl, 3-methyl-1-pentenyl,4-methyl-1-pentenyl, 1-methyl-2-pentenyl, 2-methyl-2-pentenyl,3-methyl-2-pentenyl, 4-methyl-2-pentenyl, 1-methyl-3-pentenyl,2-methyl-3-pentenyl, 3-methyl-3-pentenyl, 4-methyl-3-pentenyl,1-methyl-4-pentenyl, 2-methyl-4-pentenyl, 3-methyl-4-pentenyl,4-methyl-4-pentenyl, 1,1-dimethyl-2-butenyl, 1,1-dimethyl-3-butenyl,1,2-dimethyl-1-butenyl, 1,2-dimethyl-2-butenyl, 1,2-dimethyl-3-butenyl,1,3-dimethyl-1-butenyl, 1,3-dimethyl-2-butenyl, 1,3-dimethyl-3-butenyl,2,2-dimethyl-3-butenyl, 2,3-dimethyl-1-butenyl, 2,3-dimethyl-2-butenyl,2,3-dimethyl-3-butenyl, 3,3-dimethyl-1-butenyl, 3,3-dimethyl-2-butenyl,1-ethyl-1-butenyl, 1-ethyl-2-butenyl, 1-ethyl-3-butenyl,2-ethyl-1-butenyl, 2-ethyl-2-butenyl, 2-ethyl-3-butenyl,1,1,2-trimethyl-2-propenyl, 1-ethyl-1-methyl-2-propenyl,1-ethyl-2-methyl-1-propenyl and 1-ethyl-2-methyl-2-propenyl;

alkynyl: straight-chain or branched hydrocarbon groups having 2 to 4, 6or 8 carbon atoms and one or two triple bonds in any position, forexample C₂-C₆-alkynyl, such as ethynyl, 1-propynyl, 2-propynyl,1-butynyl, 2-butynyl, 3-butynyl, 1-methyl-2-propynyl, 1-pentynyl,2-pentynyl, 3-pentynyl, 4-pentynyl, 1-methyl-2-butynyl,1-methyl-3-butynyl, 2-methyl-3-butynyl, 3-methyl-1-butynyl,1,1-dimethyl-2-propynyl, 1-ethyl-2-propynyl, 1-hexynyl, 2-hexynyl,3-hexynyl, 4-hexynyl, 5-hexynyl, 1-methyl-2-pentynyl,1-methyl-3-pentynyl, 1-methyl-4-pentynyl, 2-methyl-3-pentynyl,2-methyl-4-pentynyl, 3-methyl-1-pentynyl, 3-methyl-4-pentynyl,4-methyl-1-pentynyl, 4-methyl-2-pentynyl, 1,1-dimethyl-2-butynyl,1,1-dimethyl-3-butynyl, 1,2-dimethyl-3-butynyl, 2,2-dimethyl-3-butynyl,3,3-dimethyl-1-butynyl, 1-ethyl-2-butynyl, 1-ethyl-3-butynyl,2-ethyl-3-butynyl and 1-ethyl-1-methyl-2-propynyl;

cycloalkyl: mono- or bicyclic saturated hydrocarbon groups having 3 to 6or 8 carbon ring members, for example C₃-C₈-cycloalkyl, such ascyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cycloheptyl andcyclooctyl;

cycloalkenyl: mono- or bicyclic unsaturated hydrocarbon groups having 3to 6 or 8 carbon ring members and one or two double bonds in anyposition, for example C₃-C₈-cycloalkenyl, such as cyclopropenyl,cyclobutenyl, cyclopentenyl, cyclohexenyl, cycloheptenyl andcyclooctenyl;

aryl or aromatic ring: a ring comprising mono-, bi- or tricyclicaromatic hydrocarbon groups and having 6, 8, 10, 12 or 14 ring members,such as phenyl, naphthyl or anthracenyl, preferably phenyl or naphthyl,in particular phenyl;

heterocyclyl: three- to ten-membered saturated, partially unsaturated oraromatic mono- or bicyclic heterocyclyl which contains one, two, threeor four heteroatoms from the group consisting of O, N and S: inparticular having five or six ring members

-   -   non-aromatic saturated or partially unsaturated 5- or 6-membered        heterocyclyl which contains one to three nitrogen atoms and/or        one oxygen or sulfur atom or one or two oxygen and/or sulfur        atoms, for example 2-tetrahydrofuranyl, 3-tetrahydrofuranyl,        2-tetrahydrothienyl, 3-tetrahydrothienyl, 2-pyrrolidinyl,        3-pyrrolidinyl, 3-isoxazolidinyl, 4-isoxazolidinyl,        5-isoxazolidinyl, 3-isothiazolidinyl, 4-isothiazolidinyl,        5-isothiazoiidinyl, 3-pyrazolidinyl, 4-pyrazolidinyl,        5-pyrazolidinyl, 2-oxazolidinyl, 4-oxazolidinyl, 5-oxazolidinyl,        2-thiazolidinyl, 4-thiazolidinyl, 5-thiazolidinyl,        2-imidazolidinyl, 4-imidazolidinyl, 2-pyrrolin-2-yl,        2-pyrrolin-3-yl, 3-pyrrolin-2-yl, 3-pyrrolin-3-yl,        2-piperidinyl, 3-piperidinyl, 4-piperidinyl, 1,3-dioxan-5-yl,        2-tetrahydropyranyl, 4-tetrahydropyranyl, 2-tetrahydrothienyl,        3-hexahydropyridazinyl, 4-hexahydro-pyridazinyl,        2-hexahydropyrimidinyl, 4-hexahydropyrimidinyl,        5-hexahydropyrimidinyl and 2-piperazinyl;    -   5-membered heteroaryl which contains one to four nitrogen atoms        or one to three nitrogen atoms and one sulfur or oxygen atom:        5-membered heteroaryl groups which, in addition to carbon atoms,        may contain one to four nitrogen atoms or one to three nitrogen        atoms and one sulfur or oxygen atom as ring members, for example        2-furyl, 3-furyl, 2-thienyl, 3-thienyl, 2-pyrrolyl, 3-pyrrolyl,        3-pyrazolyl, 4-pyrazolyl, 5-pyrazolyl, 2-oxazolyl, 4-oxazolyl,        5-oxazolyl, 2-thiazolyl, 4-thiazolyl, 5-thiazolyl, 2-imidazolyl,        4-imidazolyl, and 1,3,4-triazol-2-yl;    -   6-membered heteroaryl which contains one to three or one to four        nitrogen atoms: 6-membered heteroaryl groups which, in addition        to carbon atoms, may contain one to three or one to four        nitrogen atoms as ring members, for example 2-pyridinyl,        3-pyridinyl, 4-pyridinyl, 3-pyridazinyl, 4-pyridazinyl,        2-pyrimidinyl, 4-pyrimidinyl, 5-pyrimidinyl and 2-pyrazinyl;

cyclic groups: cycloalkyl, cycloalkenyl, aryl or heterocyclyl groups asmentioned above;

alkoxy: alkyl groups as mentioned above which are attached to theskeleton via oxygen, for example C₁-C₈-alkoxy, such as OCH₃, OCH₂CH₃,O(CH₂)₂CH₃, O(CH₂)₃CH₃, O(CH₂)₄CH₃, O(CH₂)₅CH₃, O(CH₂)₆CH₃ andO(CH₂)₇CH₃;

alkenoxy: alkenyl groups as mentioned above which are attached to theskeleton via oxygen, for example C₂-C₈-alkenoxy, such as OCH═CH₂,OCH₂CH═CH₂, OCH₂CH═CHCH₃; O(CH₂)₂CH═CHCH₃ and O(CH₂)₃CH═CHCH₃;

alkynoxy: alkynyl groups as mentioned above which are attached to theskeleton via oxygen, for example C₃-C₈-alkynoxy, such as OCH₂C≡CH,O(CH₂)₂CH≡CH, O(CH₂)₃CH≡CH and O(CH₂)₄CH≡CH;

alkylcarbonyl: alkyl groups as mentioned above which are attached to theskeleton via a carbonyl group, for example C₁-C₈-alkylcarbonyl, such asCOCH₃, COCH₂CH₃, CO(CH₂)₂CH₃, CO(CH₂)₃CH₃, CO(CH₂)₄CH₃, CO(CH₂)₅CH₃,CO(CH₂)₆CH₃ and CO(CH₂)₇CH₃;

alkoxycarbonyl: alkoxy groups as mentioned above which are attached tothe skeleton via a carbonyl group, for example C₁-C₄-alkoxycarbonyl,such as COOCH₃, COOCH₂CH₃, COO(CH₂)₂CH₃, COO(CH₂)₃CH₃, COO(CH₂)₄CH₃,COO(CH₂)₅CH₃, COO(CH₂)₆CH₃ and COO(CH₂)₇CH₃;

alkylcarbonyloxy or alkylcarboxyl: alkylcarbonyl groups as mentionedabove which are attached to the skeleton via oxo, for exampleC₁-C₄-alkylcarbonyloxy, such as OCOCH₃, OCOCH₂CH₃, OCO(CH₂)₂CH₃ andOCO(CH₂)₃CH₃;

alkylcarbonylamino: alkylcarbonyl groups as mentioned above which areattached to the skeleton via amino, for exampleC₁-C₈-alkylcarbonylamino, such as NHCOCH₃, NHCOCH₂CH₃, NHCO(CH₂)₂CH₃,NHCO(CH₂)₃CH₃, NHCO(CH₂)₄CH₃, NHCO(CH₂)₅CH₃, NHCO(CH₂)₆CH₃ andNHCO(CH₂)₇CH₃;

cycloalkylcarbonyl: cycloalkyl groups as mentioned above which areattached to the skeleton via a carbonyl group, for exampleC₃-C₈-cycloalkylcarbonyl, such as cyclopropylcarbonyl,cyclobutylcarbonyl, cyclopentylcarbonyl, cyclohexylcarbonyl,cycloheptylcarbonyl and cyclooctylcarbonyl;

cycloalkylcarbonylamino: cycloalkylcarbonyl groups as mentioned abovewhich are attached to the skeleton via amino, for exampleC₃-C₈-cycloalkylcarbonylamino, such as cyclopropylcarbonylamino,cyclobutylcarbonylamino, cyclopentylcarbonylamino,cyclohexylcarbonylamino, cycloheptylcarbonylamino andcyclooctylcarbonylamino;

alkylene: divalent unbranched chains of 2 to 8 CH₂ groups, for exampleCH₂CH₂, CH₂CH₂CH₂, CH₂CH₂CH₂CH₂, CH₂CH₂CH₂CH₂CH₂, CH₂CH₂CH₂CH₂CH₂CH₂,CH₂CH₂CH₂CH₂CH₂CH₂CH₂ and CH₂CH₂CH₂CH₂CH₂CH₂CH₂CH₂;

oxyalkylene: divalent unbranched chains of 2 to 4 CH₂ groups where onevalency is attached via an oxygen atom to the skeleton, for exampleOCH₂CH₂, OCH₂CH₂CH₂ and OCH₂CH₂CH₂CH₂;

oxyalkyleneoxy: divalent unbranched chains of 1 to 3 CH₂ groups whereboth valencies are attached via an oxygen atom to the skeleton, forexample OCH₂O, OCH₂CH₂O and OCH₂CH₂CH₂O.

alkylidene: divalente straight-chain or branched hydrocarbon groupswhich have 2 to 4, 6 or 8 carbon atoms and are attached to the skeletonvia a double bond, for example C₁-C₈-alkylidene, such as methylidene,ethylidene, propylidene, isopropylidene, butylidene, hexylidene andoctylidene;

cycloalkylidene: cycloalkyl groups as mentioned above which are attachedto the skeleton via a double bond, for example C₃-C₈-cycloalkylidene,such as cyclopropylidene, cyclobutylidene, cyclopentylidene,cyclohexylidene, cycloheptylidene and cyclooctylidene;

alkoxyimino: alkoxy groups as mentioned above which are attached to theskeleton via imino, for example C₁-C₄-alkoxyimino, such as ═NOCH₃,═NOCH₂CH₃, ═NO(CH₂)₂CH₃, ═NO(CH₂)₃CH₃, ═NO(CH₂)₄CH₃, ═NO(CH₂)₅CH₃,═NO(CH₂)₆CH₃ and ═NO(CH₂)₇CH₃;

and divalent groups: oxo, alkylene, oxyalkylene, oxyalkyleneoxy,alkylidene and cycloalkylidene groups as mentioned above.

Agriculturally useful salts include in particular the salts of thosecations or the acid addition salts of those acids whose cations andanions, respectively, have no adverse effect on the fungicidal action ofthe compounds of the formula I. Thus, suitable cations are in particularthe ions of the alkali metals, preferably sodium and potassium, of thealkaline earth metals, preferably calcium, magnesium and barium, and ofthe transition metals, preferably manganese, copper, zinc and iron, andalso the ammonium ion which, if desired, may carry from one to four(C₁-C₄)-alkyl substituents and/or one phenyl or benzyl substituent,preferably diisopropylammonium, tetramethylammonium, tetrabutylammonium,trimethylbenzylammonium, and also phosphonium ions, sulfonium ions,preferably tri(C₁-C₄)-alkylsulfonium, and sulfoxonium ions, preferablytri(C₁-C₄)-alkylsulfoxonium.

Anions of useful acid addition salts are, primarily, chloride, bromide,fluoride, hydrogensulfate, sulfate, dihydrogenphosphate,hydrogenphosphate, phosphate, nitrate, bicarbonate, carbonate,hexafluorosilicate, hexafluorophosphate, benzoate, and also the anionsof (C₁-C₄)-alkanoic acids, preferably formate, acetate, propionate andbutyrate. They can be formed by reacting the compounds of formula I withan acid of the corresponding anion, preferably hydrochloric acid,hydrobromic acid, sulfuric acid, phosphoric acid or nitric acid.

The scope of the present invention includes the (R)- and (S)-isomers andthe racemates of compounds of the formula I having chiral centers.

As a result of hindered rotation of asymmetrically substituted groups,atrope isomers of compounds of the formula I may be present. They alsoform part of the subject matter of the invention.

The embodiments of the intermediates with respect to the variablescorrespond to those of the formula I.

With a view to the intended use of the compounds of the formula I andthe compounds of all subformulae mentioned herein, such as formulae I.1to 1.10 and I.3A to I.3E, for example, particular preference is given tothe following meanings of the substituents R¹, R², R³, R⁴, R⁵, R⁶, R⁷,L¹, L², L³, L⁴ and X, in each case on their own or in combination:

In the compounds according to the invention, R¹ is preferablyC₁-C₈-alkyl, C₂-C₈-alkenyl, C₂-C₈-alkynyl, C₃-C₈-cycloalkyl, phenyl or afive- or six-membered saturated, partially unsaturated or aromaticheterocyclyl which, in addition to carbon atoms, contains-one to threeheteroatoms from the group consisting of O, N and S as ring members,where R¹ may carry one, two, three or up to the maximum possible numberof identical or different groups R^(a) which are not heterocyclicgroups.

One embodiment relates to compounds I in which R¹ is optionallyR^(a)-substituted C₁-C₈-alkyl, C₂-C₈-alkenyl, C₃-C₈-cycloalkyl, phenyl,pyridyl, pyrazolyl, imidazolyl or triazolyl.

A further embodiment relates to compounds I in which R¹ is optionallyR^(a)-substituted C₁-C₈-alkyl, C₂-C₈-alkenyl, C₃-C₈-cycloalkyl orphenyl.

A further embodiment relates to compounds I in which R¹ is optionallyR^(a)-substituted C₁-C₈-alkyl.

A further embodiment relates to compounds I in which R¹ is optionallyR^(a)-substituted C₂-C₈-alkenyl.

A further embodiment relates to compounds I in which R¹ is optionallyR^(a)-substituted C₃-C₈-cycloalkyl.

A further embodiment relates to compounds I in which R¹ is optionallyR^(a)-substituted phenyl.

A further embodiment relates to compounds I in which the α carbon atomin R¹ does not carry a cyclic group.

A further embodiment relates to compounds I in which R¹ is optionallyR^(a)-substituted C₁-C₄-alkyl or C₂-C₄-alkenyl.

A further embodiment relates to compounds I in which R¹ is optionallyR^(a)-substituted methyl.

A further embodiment relates to compounds I in which R¹ isunsubstituted.

Further embodiments relate to compounds I in which R¹ is in each caseone of the following groups I-1 to I-19 in table I:

TABLE I No. R¹ I-1 CH₃ I-2 CH₂CH₃ I-3 CH(CH₃)₂ I-4 CH₂CH₂CH₃ I-5 CH₂CF₃I-6 CHF₂ I-7 CH₂OCH₃ I-8 CH₂CH₂CH₂CH₃ I-9 CH(CH₃)CH₂CH₃ I-10 CH₂CH(CH₃)₂I-11 (S)—CHCF₃CH₃ I-12 (R)—CHCF₃CH₃ I-13 cyclopropylmethyl I-142-buten-1-yl I-15 3-methyl-2-buten-1-yl I-16 propargyl I-17 1-butyn-3-ylI-18 2-butyn-1-yl I-19 E-3-chloro-2-propen-1-yl

In the compounds according to the invention, R² is preferably optionallysubstituted amino, C₁-C₈-alkyl, C₂-C₈-alkenyl, C₂-C₈-alkynyl,C₁-C₈-alkylcarbonyl, C₁-C₈-alkoxy-carbonyl, C₃-C₈-cycloalkyl, phenyl orfive- or six-membered saturated, partially unsaturated or aromaticheterocyclyl which, in addition to carbon atoms, contains one to threeheteroatoms from the group consisting of O, N and S as ring members.

One embodiment relates to compounds I in which R² is optionallyR^(a)-substituted amino, C₁-C₈-alkyl, C₂-C₈-alkenyl, C₂-C₈-alkynyl,C₁-C₈-alkylcarbonyl, C₁-C₈-alkoxy-carbonyl, C₃-C₈-cycloalkyl, phenyl orfive- or six-membered saturated, partially unsaturated or aromaticheterocyclyl which, in addition to carbon atoms, contains one to threeheteroatoms from the group consisting of O, N and S as ring members.

A further embodiment relates to compounds I in which R² is optionallyR^(a)-substituted C₁-C₈-alkyl or phenyl.

A further embodiment relates to compounds I in which R² is optionallyR^(a)-substituted phenyl or heterocyclyl.

A further embodiment relates to compounds I in which R² is optionallyR^(a)-substituted C₁-C₈-alkyl.

A further embodiment relates to compounds I in which R² is optionallyR^(a)-substituted phenyl.

A further embodiment relates to compounds I in which R² is a substitutedC₁-C₈-alkyl which carries a phenyl or heterocyclyl group and optionallya further one, two, three or four identical or different R^(a) groups.

A further embodiment relates to compounds I in which R² is a substitutedC₁-C₈-alkyl which carries a phenyl or heterocyclyl group attached viaoxygen and optionally substituted by R^(b), and optionally carries afurther one, two, three or four identical or different R^(a) groups.

A further embodiment relates to compounds I in which R² is CH₂—R^(2a)where R^(2a) is a group R^(a)-attached via oxygen. These compoundscorrespond to the formula I.1.

A further embodiment relates to compounds I in which R² is a substitutedmethyl which carries a phenyl or heterocyclyl group which is attachedvia oxygen and optionally substituted by R^(b).

A further embodiment relates to compounds I in which R² isunsubstituted.

Further embodiments relate to compounds I in which R² is in each caseone of the following groups II-1 to II-325 in table II:

TABLE II No. R² (# defines the bond to the skeleton) II-1(2-methylpyridyl-5-oxy)methyl II-2(2-trifluoromethylpyridyl-5-oxy)methyl II-3(3-(4-chlorophenyl)-4-methyl- pyrazol-1-yl)methyl II-4(3,4-dimethylpyrazol-1-yl)methyl II-5(3-chloro-2-fluoropyridyl-5-oxy)methyl II-6(3-chloropyridyl-5-oxy)methyl II-7(4-(4-methylphenyl)pyrazol-1-yl)methyl II-8(4-chlorophenyl)methoxymethyl II-9 (4-methylpyrazol-1-yl)methyl II-10(imidazolazol-1-yl)methyl II-11 (pyrazol-1-yl)methyl II-12(pyridyl-3-oxy)methyl II-13 (pyrimidinyl-5-oxy)methyl II-14(R)-1-methyl-2,2,2-trifluoroethyl- aminomethyl II-15(S)-1-methyl-2,2,2-trifluoroethyl- aminomethyl II-16[1,2,4]-triazol-1-ylmethyl II-17 1-methylpyrazol-5-yloxymethyl II-182-(3,4-dimethoxyphenyl)ethoxy- methyl II-192-(3,4-dimethoxyphenyl)ethyl- aminomethyl II-202,2,2-trifluoroethoxymethyl II-21 2,2,2-trifluoroethyl II-222,3,4-trichlorophenoxymethyl II-23 2-fluorophenoxymethyl II-242-trifluoromethylphenoxymethyl II-25 4-trifluoromethylphenoxymethylII-26 2-bromophenoxymethyl II-27 4-bromophenoxymethyl II-274-bromophenoxymethyl II-28 2-chlorophenoxymethyl II-292,6-dichlorophenoxymethyl II-30 3,4,5-trifluorophenoxymethyl II-314-chloro-3-fluorophenoxymethyl II-32 2-chloro-4-fluorophenoxymethylII-33 4-chloro-2-fluorophenoxymethyl II-34 4-chloro-2-trifluoromethyl-phenoxymethyl II-35 4-chloro-6-trifluoromethyl- phenoxymethyl II-362-fluoro-6-trifluoromethylphenoxy- methyl II-372-fluoro-4-trifluoromethylphenoxy- methyl II-38 2,3,4-trichlorophenylII-39 2,3,4-trifluorophenoxymethyl II-40 2,3,4-tetrafluoro-4-trifluoro-methylphenoxymethyl II-41 2,3,6-trichlorophenoxymethyl II-422,3-dichlorophenoxymethyl II-43 2,4,5-trifluorophenoxymethyl II-442,4,6-trifluorophenoxymethyl II-45 2,4-dichloro-3-methylphenyl II-462,4-dichloro-5-methoxyphenoxy- methyl II-47 2,4-dichlorophenoxymethylII-48 2,4-dichlorophenyl II-49 2,4-difluorophenoxymethyl II-502,4-difluorophenyl II-51 2,5-dichlorophenoxymethyl II-522,5-dichlorophenyl II-53 2,6-dichloro-4-fluorophenoxy- methyl II-542,6-dichloro-4-methylphenoxy- methyl II-55 2,6-difluorophenoxymethylII-56 2,6-dimethylphenoxymethyl II-57 2-bromo-4,5-difluorophenoxy-methyl II-58 2- chloro-4-trifluoromethyl- phenoxymethyl II-592-chloro-5-trifluoromethyl- phenoxymethyl II-602-chloro-6-fluorophenoxymethyl II-61 2-fluoro-3-trifluoromethyl-phenoxymethyl II-62 2-fluoro-5-trifluoromethylphenoxy- methyl II-632-methoxyphenyl II-64 2-propaniminoxymethyl II-653-(2,4-dichlorophenyl)pyrazol-1-yl- methyl II-663-(4-chlorophenoxy)phenoxy- methyl II-673-(trifluoromethyl)phenoxymethyl II-68 3,4,5-trichlorophenoxymethylII-69 3,4,5-trimethylpyrazol-1-ylmethyl II-70 3,4-dichlorophenoxymethylII-71 3,4-dichlorophenyl II-72 3,4-difluorophenoxymethyl II-733,4-difluorophenyl II-74 3,4-dimethoxyphenoxymethyl II-753,4-ethylenedioxyphenyl II-76 3,4-methylenedioxyphenoxy- methyl II-773,5-bis(2-methylphenyl)pyrazol- 1-ylmethyl II-783,5-bistrifluoromethylphenoxy- methyl II-79 3,5-dichlorophenoxymethylII-80 3,5-dimethoxyphenoxymethyl II-81 3,5-dimethylpyrazol-1-ylmethylII-82 3-acetamino-2,4-dimethylphenyl II-83 3-acetaminophenyl II-843-bromo-4-fluorophenoxymethyl II-85 3-bromophenoxymethyl II-863-chloro-2-fluoro-5-trifluoromethyl- phenoxymethyl II-873-chloro-4-(3-chloro-5-trifluoro- methylpyridin-2-yloxy)phenoxy- methylII-88 3-chloro-4-(phenylcarbonyl)- phenoxymethyl II-893-chloro-4-bromophenoxymethyl II-90 3-chloro-4-ethoxycarbonyl-phenoxymethyl II-91 3-chloro-4-fluorophenoxymethyl II-923-chloro-4-methylphenoxymethyl II-93 3-chlorophenoxymethyl II-943-chlorophenyl II-95 3-cyanophenoxymethyl II-963-difluoromethoxyphenoxymethyl II-97 3-fluorophenoxymethyl II-983-isopropylphenoxymethyl II-99 3-isopropylpyrazol-1-ylmethyl II-1003-methyl-4-phenylpyrazol-1-yl- methyl II-101 3-methylpyrazol-1-ylmethylII-102 3-phenoxyphenoxymethyl II-103 3-phenylphenoxymethyl II-1043-trifluoromethyl-4-cyano- phenoxymethyl II-1053-trifluoromethylphenoxymethyl II-106 4-(3-chloro-5-trifluoromethyl-pyridin-2-yloxy)phenyl II-107 4-(4-chlorophenoxy)phenyl II-1084-(4-chlorophenyl)phenyl II-109 4-(4-fluorophenyl)pyrazol-1-yl- methylII-110 4-(methylsulfonylamino)phenyl II-1114,5-difluoro-2-methylphenoxy- methyl II-1124,6-dimethyl-2-(1-oxo-1-ethyl)- phenoxymethyl II-113 4-bromophenylII-114 4-chloro-1-naphthoxymethyl II-115 4-chloro-2,5-dimethylphenoxy-methyl II-116 4-chloro-2-fluoro-5-methylphenyl II-1174-chloro-2-phenylphenoxymethyl II-118 4-chloro-3-(phenylcarbonyl)-phenoxymethyl II-119 4-chloro-3,5-dimethylphenoxy- methyl II-1204-chloro-3-ethylphenoxymethyl II-121 4-chloro-3-methylphenoxymethylII-122 4-chloro-3-trifluoromethoxy- phenoxymethyl II-1234-chlorophenoxymethyl II-124 4-chlorophenyl II-1254-chloropyrazol-1-ylmethyl II-126 4-cyano-3-trifluoromethyl-phenoxymethyl II-127 4-cyanophenoxymethyl II-1284-fluoro-2-methylphenoxymethyl II-129 4-fluoro-2-trifluoromethyt-phenoxymethyl II-130 4-fluoro-3-methylphenoxymethyl II-1314-fluoro-3-trifluoromethylphenoxy- methyl II-132 4-fluorophenoxymethylII-133 4-fluorophenyl II-134 4-methoxyphenyl II-1354-methyl-2,3,5,6-tetrafluoro- phenoxymethyl II-1364-methyl-3-phenylpyrazol-1-yl- methyl II-137 4-methylphenoxymethylII-138 4-phenoxyphenyl II-139 4-phenylpyrazol-1-ylmethyl II-1404-tert-butylphenoxymethyl II-141 4-tert-butylphenyl II-1424-trifluoromethylphenyl II-143 5-bromo-2-chloro-4-fluoro- phenoxymethylII-144 5-bromo-2-chloro-4-iodophenoxy- methyl II-1455-chloro-2-methoxyphenyl II-146 C(CH₃)₃ II-147 CCH₃═NOCH₃ II-148 CH₂CH₃II-149 CH₂CH₂CH₃ II-150 CH₂CN II-151 CH₂COOCH₂CH₃ II-152 CH₂OCH₃ II-153CH₃ II-154 COOCH₂CH₃ II-155 COOCH₃ II-156 cyanoaminomethyl II-157hydroxymethyl II-158 isopropyloxymethyl II-159 methoxycarbonylmethylII-160 morpholin-4-ylmethyl II-161 N-ethyl-N-methylaminomethyl II-162NH₂ II-163 phenyl II-164 piperidin-1-ylmethyl II-165 piperidin-1-ylII-166 pyrrolidin-1-yl II-167 2-pyrolidon-1-yl II-168 pyrazol-1-ylII-169 trifluoromethyl II-170 isopropyl II-171 3-(4-chlorophenyl)propylII-172 2-(2,3,4-trichlorophenyl)ethyl II-173 2-(2-fluorophenyl)ethylII-174 2-(2-trifluoromethylphenyl)ethyl II-1752-(4-trifluoromethylphenyl)ethyl II-176 2-(2-bromophenyl)ethyl II-1772-(4-bromophenyl)ethyl II-178 2-(2-chlorophenyl)ethyl II-1792-(2,6-dichlorophenyl)ethyl II-180 2-(3,4,5-trifluorophenyl)ethyl II-1812-(4-chloro-3-fluoro.phenyl)ethyl II-1822-(2-chloro-4-fluorophenyl)ethyl II-183 2-(4-chloro-2-fluorophenyl)ethylII-184 2-(4-chloro-2-trifluoromethyl- phenyl)ethyl II-1852-(4-chloro-6-trifluoromethyl- phenyl)ethyl II-186 2-(2-fluoro-6-trifluoromethylphenyl)ethyl II-187 2-(2-fluoro-4-trifluoromethyphenyl)ethyl II-188 2-(2,3,4-trifluorophenyl)ethyl II-1892-(2,3,6-trichlorophenyl)ethyl II-190 2-(2,3-dichlorophenyl)ethyl II-1912-(2,4,5-trifluorophenyl)ethyl II-192 2-(2,4,6-trifluorophenyl)ethylII-193 2-(2,4-dichloro-5-methoxy- phenyl)ethyl II-1942-(2,4-dichlorophenyl)ethyl II-195 2-(2,4-difluorophenyl)ethyl II-1962-(2,5-dichlorophenyl)ethyl II-197 2-(2,6-dichloro-4-fluorophenyl)-ethyl II-198 2-(2,6-dichloro-4-methylphenyl)- ethyl II-199 2-(2,6-difluorophenyl)ethyl II-200 2-(2, 6-dimethylphenyl)ethyl II-2012-(2-bromo-4,5-difluorophenyl)- ethyl II-2022-(2-chloro-4-trifluoromethyl- phenyl)ethyl II-2032-(2-chloro-5-trifluoromethyl- phenyl)ethyl II-2042-(2-chloro-6-fluorophenyl)ethyl II-205 2-(2-fluoro-3-trifluoromethyl-phenyl)-ethyl II-206 2-(2-fluoro-5-trifluoromethyl- phenyl)-ethyl II-2072-(3-(4-chlorophenylthio)phenyl)- ethyl II-2082-(3-(trifluoromethyl)phenyl)ethyl II-209 2-(3,4,5-trichlorophenyl)ethylII-210 2-(3,4-dichlorophenyl)ethyl II-211 2-(3,4-difluorophenyl)ethylII-212 2-(3,4-dimethoxyphenyl)ethyl II-2132-(3,5-bistrifluoromethylphenyl)ethyl II-214 2-(3,5-dichlorophenyl)ethylII-215 2-(3,5-dimethoxyphenyl)ethyl II-2162-(3-bromo-4-fluorophenyl)ethyl II-217 2-(3-bromophenyl)ethyl II-2182-(3-chloro-2-fluoro-5-trifluoro- methylphenyl)ethyl II-2192-(3-chloro-4-(3-chloro-5-trifluoro- methylpyridin-2-yloxy)phenyl)ethylII-220 2-(3-chloro-4-(phenyl-carbonyl)- phenyl)ethyl II-2212-(3-chloro-4-bromophenyl)ethyl II-222 2-(3-chloro-4-fluoro-phenyl)ethylII-223 2-(3-chloro-4-methyl-phenyl)ethyl II-224 2-(3-cyanophenyl)ethylII-225 2-(3-difluoromethoxyphenyl)ethyl II-226 2-(3-fluorophenyl)ethylII-227 2-(3-isopropylphenyl)ethyl II-228 2-(3-phenoxyphenyl)ethyl II-2292-(3-phenylphenyl)ethyl II-230 2-(3-trifluoromethylphenyl)ethyl II-2312-(4,5-difluoro-2-methylphenyl)ethyl II-2322-(4-chloro-2,5-dimethylphenyl)ethyl II-2332-(4-chloro-2-phenylphenyl)ethyl II-2342-(4-chloro-3,5-dimethylphenyl)ethyl II-2352-(4-chloro-3-ethylphenyl)ethyl II-236 2-(4-chloro-3-methylphenyl)ethylII-237 2-(4-chloro-3-trifluoromethoxy- phenyl)ethyl II-2382-(4-chlorophenyl)ethyl II-239 2-(4-cyanophenyl)ethyl II-2402-(4-fluoro-2-methylphenyl)ethyl II-241 2-(4-fluoro-2-trifluoromethyl-II-242 2-(4-fluoro-3-methylphenyl)ethyl II-2432-(4-fluoro-3-trifluoromethyl- phenyl)ethyl II-2442-(4-fluorophenypethyl II-245 2-(4-methylphenyl)ethyl II-2462-(4-tert.-Butylphenyl)ethyl II-247 2-(5-bromo-2-chloro-4-fluoro-phenyl)ethyl II-248 2-(5-bromo-2-chloro-4-iodo- phenyl)ethyl II-2492-(3-chlorophenyl)ethyl II-250 N-(2-chlorophenyl)aminomethyl II-251N-(2-bromophenyl)aminomethyl II-252 N-(2-trifluoromethylphenyl)-aminomethyl II-253 N-(3-chlorophenyl)aminomethyl II-254N-(3-bromophenyl)aminomethyl II-255 N-(3-trifluoromethylphenyl)-aminomethyl II-256 N-(4-chlorophenyl)aminomethyl II-257N-(4-bromophenyl)aminomethyl II-258 N-(4-trifluoromethylphenyl)-aminomethyl II-259 N-(3,4-dichlorophenyl)- aminomethyl II-260N-(2,6-dichlorophenyl)- aminomethyl II-261N-(2-chloro-6-fluorophenyl)-1- aminomethyl II-2623-(3-chlorophenyl)propyl II-263 3-(3-bromophenyl)propyl II-2643-(3-trifluoromethylphenyl)propyl II-265 3-(4-bromophenyl)propyl II-2663-(4-trifluoromethylphenyl)propyl II-267 3-(3,4-dichlorophenyppropylII-268 3-(2,6-dichlorophenyl)propyl II-2693-(2-chloro-6-fluorophenyl)propyl II-270 4-(3-chlorophenyl)butyl II-2714-(3-bromophenyl)butyl II-272 4-(3-trifluoromethylphenyl)butyl II-2734-(4-chlorophenyl)butyl II-274 4-(4-bromophenyl)butyl II-2754-(4-trifluoromethylphenyl)butyl II-276 4-(3,4-dichlorophenyl)butylII-277 4-(2,6-dichlorophenyl)butyl II-2784-(2-chloro-6-fluorophenyl)butyl II-279 3-chlorophenylmethyl II-2803-bromophenylmethyl II-281 3-trifluoromethylphenylmethyl II-2824-fluorophenylmethyl II-283 4-chlorophenylmethyl II-2844-bromophenylmethyl II-285 4-trifluoromethylphenylmethyl II-2863,4-dichlorophenylmethyl II-287 3,4-difluorophenylmethyl II-2882,6-dichlorophenylmethyl II-289 2-chloro-6-fluorophenylmethyl II-2902,4-dichlorophenylmethyl II-291 2,4-difluorophenylmethyl II-292

II-293

II-294

II-295

II-296

II-297

II-298

II-299

II-300

II-301

II-302

II-303

II-304

II-305

II-306

II-307

II-308

II-309

II-310

II-311

II-312

II-313

II-314

II-315

II-316

II-317

II-318

II-319

II-320

II-321

II-322

II-323

II-324

II-325

One embodiment relates to compounds I in which X is oxygen. Thesecompounds correspond to the formula I.3:

A further embodiment relates to compounds I in which X is sulfur.

One embodiment relates to compounds I in which R³ is C₁-C₄-alkyl orC₁-C₈-haloalkyl.

A further embodiment relates to compounds I in which R³ is C₁-C₄-alkyl.

A further embodiment relates to compounds I in which R³ isC₁-C₈-haloalkyl.

A further embodiment relates to compounds I in which R³ is methyl.

A further embodiment relates to compounds I in which R⁴ is hydrogen.These compounds correspond to the formula I.4:

A further embodiment relates to compounds I in which R³ and R⁴ arehydrogen. These compounds correspond to the formula I.5:

A further embodiment relates to compounds I in which R³ and R⁴ are nothydrogen.

A further embodiment relates to compounds I in which X is oxygen and R³and R⁴ are hydrogen. These compounds correspond to the formula I.3A:

A further embodiment relates to compounds I in which X is oxygen, R³ ismethyl and R⁴ is hydrogen. These compounds correspond to the formulaI.3B:

A further embodiment relates to compounds I in which X is oxygen and R³and R⁴ are methyl. These compounds correspond to the formula I.3C:

A further embodiment relates to compounds I in which X is oxygen, R³ isethyl and R⁴ is hydrogen. These compounds correspond to the formulaI.3D:

A further embodiment relates to compounds I in which X is oxygen, R³ isethyl and R⁴ is methyl. These compounds correspond to the formula I.3E:

One embodiment relates to compounds I in which R⁵ is methyl or ethyl.

A further embodiment relates to compounds I in which R⁵ is methyl.

One embodiment relates to compounds I in which R⁶ is ethyl.

Further embodiments relate to compounds I in which R⁵ and R⁶ are one ofthe following combinations III-1 to III-43 in table III:

TABLE III No. R⁵ R⁶ III-1 CH₃ CH₂CH₃ III-2 CH₃ CH₂CF₃ III-3 CH₃ CH₃III-4 CH₃ CH(CH₃)₂ III-5 CH₃ CHF₂ III-6 CH₃ CF₃ III-7 CH₃ CH₂CH₂CH₃III-8 CH₃ CH₂OCH₃ III-9 CH₃ C(CH₃)₃ III-10 CH₃ OCH₃ III-11 CH₃ OCH₂CH₃III-12 CH₃ OCH₂CH₂CH₃ III-13 CH₃ OCH(CH₃)₂ III-14 CH₃ OCHF₂ III-15 CH₃CH₂CH₂CH₃ III-16 CH₃ CH₂CH₂CF₃ III-17 CH₃ CH₂CHF₂ III-18 CH₃CH₂CH₂CH₂CH₃ III-19 CH₃ CH(CH₃)CH₂CH₃ III-20 CH₃ CH₂CH(CH₃)₂ III-21 CH₃(S)—CHCF₃CH₃ III-22 CH₃ (R)—CHCF₃CH₃ III-23 CH₃ cyclopropylmethyl III-24CH₃ 2-buten-1-yl III-25 CH₃ 3-methyl-2-buten-1-yl III-26 CH₃ propargylIII-27 CH₃ 1-butyn-3-yl III-28 CH₃ 2-butyn-1-yl III-29 CH₃E-3-chloro-2-propen-1-yl III-30 CH₃ cyclopropyl III-31 CH₃cyclopropylmethyl III-32 —CH₂CH₂CH₂CH₂— III-33 —(S)—CH(CH₃)CH₂CH₂CH₂—III-34 —(R)—CH(CH₃)CH₂CH₂CH₂— III-35 —CH(CH₃)CH₂CH₂CH(CH₃)— III-36—CH₂CH₂CH₂CH₂CH₂— III-37 —(S)—CH(CH₃)CH₂CH₂CH₂CH₂— III-38—(R)—CH(CH₃)CH₂CH₂CH₂CH₂— III-39 —CH(CH₃)CH₂CH₂CH₂CH(CH₃)— III-40—CH₂CH₂CH(CH₃)CH₂CH₂— III-41 —CH₂CH₂OCH₂CH₂— III-42 —CH₂CH₂N(CH₃)CH₂CH₂—III-43 —CH₂N(CH₃)CH₂CH₂CH₂—

One embodiment relates to compounds I in which L¹ and L² independentlyof one another are halogen or C₁-C₄-alkyl or haloalkyl.

One embodiment relates to compounds I in which L¹ and L² independentlyof one another are halogen, such as chlorine or fluorine.

A further embodiment relates to compounds I in which L¹ and L²independently of one another are methyl or halomethyl, such as CF₃,CCl₃, CH₂Cl, CH₂F, CHF₂ or CHCl₂.

A further embodiment relates to compounds in which L¹ and L² are methyl.

One embodiment relates to compounds I in which L³ and L⁴ are hydrogen.These compounds correspond to the formula I.6:

A preferred embodiment relates to compounds I in which L¹ and L²independently of one another are halogen or C₁-C₄-alkyl and L³ and L⁴are hydrogen.

Preferably, R⁵ and R⁶ in the compounds I according to the invention areC₁-C₄-alkyl which may carry one, two, three, four or five identical ordifferent groups R^(a).

One embodiment relates to compounds I in which R⁵ and R⁶ areC₁-C₄-alkyl.

One embodiment relates to compounds I in which R⁷ is unsubstituted.

One embodiment relates to compounds I in which R⁷ is hydrogen. Thesecompounds correspond to the formula I.7:

A further embodiment relates to compounds I in which R⁷ is methyl.

One embodiment relates to compounds I in which R³ and R⁴ together arenot able to form a cyclic group as described at the outset.

A further embodiment relates to compounds I in which R¹ and R², R¹ andR³, R² and R³ and also R³ and R⁴ are in each case not able to formcyclic groups as described at the outset.

A further embodiment relates to compounds I in which R² and R³ togetherwith the atoms linking them form a cyclic group and R² is optionallyR^(a)-substituted C₁-alkyl. These compounds correspond to the formulaI.2.

In the compounds according to the invention, R^(a) is preferablyhalogen, C₁-C₄-alkyl, C₁-C₄-haloalkyl, C₁-C₄-alkoxy, C₁-C₄-haloalkoxy,phenyl or a five- or six-membered saturated, partially unsaturated oraromatic heterocyclyl which, in addition to carbon atoms, contains oneto three heteroatoms from the group consisting of O, N and S as ringmembers, where the cyclic groups R^(a) may be attached directly or via anitrogen or oxygen atom; where the aliphatic and cyclic groups R^(a) fortheir part may be partially or fully halogenated and/or may carry one,two, three or up to the maximum possible number of identical ordifferent groups R^(b), where R^(b) is halogen, C₁-C₄-alkyl,C₁-C₄-haloalkyl, C₁-C₄-alkoxy or C₁-C₄-haloalkoxy.

In the compounds according to the invention, R^(a) is in particularhalogen, C₁-C₄-alkyl, C₁-C₄-alkoxy, C₁-C₄-haloalkoxy, phenyl, pyridyl,pyrimidinyl, pyridazinyl, triazinyl, pyrazolyl, imidazolyl or triazolyl,where the cyclic groups R^(a) may be attached directly or via an oxygenatom, where the aromatic and heterocyclic groups R^(a) for their partmay be partially or fully halogenated and/or may carry one, two, threeor up to the maximum possible number of identical or different groupsR^(b), where R^(b) is halogen, C₁-C₄-alkyl, C₁-C₄-haloalkyl,C₁-C₄-alkoxy or C₁-C₄-haloalkoxy.

In a further preferred embodiment, R^(a) in the compounds according tothe invention is halogen, C₁-C₄-alkyl, C₁-C₄-alkoxy, C₁-C₄-haloalkoxy,phenyl or pyridyl, where the cyclic groups R^(a) may be attacheddirectly or via an oxygen atom, where the aromatic and heterocyclicgroups R^(a) for their part may be partially or fully halogenated and/ormay carry one, two, three or up to the maximum possible number ofidentical or different groups R^(b), where R^(b) is halogen,C₁-C₄-alkyl, C₁-C₄-haloalkyl, C₁-C₄-alkoxy or C₁-C₄-haloalkoxy.

A further embodiment relates to compounds I in which R⁴, R⁷, L³ and L⁴are hydrogen and X is oxygen. These compounds correspond to the formulaI.8:

A further embodiment relates to compounds I in which R⁴, R⁷ and L⁴ arehydrogen and X is oxygen. These compounds correspond to the formula I.9:

According to a preferred embodiment of the compounds I:

-   R¹ is C₁-C₈-alkyl, C₂-C₈-alkenyl, C₃-C₈-cycloalkyl, phenyl, pyridyl,    pyrazoloyl, imidazolyl or triazolyl, where R¹ may carry one, two,    three or up to the maximum possible number of identical or different    groups R^(a) which are not heterocyclic groups;-   R² is amino, C₁-C₈-alkyl, C₂-C₈-alkenyl, C₃-C₈-cycloalkyl, phenyl,    pyridyl, pyrimidinyl, pyrazinyl, triazinyl, pyrazolyl, imidazolyl or    triazolyl, where R² may carry one, two, three or up to the maximum    possible number of identical or different groups R^(a);    -   R^(a) is halogen, C₁-C₄-alkyl, C₁-C₄-haloalkyl, C₁-C₄-alkoxy,        C₁-C₄-haloalkoxy, phenyl, pyrimidinyl, pyradizinyl, triazinyl,        pyrazolyl, imidazolyl or triazolyl; where the cyclic groups        R^(a) may be attached directly or via an oxygen atom and/or for        their part may be partially or fully halogenated and/or may        carry one, two, three or up to the maximum possible number of        identical or different groups R^(b):    -    R^(b) is halogen, C₁-C₄-alkyl, C₁-C₄-haloalkyl, C₁-C₄-alkoxy or        C₁-C₄-haloalkoxy;-   R³,R⁴ independently of one another are hydrogen, C₁-C₄-alkyl or    C₁-C₈-haloalkyl;-   R⁵,R⁶ is C₁-C₄-alkyl;-   R⁷ is hydrogen;-   L¹, L² independently of one another are halogen or C₁-C₄-alkyl;-   L³, L⁴ are hydrogen; and-   X is oxygen.    These compounds correspond to the formula I.10:

According to a further preferred embodiment of the compounds I:

-   R¹ C₁-C₈-alkyl, C₂-C₈-alkenyl, C₃-C₈-cycloalkyl or phenyl, where R¹    may carry one, two, three or up to the maximum possible number of    identical or different groups R^(a) which are not heterocyclic    groups;-   R² is C₁-C₈-alkyl or phenyl, where R² may carry one, two, three or    up to the maximum possible number of identical or different groups    R^(a);    -   R^(a) is halogen, C₁-C₄-alkyl, C₁-C₄-haloalkyl, C₁-C₄-alkoxy,        C₁-C₄-haloalkoxy, phenyl or pyridyl;    -    where the cyclic groups R^(a) may be attached directly or via        an oxygen atom and/or for their part may be partially or fully        halogenated and/or may carry one, two, three or up to the        maximum possible number of identical or different groups R^(b):        -   R^(b) is halogen, C₁-C₄-alkyl, C₁-C₄-haloalkyl, C₁-C₄-alkoxy            or C₁-C₄-haloalkoxy; and-   R³,R⁴ independently of one another are hydrogen, C₁-C₄-alkyl or    C₁-C₈-haloalkyl;-   R⁵,R⁶ are C₁-C₄-alkyl;-   R⁷ is hydrogen;-   L¹, L² independently of one another are halogen or C₁-C₄-alkyl;-   L³, L⁴ are hydrogen; and-   X is oxygen.    These compounds correspond to the formula I.10.

With a view to their intended use, preference is given in particular tothe compounds of the formula I compiled in tables 1 to 2655250 below inwhich the definitions for the substituents R¹ are selected from groupsI-1 to I-19 in table I, the definitions for R² are selected from groupsII-1 to II-325 in table II, the definitions for R⁵ and R⁶ are selectedfrom the combinations III-1 to III-43 in table III and the definitionsfor L¹, L², L³ and L⁴ are selected from the combinations A-1 to A-386 oftable A and additionally the definitions of X, R³ and R⁴ correspond tothose in the subformulae I.3A to I.3E. The groups mentioned for asubstituent in the tables are furthermore per se, independently of thecombination in which they are mentioned, a particularly preferredembodiment of the substituent in question.

Table 1. Compounds of the formula I.3A in which R⁷ is hydrogen and R²corresponds to row II-1 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 2. Compounds of the formula I.3A in which R⁷ is hydrogen and R²corresponds to row II-2 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 3. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-3 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 4. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-4 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 5. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-5 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 6. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-6 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 7. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-7 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 8. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-8 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 9. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-9 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 10. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-10 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 11. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-11 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 12. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-12 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 13. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-13 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 14. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-14 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 15. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-15 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 16. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-16 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 17. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-17 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 18. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-18 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 19. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-19 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 20. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-20 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 21. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-21 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 22. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-22 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 23. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-23 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 24. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-24 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 25. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-25 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 26. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-26 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of fable A.

Table 27. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-27 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 28. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-28 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 29. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-29 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 30. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-30 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 31. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-31 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 32. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-32 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 33. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-33 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 34. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-34 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 35. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-35 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 36. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-36 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 37. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-37 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 38. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-38 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 39. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-39 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 40. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-40 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 41. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-41 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 42. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-42 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 43. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-43 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 44. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-44 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 45. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-45 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 46. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-46 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 47. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-47 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 48. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-48 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 49. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-49 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 50. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-50 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 51. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-51 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 52. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-52 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 53. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-53 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 54. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-54 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 55. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-55 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 56. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-56 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 57. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-57 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 58. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-58 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 59. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-59 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 60. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-60 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 61. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-61 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 62. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-62 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 63. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-63 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 64. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-64 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 65. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-65 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 66. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-66 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 67. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-67 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 68. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-68 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 69. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-69 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 70. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-70 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 71. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-71 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 72. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-72 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 73. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-73 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 74. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-74 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals. L¹, L², L³ and L⁴ fora compound corresponds in each case to one row of table A.

Table 75. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-75 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 76. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-76 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 77. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-77 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 78. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-78 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 79. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-79 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 80. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-80 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 81. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-81 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 82. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-82 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 83. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-83 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 84. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-84 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 85. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-85 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 86. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-86 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 87. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-87 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 88. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-88 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 89. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-89 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 90. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-90 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 91. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-91 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 92. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-92 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 93. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-93 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 94. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-94 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 95. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-95 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 96. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-96 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 97. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-97 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 98. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-98 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 99. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-99 of table II, R¹ corresponds to row I-1 of tableII, the combination of the radicals R³ and R⁴ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 100. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-100 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R³ and R⁴ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 101. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-101 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R³ and R⁴ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 102. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-102 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R³ and R⁴ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 103. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-103 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R³ and R⁴ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 104. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-104 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R³ and R⁴ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 105. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-105 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R³ and R⁴ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 106. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-106 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R³ and R⁴ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 107. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-107 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R³ and R⁴ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 108. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-108 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R³ and R⁴ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 109. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-109 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R³ and R⁴ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 110. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-110 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R³ and R⁴ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 111. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-111 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R³ and R⁴ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 112. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-112 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R³ and R⁴ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 113. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-113 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R³ and R⁴ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 114. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-114 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R³ and R⁴ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 115. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-115 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R³ and R⁴ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 116. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-116 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R³ and R⁴ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 117. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-117 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R³ and R⁴ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 118. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-118 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R³ and R⁴ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 119. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-119 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R³ and R⁴ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 120. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-120 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R³ and R⁴ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 121. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-121 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R³ and R⁴ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 122. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-122 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R³ and R⁴ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 123. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-123 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R³ and R⁴ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 124. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-124 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R³ and R⁴ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 125. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-125 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R³ and R⁴ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 126. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-126 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R³ and R⁴ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 127. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-127 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R³ and R⁴ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 128. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-128 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R³ and R⁴ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 129. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-129 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R³ and R⁴ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 130. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-130 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R³ and R⁴ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 131. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-131 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R³ and R⁴ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 132. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-132 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R³ and R⁴ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 133. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-133 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R³ and R⁴ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 134. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-134 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R³ and R⁴ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 135. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-135 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R³ and R⁴ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 136. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-136 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R³ and R⁴ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 137. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-137 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R³ and R⁴ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 138. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-138 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R³ and R⁴ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 139. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-139 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R³ and R⁴ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 140. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-140 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R³ and R⁴ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 141. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-141 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R³ and R⁴ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 142. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-142 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R³ and R⁴ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 143. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-143 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R³ and R⁴ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 144. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-144 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 145. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-145 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 146. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-146 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 147. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-147 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 148. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-148 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 149. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-149 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 150. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-150 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 151. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-151 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 152. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-152 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 153. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-153 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 154. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-154 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 155. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-155 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 156. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-156 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 157. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-157 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 158. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-158 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 159. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-159 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 160. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-160 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 161. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-161 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 162. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-162 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 163. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-163 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 164. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-164 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals. L¹, L², L³ andL⁴ for a compound corresponds in each case to one row of table A.

Table 165. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-165 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 166. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-166 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 167. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-167 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 168. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-168 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 169. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-169 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 170. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-170 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 171. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-171 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 172. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-172 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 173. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-173 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 174. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-174 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 175. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-175 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 176. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-176 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 177. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-177 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 178. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-178 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 179. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-179 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 180. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-180 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 181. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-181 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 182. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-182 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 183. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-183 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 184. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-184 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 185. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-185 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 186. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-186 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 187. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-187 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 188. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-188 of table II, R¹ corresponds to row I-1 oftable. II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 189. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-189 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 190. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-190 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 191. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-191 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 192. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-192 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 193. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-193 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 194. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-194 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 195. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-195 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 196. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-196 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 197. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-197 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 198. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-198 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 199. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-199 of table II; R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 200. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-200 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 201. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-201 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table. A.

Table 202. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-202 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 203. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-203 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 204. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-204 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 205. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-205 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 206. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-206 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 207. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-207 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 208. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-208 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 209. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-209 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 210. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-210 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 211. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-211 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 212. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-212 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 213. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-213 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 214. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-214 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 215. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-215 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 216. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-216 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 217. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-217 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 218. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-218 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 219. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-219 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 220. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-220 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 221. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-221 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 222. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-222 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 223. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-223 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 224. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-224 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 225. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-225 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 226. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-226 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 227. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-227 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 228. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-228 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 229. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-229 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 230. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-230 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 231. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-231 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 232. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-232 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 233. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-233 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 234. Compounds, of the formula I.3A, in which R⁷ is hydrogen andR² corresponds to row II-234 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 235. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-235 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 236. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-236 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 237. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-237 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 238. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-238 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 239. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-239 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 240. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-240 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 241. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-241 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 242. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-242 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 243. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-243 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 244. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-244 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 245. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-245 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 246. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-246 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 247. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-247 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 248. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-248 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 249. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-249 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 250. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-250 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 251. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-251 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 252. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-252 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 253. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-253 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 254. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-254 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 255. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-255 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 256. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-256 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 257. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-257 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 258. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-258 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 259. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-259 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 260. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-260 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 261. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-261 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 262. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-262 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 263. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-263 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 264. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-264 of table II, R¹ corresponds to row. I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 265. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-265 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 266. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-266 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 267. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-267 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radical L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 268. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-268 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 269. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-269 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 270. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-270 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 271. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-271 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 272. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-272 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 273. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-273 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 274. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-274 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 275. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-275 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 276. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-276 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 277. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-277 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 278. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-278 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 279. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-279 of table II, R¹ corresponds to row I-1 oftable the combination of the radicals R⁵ and R⁶ corresponds to row III-1of table III and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Table 280. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-280 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 281. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-281 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 282. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-282 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 283. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-283 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 284. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-284 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 285. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-285 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 286. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-286 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 287. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-287 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 288. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-288 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 289. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-289 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 290. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-290 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 291. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-291 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 292. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-292 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 293. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-293 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 294. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-294 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 295. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-295 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 296. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-296 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 297. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-297 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 298. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-298 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 299. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-299 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 300. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-300 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 301. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-301 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 302. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-302 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 303. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-303 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 304. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-304 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 305. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-305 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 306. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-306 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 307. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-307 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 308. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-308 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 309. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-309 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 310. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-310 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 311. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-311 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 312. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-312 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals. L¹, L², L³ andL⁴ for a compound corresponds in each case to one row of table A.

Table 313. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-313 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 314. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-314 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 315. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-315 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 316. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-316 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 317. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-317 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 318. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-318 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 319. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-319 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 320. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-320 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 321. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-321 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 322. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-322 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 323. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-323 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 324. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-324 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Table 325. Compounds of the formula I.3A, in which R⁷ is hydrogen and R²corresponds to row II-325 of table II, R¹ corresponds to row I-1 oftable II, the combination of the radicals R⁵ and R⁶ corresponds to rowIII-1 of table III and the combination of the radicals L¹, L², L³ and L⁴for a compound corresponds in each case to one row of table A.

Tables 326 to 650. Compounds of the formula I.3A, in which R², R⁵, R⁶and R⁷ are as defined in tables 1 to 325, R¹ corresponds to row I-2instead of I-1 in table I and the combination of the radicals L¹, L², L³and L⁴ for a compound corresponds in each case to one row of table A.

Tables 651 to 975. Compounds of the formula I.3A, in which R², R⁵, R⁶and R⁷ are as defined in tables 1 to 325, R¹ corresponds to row I-3instead of I-1 in table I and the combination of the radicals L¹, L², L³and L⁴ for a compound corresponds in each case to one row of table A.

Tables 976 to 1300. Compounds of the formula I.3A, in which R², R⁵, R⁶and R⁷ are as defined in tables 1 to 325, R¹ corresponds to row I-4instead of I-1 in table I and the combination of the radicals L¹, L², L³and L⁴ for a compound corresponds in each case to one row of table A.

Tables 1301 to 1625. Compounds of the formula I.3A, in which R², R⁵, R⁶and R⁷ are as defined in tables 1 to 325, R¹ corresponds to row I-5instead of I-1 in table I and the combination of the radicals L¹, L², L³and L⁴ for a compound corresponds in each case to one row of table A.

Tables 1626 to 1950. Compounds of the formula I.3A, in which R², R⁵, R⁶and R⁷ are as defined in tables 1 to 325, R¹ corresponds to row I-6instead of I-1 in table I and the combination of the radicals L¹, L², L³and L⁴ for a compound corresponds in each case to one row of table A.

Tables 1951 to 2275. Compounds of the formula I.3A, in which R², R⁵, R⁶and R⁷ are as defined in tables 1 to 325, R¹ corresponds to row I-7instead of I-1 in table I and the combination of the radicals L¹, L², L³and L⁴ for a compound corresponds in each case to one row of table A.

Tables 2276 to 2600. Compounds of the formula I.3A, in which R², R⁵, R⁶and R⁷ are as defined in tables 1 to 325, R¹ corresponds to row I-8instead of I-1 in table I and the combination of the radicals L¹, L², L³and L⁴ for a compound corresponds in each case to one row of table A.

Tables 2601 to 2925. Compounds of the formula I.3A, in which R², R⁵, R⁶and R⁷ are as defined in tables 1 to 325, R¹ corresponds to row I-9instead of I-1 in table I and the combination of the radicals L¹, L², L³and L⁴ for a compound corresponds in each case to one row of table A.

Tables 2926 to 3250. Compounds of the formula I.3A, in which R², R⁵, R⁶and R⁷ are as defined in tables 1 to 325, R¹ corresponds to row I-10instead of I-1 in tape I and the combination of the radicals L¹, L², L³and L⁴ for a compound corresponds in each case to one row of table A.

Tables 3251 to 3575. Compounds of the formula I.3A, in which R², R⁵, R⁶and R⁷ are as defined in tables 1 to 325, R¹ corresponds to row I-11instead of I-1 in table I and the combination of the radicals L¹, L², L³and L⁴ for a compound corresponds in each case to one row of table A.

Tables 3576 to 3900. Compounds of the formula I.3A, in which R², R⁵, R⁶and R⁷ are as defined in tables 1 to 325, R¹ corresponds to row I-12instead of I-1 in table I and the combination of the radicals L¹, L², L³and L⁴ for a compound corresponds in each case to one row of table A.

Tables 3901 to 4225. Compounds of the formula I.3A, in which R², R⁵, R⁶and R⁷ are as defined in tables 1 to 325, R¹ corresponds to row I-13instead of I-1 in table I and the combination of the radicals L¹, L², L³and L⁴ for a compound corresponds in each case to one row of table A.

Tables 4226 to 4550. Compounds of the formula I.3A, in which R², R⁵, R⁶and R⁷ are as defined in tables 1 to 325, R¹ corresponds to row I-14instead of I-1 in table I and the combination of the radicals L¹, L², L³and L⁴ for a compound corresponds in each case to one row of table A.

Tables 4551 to 4875. Compounds of the formula I.3A, in which R², R⁵, R⁶and R⁷ are as defined in tables 1 to 325, R¹ corresponds to row I-15instead of I-1 in table I and the combination of the radicals L¹, L², L³and L⁴ for a compound corresponds in each case to one row of table A.

Tables 4876 to 5200. Compounds of the formula I.3A, in which R², R⁵, R⁶and R⁷ are as defined in tables 1 to 325, R¹ corresponds to row I-16instead of I-1 in table I and the combination of the radicals L¹, L², L³and L⁴ for a compound corresponds in each case to one row of table A.

Tables 5201 to 5525. Compounds of the formula I.3A, in which R², R⁵, R⁶and R⁷ are as defined in tables 1 to 325, R¹ corresponds to row I-17instead of I-1 in tableland the combination of the radicals L¹, L², L³and L⁴ for a compound corresponds in each case to one row of table A.

Tables 5526 to 5850. Compounds of the formula I.3A, in which R², R⁵, R⁶and R⁷ are as defined in tables 1 to 325, R¹ corresponds to row I-18instead of I-1 in table I and the combination of the radicals L¹, L², L³and L⁴ for a compound corresponds in each case to one row of table A.

Tables 5851 to 6175. Compounds of the formula I.3A, in which R², R⁵, R⁶and R⁷ are as defined in tables 1 to 325, R¹ corresponds to row I-19instead of I-1 in table I and the combination of the radicals L¹, L², L³and L⁴ for a compound corresponds in each case to one row of table A.

Tables 6176 to 12350. Compounds of the formula I.3A, in which R¹, R² andR⁷ are as defined in tables 1 to 6175, the combination of the radicalsR⁵ and R⁶ corresponds to row III-2 instead of III-1 in table III and thecombination of the radicals L¹, L², L³ and L⁴ for a compound correspondsin each case to one row of table A.

Tables 12351 to 18525. Compounds of the formula I.3A, in which R¹, R²and R⁷ are as defined in tables 1 to 6175, the combination of theradicals R⁵ and R⁶ corresponds to row III-3 instead of III-1 in tableIII and the combination of the radicals L¹, L², L³ and L⁴ for a compoundcorresponds in each case to one row of table A.

Tables 18526 to 24700. Compounds of the formula I.3A, in which R¹, R²and R⁷ are as defined in tables 1 to 6175, the combination of theradicals R⁵ and R⁶ corresponds to row III-4 instead of III-1 in tableIII and the combination of the radicals L¹, L², L³ and L⁴ for a compoundcorresponds in each case to one row of table A.

Tables 24701 to 30875. Compounds of the formula I.3A, in which R¹, R²and R⁷ are as defined in tables 1 to 6175, the combination of theradicals R⁵ and R⁶ corresponds to row III-5 instead of III-1 in tableIII and the combination of the radicals L¹, L², L³ and L⁴ for a compoundcorresponds in each case to one row of table A.

Tables 30876 to 37050. Compounds of the formula I.3A, in which R¹, R²and R⁷ are as defined in tables 1 to 6175, the combination of theradicals R⁵ and R⁶ corresponds to row III-6 instead of III-1 in tableIII and the combination of the radicals L¹, L², L³ and L⁴ for a compoundcorresponds in each case to one row of table A.

Tables 37051 to 43225. Compounds of the formula I.3A, in which R¹, R²and R⁷ are as defined in tables 1 to 6175, the combination of theradicals R⁵ and R⁶ corresponds to row III-7 instead of III-1 in tableIII and the combination of the radicals L¹, L², L³ and L⁴ for a compoundcorresponds in each case to one row of table A.

Tables 43226 to 49400. Compounds of the formula I.3A, in which R¹, R²and R⁷ are as defined in tables 1 to 6175, the combination of theradicals R⁵ and R⁶ corresponds to row III-8 instead of III-1 in tableIII and the combination of the radicals L¹, L², L³ and L⁴ for a compoundcorresponds in each case to one row of table A.

Tables 49401 to 55575. Compounds of the formula I.3A, in which R¹, R²and R⁷ are as defined in tables 1 to 6175, the combination of theradicals R⁵ and R⁶ corresponds to row III-9 instead of III-1 in tableIII and the combination of the radicals L¹, L², L³ and L⁴ for a compoundcorresponds in each case to one row of table A.

Tables 55576 to 61750. Compounds of the formula I.3A, in which R¹, R²and R⁷ are as defined in tables 1 to 6175, the combination of theradicals R⁵ and R⁶ corresponds to row III-10 instead of III-1 in tableIII and the combination of the radicals L¹, L², L³ and L⁴ for a compoundcorresponds in each case to one row of table A.

Tables 61751 to 67925. Compounds of the formula I.3A, in which R¹, R²and R⁷ are as defined in tables 1 to 6175, the combination of theradicals R⁵ and R⁶ corresponds to row III-11 instead of III-1 in tableIII and the combination of the radicals L¹, L², L³ and L⁴ for a compoundcorresponds in each case to one row of table A.

Tables 67926 to 74100. Compounds of the formula I.3A, in which R¹, R²and R⁷ are as defined in tables 1 to 6175, the combination of theradicals R⁵ and R⁶ corresponds to row III-12 instead of III-1 in tableIII and the combination of the radicals L¹, L², L³ and L⁴ for a compoundcorresponds in each case to one row of table A.

Tables 74101 to 80275. Compounds of the formula I.3A, in which R¹, R²and R⁷ are as defined in tables 1 to 6175, the combination of theradicals R⁵ and R⁶ corresponds to row III-13 instead of III-1 in tableIII and the combination of the radicals L¹, L², L³ and L⁴ for a compoundcorresponds in each case to one row of table A.

Tables 80276 to 86450. Compounds of the formula I.3A, in which R¹, R²and R⁷ are as defined in tables 1 to 6175, the combination of theradicals R⁵ and R⁶ corresponds to row III-14 instead of III-1 in tableIII and the combination of the radicals L¹, L², L³ and L⁴ for a compoundcorresponds in each case to one row of table A.

Tables 86451 to 92625. Compounds of the formula I.3A, in which R¹, R²and R⁷ are as defined in tables 1 to 6175, the combination of theradicals R⁵ and R⁶ corresponds to row III-15 instead of III-1 in tableIII and the combination of the radicals L¹, L², L³ and L⁴ for a compoundcorresponds in each case to one row of table A.

Tables 92626 to 98800. Compounds of the formula I.3A, in which R¹, R²and R⁷ are as defined in tables 1 to 6175, the combination of theradicals R⁵ and R⁶ corresponds to row III-16 instead of III-1 in tableIII and the combination of the radicals L¹, L², L³ and L⁴ for a compoundcorresponds in each case to one row of table A.

Tables 98801 to 104975. Compounds of the formula I.3A, in which R¹, R²and R⁷ are as defined in tables 1 to 6175, the combination of theradicals R⁵ and R⁶ corresponds to row III-17 instead of III-1 in tableIII and the combination of the radicals L¹, L², L³ and L⁴ for a compoundcorresponds in each case to one row of table A.

Tables 104976 to 111150. Compounds of the formula I.3A, in which R¹, R²and R⁷ are as defined in tables 1 to 6175, the combination of theradicals R⁵ and R⁶ corresponds to row III-18 instead of III-1 in tableIII and the combination of the radicals L¹, L², L³ and L⁴ for a compoundcorresponds in each case to one row of table A.

Tables 111151 to 117325. Compounds of the formula I.3A, in which R¹, R²and R⁷ are as defined in tables 1 to 6175, the combination of theradicals R⁵ and R⁶ corresponds to row III-19 instead of III-1 in tableIII and the combination of the radicals L¹, L², L³ and L⁴ for a compoundcorresponds in each case to one row of table A.

Tables 117326 to 123500. Compounds of the formula I.3A, in which R¹, R²and R⁷ are as defined in tables 1 to 6175, the combination of theradicals R⁵ and R⁶ corresponds to row III-20 instead of III-1 in tableIII and the combination of the radicals L¹, L², L³ and L⁴ for a compoundcorresponds in each case to one row of table A.

Tables 123501 to 129675. Compounds of the formula I.3A, in which R¹, R²and R⁷ are as defined in tables 1 to 6175, the combination of theradicals R⁵ and R⁶ corresponds to row III-21 instead of III-1 in tableIII and the combination of the radicals L¹, L², L³ and L⁴ for a compoundcorresponds in each case to one row of table A.

Tables 129676 to 135850. Compounds of the formula I.3A, in which R¹, R²and R⁷ are as defined in tables 1 to 6175, the combination of theradicals R⁵ and R⁶ corresponds to row III-22 instead of III-1 in tableIII and the combination of the radicals L¹, L², L³ and L⁴ for a compoundcorresponds in each case to one row of table A.

Tables 135851 to 142025. Compounds of the formula I.3A, in which R¹, R²and R⁷ are as defined in tables 1 to 6175, the combination of theradicals R⁵ and R⁶ corresponds to row III-23 instead of III-1 in tableIII and the combination of the radicals L¹, L², L³ and L⁴ for a compoundcorresponds in each case to one row of table A.

Tables 142026 to 148200. Compounds of the formula I.3A, in which R¹, R²and R⁷ are as defined in tables 1 to 6175, the combination of theradicals R⁵ and R⁶ corresponds to row III-24 instead of III-1 in tableIII and the combination of the radicals L¹, L², L³ and L⁴ for a compoundcorresponds in each case to one row of table A.

Tables 148201 to 154375. Compounds of the formula I.3A, in which R¹, R²and R⁷ are as defined in tables 1 to 6175, the combination of theradicals R⁵ and R⁶ corresponds to row III-25 instead of III-1 in tableIII and the combination of the radicals L¹, L², L³ and L⁴ for a compoundcorresponds in each case to one row of table A.

Tables 154376 to 160550. Compounds of the formula I.3A, in which R¹, R²and R⁷ are as defined in tables 1 to 6175, the combination of theradicals R⁵ and R⁶ corresponds to row III-26 instead of III-1 in tableIII and the combination of the radicals L¹, L², L³ and L⁴ for a compoundcorresponds in each case to one row of table A.

Tables 160551 to 166725. Compounds of the formula I.3A, in which R¹, R²and R⁷ are as defined in tables 1 to 6175, the combination of theradicals R⁵ and R⁶ corresponds to row III-27 instead of III-1 in tableIII and the combination of the radicals L¹, L², L³ and L⁴ for a compoundcorresponds in each case to one row of table A.

Tables 166726 to 172900. Compounds of the formula I.3A, in which R¹, R²and R⁷ are as defined in tables 1 to 6175, the combination of theradicals R⁵ and R⁶ corresponds to row III-28 instead of III-1 in tableIII and the combination of the radicals L¹, L², L³ and L⁴ for a compoundcorresponds in each case to one row of table A.

Tables 172901 to 179075. Compounds of the formula I.3A, in which R¹, R²and R⁷ are as defined in tables 1 to 6175, the combination of theradicals R⁵ and R⁶ corresponds to row III-29 instead of III-1 in tableIII and the combination of the radicals L¹, L², L³ and L⁴ for a compoundcorresponds in each case to one row of table A.

Tables 179076 to 185250. Compounds of the formula I.3A, in which R¹, R²and R⁷ are as defined in tables 1 to 6175, the combination of theradicals R⁵ and R⁶ corresponds to row III-30 instead of III-1 in tableIII and the combination of the radicals L¹, L², L³ and L⁴ for a compoundcorresponds in each case to one row of table A.

Tables 185251 to 191425. Compounds of the formula I.3A, in which R¹, R²and R⁷ are as defined in tables 1 to 6175, the combination of theradicals R⁵ and R⁶ corresponds to row III-31 instead of III-1 in tableIII and the combination of the radicals L¹, L², L³ and L⁴ for a compoundcorresponds in each case to one row of table A.

Tables 191426 to 197600. Compounds of the formula I.3A, in which R¹, R²and R⁷ are as defined in tables 1 to 6175, the combination of theradicals R⁵ and R⁶ corresponds to row III-32 instead of III-1 in tableIII and the combination of the radicals L¹, L², L³ and L⁴ for a compoundcorresponds in each case to one row of table A.

Tables 197601 to 203775. Compounds of the formula I.3A, in which R¹, R²and R⁷ are as defined in tables 1 to 6175, the combination of theradicals R⁵ and R⁶ corresponds to row III-33 instead of III-1 in tableIII and the combination of the radicals L¹, L², L³ and L⁴ for a compoundcorresponds in each case to one row of table A.

Tables 203776 to 209950. Compounds of the formula I.3A, in which R¹, R²and R⁷ are as defined in tables 1 to 6175, the combination of theradicals R⁵ and R⁶ corresponds to row III-34 instead of III-1 in tableIII and the combination of the radicals L¹, L², L³ and L⁴ for a compoundcorresponds in each case to one row of table A.

Tables 209951 to 216125. Compounds of the formula I.3A, in which R¹, R²and R⁷ are as defined in tables 1 to 6175, the combination of theradicals R⁵ and R⁶ corresponds to row III-35 instead of III-1 in tableIII and the combination of the radicals L¹, L², L³ and L⁴ for a compoundcorresponds in each case to one row of table A.

Tables 216126 to 222300. Compounds of the formula I.3A, in which R¹, R²and R⁷ are as defined in tables 1 to 6175, the combination of theradicals R⁵ and R⁶ corresponds to row III-36 instead of III-1 in tableIII and the combination of the radicals L¹, L², L³ and L⁴ for a compoundcorresponds in each case to one row of table A.

Tables 222301 to 228475. Compounds of the formula I.3A, in which R¹, R²and R⁷ are as defined in tables 1 to 6175, the combination of theradicals R⁵ and R⁶ corresponds to row III-37 instead of III-1 in tableIII and the combination of the radicals L¹, L², L³ and L⁴ for a compoundcorresponds in each case to one row of table A.

Tables 228476 to 234650. Compounds of the formula I.3A, in which R¹, R²and R⁷ are as defined in tables 1 to 6175, the combination of theradicals R⁵ and R⁶ corresponds to row III-38 instead of III-1 in tableIII and the combination of the radicals L¹, L², L³ and L⁴ for a compoundcorresponds in each case to one row of table A.

Tables 234651 to 240825. Compounds of the formula I.3A, in which R¹, R²and R⁷ are as defined in tables 1 to 6175, the combination of theradicals R⁵ and R⁶ corresponds to row III-39 instead of III-1 in tableIII and the combination of the radicals L¹, L², L³ and L⁴ for a compoundcorresponds in each case to one row of table A.

Tables 240826 to 247000. Compounds of the formula I.3A, in which R¹, R²and R⁷ are as defined in tables 1 to 6175, the combination of theradicals R⁵ and R⁶ corresponds to row III-40 instead of III-1 in tableIII and the combination of the radicals L¹, L², L³ and L⁴ for a compoundcorresponds in each case to one row of table A.

Tables 247001 to 253175. Compounds of the formula I.3A, in which R¹, R²and R⁷ are as defined in tables 1 to 6175, the combination of theradicals R⁵ and R⁶ corresponds to row III-41 instead of III-1 in tableIII and the combination of the radicals L¹, L², L³ and L⁴ for a compoundcorresponds in each case to one row of table A.

Tables 253176 to 259350. Compounds of the formula I.3A, in which R¹, R²and R⁷ are as defined in tables 1 to 6175, the combination of theradicals R⁵ and R⁶ corresponds to row III-42 instead of III-1 in tableIII and the combination of the radicals L¹, L², L³ and L⁴ for a compoundcorresponds in each case to one row of table A.

Tables 259351 to 265525. Compounds of the formula I.3A, in which R¹, R²and R⁷ are as defined in tables 1 to 6175, the combination of theradicals R⁵ and R⁶ corresponds to row III-43 instead of III-1 in tableIII and the combination of the radicals L¹, L², L³ and L⁴ for a compoundcorresponds in each case to one row of table A.

Tables 265526 to 531050. Compounds of the formula I.3A, in which. R¹,R², R⁵ and R⁶ are as defined in tables 1 to 265525, R⁷ is methyl insteadof hydrogen and the combination of the radicals L¹, L², L³ and L⁴ for acompound corresponds in each case to one row of table A.

Tables 531051 to 1062100. Compounds of the formula I.3B, in which R¹,R², R⁵, R⁶ and R⁷ are as defined in tables 1 to 531050 and thecombination of the radicals L¹, L², L³ and L⁴ for a compound correspondsin each case to one row of table A.

Tables 1062101 to 1593150. Compounds of the formula I.3C, in which R¹,R², R⁵, R⁶ and R⁷ are as defined in tables 1 to 531050 and thecombination of the radicals L¹, L², L³ and L⁴ for a compound correspondsin each case to one row of table A.

Tables 1593151 to 2124200. Compounds of the formula I.3D, in which R¹,R², R⁵, R⁶ and R⁷ are as defined in tables 1 to 531050 and thecombination of the radicals L¹, L², L³ and L⁴ for a compound correspondsin each case to one row of table A.

Tables 2124201 to 2655250. Compounds of the formula I.3E, in which R¹,R², R⁵, R⁶ and R⁷ are as defined in tables 1 to 531050 and thecombination of the radicals L¹, L², L³ and L⁴ for a compound correspondsin each case to one row of table A.

TABLE A Row L¹ L² L³ L⁴ A-1 CH₃ F H H A-2 H H H H A-3 H CH₃ H H A-4 HCH₂CH₃ H H A-5 H CHF₂ H H A-6 H CF₃ H H A-7 H OCHF₂ H H A-8 H OCF₃ H HA-9 H OCH₃ H H A-10 H Cl H H A-11 H Br H H A-12 H F H H A-13 CH₂CH₃ H HH A-14 CH₂CH₃ CH₃ H H A-15 CH₂CH₃ CH₂CH₃ H H A-16 CH₂CH₃ CHF₂ H H A-17CH₂CH₃ CF₃ H H A-18 CH₂CH₃ OCHF₂ H H A-19 CH₂CH₃ OCF₃ H H A-20 CH₂CH₃OCH₃ H H A-21 CH₂CH₃ Cl H H A-22 CH₂CH₃ Br H H A-23 CH₂CH₃ F H H A-24CHF₂ H H H A-25 CHF₂ CH₃ H H A-26 CHF₂ CH₂CH₃ H H A-27 CHF₂ CHF₂ H HA-28 CHF₂ CF₃ H H A-29 CHF₂ OCHF₂ H H A-30 CHF₂ OCF₃ H H A-31 CHF₂ OCH₃H H A-32 CHF₂ Cl H H A-33 CHF₂ Br H H A-34 CHF₂ F H H A-35 CF₃ H H HA-36 CF₃ CH₃ H H A-37 CF₃ CH₂CH₃ H H A-38 CF₃ CHF₂ H H A-39 CF₃ CF₃ H HA-40 CF₃ OCHF₂ H H A-41 CF₃ OCF₃ H H A-42 CF₃ OCH₃ H H A-43 CF₃ Cl H HA-44 CF₃ Br H H A-45 CF₃ F H H A-46 OCHF₂ H H H A-47 OCHF₂ CH₃ H H A-48OCHF₂ CH₂CH₃ H H A-49 OCHF₂ CHF₂ H H A-50 OCHF₂ CF₃ H H A-51 OCHF₂ OCHF₂H H A-52 OCHF₂ OCF₃ H H A-53 OCHF₂ OCH₃ H H A-54 OCHF₂ Cl H H A-55 OCHF₂Br H H A-56 OCHF₂ F H H A-57 OCF₃ H H H A-58 OCF₃ CH₃ H H A-59 OCF₃CH₂CH₃ H H A-60 OCF₃ CHF₂ H H A-61 OCF₃ CF₃ H H A-62 OCF₃ OCHF₂ H H A-63OCF₃ OCF₃ H H A-64 OCF₃ OCH₃ H H A-65 OCF₃ Cl H H A-66 OCF₃ Br H H A-67OCF₃ F H H A-68 OCH₃ H H H A-69 OCH₃ CH₃ H H A-70 OCH₃ CH₂CH₃ H H A-71OCH₃ CHF₂ H H A-72 OCH₃ CF₃ H H A-73 OCH₃ OCHF₂ H H A-74 OCH₃ OCF₃ H HA-75 OCH₃ OCH₃ H H A-76 OCH₃ Cl H H A-77 OCH₃ Br H H A-78 OCH₃ F H HA-79 Cl H H H A-80 Cl CH₃ H H A-81 Cl CH₂CH₃ H H A-82 Cl CHF₂ H H A-83Cl CF₃ H H A-84 Cl OCHF₂ H H A-85 Cl OCF₃ H H A-86 Cl OCH₃ H H A-87 ClCl H H A-88 Cl Br H H A-89 Cl F H H A-90 Br H H H A-91 Br CH₃ H H A-92Br CH₂CH₃ H H A-93 Br CHF₂ H H A-94 Br CF₃ H H A-95 Br OCHF₂ H H A-96 BrOCF₃ H H A-97 Br OCH₃ H H A-98 Br Cl H H A-99 Br Br H H A-100 Br F H HA-101 F H H H A-102 F CH₃ H H A-103 F CH₂CH₃ H H A-104 F CHF₂ H H A-105F CF₃ H H A-106 F OCHF₂ H H A-107 F OCF₃ H H A-108 F OCH₃ H H A-109 F ClH H A-110 F Br H H A-111 F F H H A-112 CH₃ H F H A-113 CH₃ CH₃ F H A-114CH₃ CH₂CH₃ F H A-115 CH₃ CHF₂ F H A-116 CH₃ CF₃ F H A-117 CH₃ OCHF₂ F HA-118 CH₃ OCF₃ F H A-119 CH₃ OCH₃ F H A-120 CH₃ Cl F H A-121 CH₃ Br F HA-122 CH₃ F F H A-123 H H F H A-124 H CH₃ F H A-125 H CH₂CH₃ F H A-126 HCHF₂ F H A-127 H CF₃ F H A-128 H OCHF₂ F H A-129 H OCF₃ F H A-130 H OCH₃F H A-131 H Cl F H A-132 H Br F H A-133 H F F H A-134 CH₂CH₃ H F H A-135CH₂CH₃ CH₃ F H A-136 CH₂CH₃ CH₂CH₃ F H A-137 CH₂CH₃ CHF₂ F H A-138CH₂CH₃ CF₃ F H A-139 CH₂CH₃ OCHF₂ F H A-140 CH₂CH₃ OCF₃ F H A-141 CH₂CH₃OCH₃ F H A-142 CH₂CH₃ Cl F H A-143 CH₂CH₃ Br F H A-144 CH₂CH₃ F F HA-145 CHF₂ H F H A-146 CHF₂ CH₃ F H A-147 CHF₂ CH₂CH₃ F H A-148 CHF₂CHF₂ F H A-149 CHF₂ CF₃ F H A-150 CHF₂ OCHF₂ F H A-151 CHF₂ OCF₃ F HA-152 CHF₂ OCH₃ F H A-153 CHF₂ Cl F H A-154 CHF₂ Br F H A-155 CHF₂ F F HA-156 CF₃ H F H A-157 CF₃ CH₃ F H A-158 CF₃ CH₂CH₃ F H A-159 CF₃ CHF₂ FH A-160 CF₃ CF₃ F H A-161 CF₃ OCHF₂ F H A-162 CF₃ OCF₃ F H A-163 CF₃OCH₃ F H A-164 CF₃ Cl F H A-165 CF₃ Br F H A-166 CF₃ F F H A-167 OCHF₂ HF H A-168 OCHF₂ CH₃ F H A-169 OCHF₂ CH₂CH₃ F H A-170 OCHF₂ CHF₂ F HA-171 OCHF₂ CF₃ F H A-172 OCHF₂ OCHF₂ F H A-173 OCHF₂ OCF₃ F H A-174OCHF₂ OCH₃ F H A-175 OCHF₂ Cl F H A-176 OCHF₂ Br F H A-177 OCHF₂ F F HA-178 OCF₃ H F H A-179 OCF₃ CH₃ F H A-180 OCF₃ CH₂CH₃ F H A-181 OCF₃CHF₂ F H A-182 OCF₃ CF₃ F H A-183 OCF₃ OCHF₂ F H A-184 OCF₃ OCF₃ F HA-185 OCF₃ OCH₃ F H A-186 OCF₃ Cl F H A-187 OCF₃ Br F H A-188 OCF₃ F F HA-189 OCH₃ H F H A-190 OCH₃ CH₃ F H A-191 OCH₃ CH₂CH₃ F H A-192 OCH₃CHF₂ F H A-193 OCH₃ CF₃ F H A-194 OCH₃ OCHF₂ F H A-195 OCH₃ OCF₃ F HA-196 OCH₃ OCH₃ F H A-197 OCH₃ Cl F H A-198 OCH₃ Br F H A-199 OCH₃ F F HA-200 Cl H F H A-201 Cl CH₃ F H A-202 Cl CH₂CH₃ F H A-203 Cl CHF₂ F HA-204 Cl CF₃ F H A-205 Cl OCHF₂ F H A-206 Cl OCF₃ F H A-207 Cl OCH₃ F HA-208 Cl Cl F H A-209 Cl Br F H A-210 Cl F F H A-211 Br H F H A-212 BrCH₃ F H A-213 Br CH₂CH₃ F H A-214 Br CHF₂ F H A-215 Br CF₃ F H A-216 BrOCHF₂ F H A-217 Br OCF₃ F H A-218 Br OCH₃ F H A-219 Br Cl F H A-220 BrBr F H A-221 Br F F H A-222 F H F H A-223 F CH₃ F H A-224 F CH₂CH₃ F HA-225 F CHF₂ F H A-226 F CF₃ F H A-227 F OCHF₂ F H A-228 F OCF₃ F HA-229 F OCH₃ F H A-230 F Cl F H A-231 F Br F H A-232 F F F H A-233 CH₃ HH F A-234 CH₃ CH₃ H F A-235 CH₃ CH₂CH₃ H F A-236 CH₃ CHF₂ H F A-237 CH₃CF₃ H F A-238 CH₃ OCHF₂ H F A-239 CH₃ OCF₃ H F A-240 CH₃ OCH₃ H F A-241CH₃ Cl H F A-242 CH₃ Br H F A-243 CH₃ F H F A-244 H H H F A-245 H CH₃ HF A-246 H CH₂CH₃ H F A-247 H CHF₂ H F A-248 H CF₃ H F A-249 H OCHF₂ H FA-250 H OCF₃ H F A-251 H OCH₃ H F A-252 H Cl H F A-253 H Br H F A-254 HF H F A-255 CH₂CH₃ H H F A-256 CH₂CH₃ CH₃ H F A-257 CH₂CH₃ CH₂CH₃ H FA-258 CH₂CH₃ CHF₂ H F A-259 CH₂CH₃ CF₃ H F A-260 CH₂CH₃ OCHF₂ H F A-261CH₂CH₃ OCF₃ H F A-262 CH₂CH₃ OCH₃ H F A-263 CH₂CH₃ Cl H F A-264 CH₂CH₃Br H F A-265 CH₂CH₃ F H F A-266 CHF₂ H H F A-267 CHF₂ CH₃ H F A-268 CHF₂CH₂CH₃ H F A-269 CHF₂ CHF₂ H F A-270 CHF₂ CF₃ H F A-271 CHF₂ OCHF₂ H FA-272 CHF₂ OCF₃ H F A-273 CHF₂ OCH₃ H F A-274 CHF₂ Cl H F A-275 CHF₂ BrH F A-276 CHF₂ F H F A-277 CF₃ H H F A-278 CF₃ CH₃ H F A-279 CF₃ CH₂CH₃H F A-280 CF₃ CHF₂ H F A-281 CF₃ CF₃ H F A-282 CF₃ OCHF₂ H F A-283 CF₃OCF₃ H F A-284 CF₃ OCH₃ H F A-285 CF₃ Cl H F A-286 CF₃ Br H F A-287 CF₃F H F A-288 OCHF₂ H H F A-289 OCHF₂ CH₃ H F A-290 OCHF₂ CH₂CH₃ H F A-291OCHF₂ CHF₂ H F A-292 OCHF₂ CF₃ H F A-293 OCHF₂ OCHF₂ H F A-294 OCHF₂OCF₃ H F A-295 OCHF₂ OCH₃ H F A-296 OCHF₂ Cl H F A-297 OCHF₂ Br H FA-298 OCHF₂ F H F A-299 OCF₃ H H F A-300 OCF₃ CH₃ H F A-301 OCF₃ CH₂CH₃H F A-302 OCF₃ CHF₂ H F A-303 OCF₃ CF₃ H F A-304 OCF₃ OCHF₂ H F A-305OCF₃ OCF₃ H F A-306 OCF₃ OCH₃ H F A-307 OCF₃ Cl H F A-308 OCF₃ Br H FA-309 OCF₃ F H F A-310 OCH₃ H H F A-311 OCH₃ CH₃ H F A-312 OCH₃ CH₂CH₃ HF A-313 OCH₃ CHF₂ H F A-314 OCH₃ CF₃ H F A-315 OCH₃ OCHF₂ H F A-316 OCH₃OCF₃ H F A-317 OCH₃ OCH₃ H F A-318 OCH₃ Cl H F A-319 OCH₃ Br H F A-320OCH₃ F H F A-321 Cl H H F A-322 Cl CH₃ H F A-323 Cl CH₂CH₃ H F A-324 ClCHF₂ H F A-325 Cl CF₃ H F A-326 Cl OCHF₂ H F A-327 Cl OCF₃ H F A-328 ClOCH₃ H F A-329 Cl Cl H F A-330 Cl Br H F A-331 Cl F H F A-332 Br H H FA-333 Br CH₃ H F A-334 Br CH₂CH₃ H F A-335 Br CHF₂ H F A-336 Br CF₃ H FA-337 Br OCHF₂ H F A-338 Br OCF₃ H F A-339 Br OCH₃ H F A-340 Br Cl H FA-341 Br Br H F A-342 Br F H F A-343 F H H F A-344 F CH₃ H F A-345 FCH₂CH₃ H F A-346 F CHF₂ H F A-347 F CF₃ H F A-348 F OCHF₂ H F A-349 FOCF₃ H F A-350 F OCH₃ H F A-351 F Cl H F A-352 F Br H F A-353 F F H FA-354 CH₃ CH₃ H CH₃ A-355 CH₃ CH₃ CH₃ H A-356 CHF₂ CH₃ H CH₃ A-357 CH₃CHF₂ CH₃ H A-358 CF₃ CH₃ H CH₃ A-359 CH₃ CF₃ CH₃ H A-360 OCHF₂ CH₃ H CH₃A-361 CH₃ OCHF₂ CH₃ H A-362 CHF₂ CH₃ H Cl A-363 CH₃ CHF₂ Cl H A-364 CF₃CH₃ H Cl A-365 CH₃ CF₃ Cl H A-366 OCHF₂ CH₃ H Cl A-367 CH₃ OCHF₂ Cl HA-368 CH₃ CH₃ H Cl A-369 CH₃ CH₃ Cl H A-370 OCH₃ H OCH₃ H A-371 OCH₃ CH₃OCH₃ H A-372 OCH₃ CH₂CH₃ OCH₃ H A-373 OCH₃ CHF₂ OCH₃ H A-374 OCH₃ CF₃OCH₃ H A-375 OCH₃ OCHF₂ OCH₃ H A-376 OCH₃ OCF₃ OCH₃ H A-377 OCH₃ OCH₃OCH₃ H A-378 OCH₃ Cl OCH₃ H A-379 OCH₃ Br OCH₃ H A-380 OCH₃ F OCH₃ HA-381 OCHF₂ H OCHF₂ H A-382 OCHF₂ CH₃ OCHF₂ H A-383 OCHF₂ OCHF₂ OCHF₂ HA-384 OCHF₂ Cl OCHF₂ H A-385 OCHF₂ Br OCHF₂ H A-386 OCHF₂ F OCHF₂ H

The compounds of the formula I and, respectively, the compositionsaccording to the invention are suitable as fungicides for controllingharmful fungi. They are distinguished by excellent activity against abroad spectrum of phytopathogenic fungi including soilborne pathogenswhich originate in particular from the classes of thePlasmodiophoramycetes, Peronosporomycetes (syn. Oomycetes),Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes andDeuteromycetes (syn. Fungi imperfecti). Some of them are systemicallyactive and can be used in crop protection as foliar fungicides,fungicides for seed dressing and soil fungicides. In addition, they aresuitable for controlling fungi which, inter alia, attack the wood or theroots of plants.

The compounds I and the compositions according to the invention are ofparticular importance for the control of a large number of pathogenicfungi on various crop plants such as cereals, for example wheat, rye,barley, triticale, oats or rice; beets, for example sugar beets orfodder beets; pomaceous fruits, stone fruits and soft fruits, forexample apples, pears, plums, peaches, almonds, cherries, strawberries,raspberries, currents or gooseberries; leguminous-plants, for examplebeans, lentils, peas, lucerne or soybeans; oil plants, for exampleoilseed rape, mustard, olives, sunflowers, coconut, cocoa, castor beans,oil palms, peanuts or soybeans; cucurbits, for example pumpkins,cucumbers or melons; fiber plants, for example cotton, flax, hemp orjute; citrus fruits, for example oranges, lemons, grapefruits ormandarins; vegetable plants, for example spinach, lettuce, asparagus,cabbage plants, carrots, onions, tomatoes, potatoes, pumpkins or bellpeppers; laurel plants, for example avocados, cinnamon or camphor;energy and raw material plants, for example corn, soybeans, wheat,oilseed rape, sugar cane or oil palms; corn; tobacco; nuts; coffee; tea;bananas; grape vines (grapes for eating and grapes for wine making);hops; grass, for example lawns; rubber plants; ornamental and forestplants, for example flowers, shrubs, deciduous trees and coniferoustrees, and also on the propagation material, for example seeds, and onthe harvested material of these plants.

Preferably, the compounds I and the compositions according to theinvention are used for controlling a large number of fungal pathogens inagricultural crops, for example potatoes, sugar beets, tobacco, wheat,rye, barley, oats, rice, corn, cotton, soybeans, oilseed rape,leguminous plants, sunflowers, coffee or sugarcane; fruit plants,grapevines and ornamental plants and vegetables, for example cucumbers,tomatoes, beans and cucurbits and also on the propagation material, forexample seeds, and the harvested products of these plants.

The term “plant propagation materials” includes all generative parts ofthe plant, for example seeds, and vegetative plant parts, such asseedlings and tubers (for example potatoes) which can be utilized forpropagating a plant. These include seeds, roots, fruits, tubers, bulbs,rhizomes, shoots and other plant parts including seedlings and youngplants which are transplanted after germination or after emergence. Theyoung plants can be protected by partial or complete treatment, forexample by immersion or watering, against harmful fungi.

The treatment of plant propagation materials with compounds I or thecompositions according to the invention is used for controlling a largenumber of fungal pathogens in cereal crops, for example wheat, rye,barley or oats; rice, corn, cotton and soybeans.

The term crop plants also includes those plants which have been modifiedby breeding, mutagenesis or genetic engineering methods including thebiotechnological agricultural products which are on the market or underdevelopment (see, for example,http://www.bio.org/speeches/pubs/er/agri_products.asp). Geneticallymodified plants are plants whose genetic material has been modified in amanner which does not occur under natural conditions by crossing,mutations or by natural recombination (that is a recombination of thegenetic information). In general, one or more genes are integrated intothe genetic material of the plant in order to improve the properties ofthe plant. Such modifications by genetic engineering includepost-translational modifications of proteins, oligopeptides orpolypeptides, for example by glycosylation or attachment of polymerssuch as, for example, prenylated, acetylated or farnesylated radicals orPEG radicals.

By way of example, mention may be made of plants which, by breeding andgenetic engineering, are tolerant to certain classes of herbicides, suchas hydroxyphenylpyruvate dioxygenase (HPPD) inhibitors, acetolactatesynthase (ALS) inhibitors, such as, for example, sulfonylureas (EP-A 257993, U.S. Pat. No. 5,013,659) or imidazolinones (for example U.S. Pat.No. 6,222,100, WO 01/82685, WO 00/26390, WO 97/41218, WO 98/02526, WO98/02527, WO 04/106529, WO 05/20673, WO 03/14357, WO 03/13225, WO03/14356, WO 04/16073), enolpyruvylshikimate 3-phosphate synthase(EPSPS) inhibitors, such as, for example, glyphosate (see, for example,WO 92/00377), glutamine synthetase (GS) inhibitors, such as, forexample, gluphosinate (see, for example, EP-A 242 236, EP-A 242 246) oroxynil herbicides (see, for example, U.S. Pat. No. 5,559,024).Clearfield® oilseed rape (BASF SE, Germany), for example, which istolerant to imidazolinones, for example imazamox, was generated bybreeding and mutagenesis. With the aid of genetic engineering methods,crop plants such as soybeans, cotton, corn, beets and oilseed rape weregenerated which are resistant to glyphosate or glufosinate, and whichare obtainable under the trade names RoundupReady®(glyphosate-resistant, Monsanto, U.S.A.) and Liberty Link®(glufosinate-resistant, Bayer CropScience, Germany).

Also included are plants which, owing to interventions by geneticengineering, produce one or more toxins, for example those of thebacterial strain Bacillus. Toxins which are produced by such geneticallymodified plants include, for example, insecticidal proteins of Bacillusspp., in particular B. thuringiensis, such as the endotoxins Cry1Ab,Cry1Ac, Cry1F, Cry1Fa2, Cry2Ab, Cry3A, Cry3Bb1, Cry9c, Cry34Ab1 orCry35Ab1; or vegetative insecticidal proteins (VIPs), for example VIP1,VIP2, VIP3, or VIP3A; insecticidal proteins of nematode-colonizingbacteria, for example Photorhabdus spp. or Xenorhabdus spp.; toxins ofanimal organisms, for example wasp, spider or scorpion toxins; fungaltoxins, for example from Streptomycetes; plant lectins, for example frompeas or barley; agglutinins; protease inhibitors, for example trypsininhibitors, serine protease inhibitors, patatin, cystatin or papaininhibitors; ribosome-inactivating proteins (RIPs), for example ricin,corn-RIP, abrin, luffin, saporin or bryodin; steroid-metabolizingenzymes, for example 3-hydroxysteroid oxidase, ecdysteroid-IDP glycosyltransferase, cholesterol oxidase, ecdyson inhibitors, or HMG-CoAreductase; ion channel blockers, for example inhibitors of sodiumchannels or calcium channels; juvenile hormone esterase; receptors ofthe diuretic hormone (helicokinin receptors); stilbene synthase,bibenzyl synthase, chitinases and glucanases. In the plants, thesetoxins may also be produced as pretoxins, hybrid proteins or truncatedor otherwise modified proteins. Hybrid proteins are characterized by anovel combination of different protein domains (see, for example, WO2002/015701). Further examples of such toxins or genetically modifiedplants which produce these toxins are disclosed in EP-A 374 753, WO93/07278, WO 95/34656, EP-A 427 529, EP-A 451 878, WO 03/18810 and WO03/52073. The methods for producing these genetically modified plantsare known to the person skilled in the art and disclosed, for example,in the publications mentioned above. Many of the toxins mentioned abovebestow, upon the plants by which they are produced, tolerance to pestsfrom all taxonomic classes of arthropods, in particular to beetles(Coeleropta), dipterans (Diptera) and butterflies (Lepidoptera) and tonematodes (Nematoda). Genetically modified plants which produce one ormore genes coding for insecticidal toxins are described, for example, inthe publications mentioned above, and some of them are commerciallyavailable, such as, for example, YieldGard® (corn varieties producingthe toxin Cry1Ab), YieldGard® Plus (corn varieties which produce thetoxins Cry1Ab and Cry3Bb1), Starlink® (corn varieties which produce thetoxin Cry9c), Herculex® RW (corn varieties which produce the toxinsCry34Ab1, Cry35Ab1 and the enzyme phosphinothricin-N-acetyltransferase[PAT]); NuCOTN® 33B (cotton varieties which produce the toxin Cry1Ac),Bollgard® I (cotton varieties which produce the toxin Cry1Ac), Bollgard®II (cotton varieties which produce the toxins Cry1Ac and Cry2Ab2);VIPCOT® (cotton varieties which produce a VIP toxin); NewLeaf® (potatovarieties which produce the toxin Cry3A); Bt-Xtra®, NatureGard®,KnockOut®, BiteGard®, Protecta®, Bt11 (for example Agrisure® CB) andBt176 from Syngenta Seeds SAS, France (corn varieties which produce thetoxin Cry1Ab and the PAT enyzme), MIR604 from Syngenta Seeds SAS, France(corn varieties which produce a Modified version of the toxin Cry3A, seeWO 03/018810), MON 863 from Monsanto Europe S.A., Belgium (cornvarieties which produce the toxin Cry3Bb1), IPC 531 from Monsanto EuropeS.A., Belgium (cotton varieties which produce a modified version of thetoxin Cry1Ac) and 1507 from Pioneer Overseas Corporation, Belgium (cornvarieties which produce the toxin Cry1F and the PAT enzyme).

Also included are plants which, with the aid of genetic engineering,produce one or more proteins which are more robust or have increasedresistance to bacterial, viral or fungal pathogens, such as, forexample, pathogenesis-related proteins (PR proteins, see EP-A 0 392225), resistance proteins (for example potato varieties producing tworesistance genes against Phytophthora infestans from the wild Mexicanpotato Solanum bulbocastanum) or T4 lysozyme (for example potatovarieties which, by producing this protein, are resistant to bacteriasuch as Erwinia amylvora).

Also included are plants whose productivity has been improved with theaid of genetic engineering methods, for example by enhancing thepotential yield (for example biomass, grain yield, starch, oil orprotein content), tolerance to drought, salt or other limitingenvironmental factors or resistance to pests and fungal, bacterial andviral pathogens.

Also included are plants whose ingredients have been modified with theaid of genetic engineering methods in particular for improving human oranimal diet, for example oil plants producing health-promotinglong-chain omega 3 fatty acids or monounsaturated omega 9 fatty acids(for example Nexera® oilseed rape, DOW Agro Sciences, Canada).

Also included are plants which have been modified with the aid ofgenetic engineering methods for improving the production of rawmaterials, for example by increasing the amylopectin content of potatoes(Amflora® potato, BASF SE, Germany).

Specifically, the compounds I and, respectively, the compositionsaccording to the invention are suitable for controlling the followingplant diseases:

Albugo spp. (white rust) on ornamental plants, vegetable crops (forexample A. candida) and sunflowers (for example A. tragopogonis);Alternaria spp. (black spot disease, black blotch) on vegetables,oilseed rape (for example A. brassicola or A. brassicae), sugar beet(for example A. tenuis), fruit, rice, soybeans and also on potatoes (forexample A. solani or A. alternata) and tomatoes (for example A. solanior A. alternata) and Alternaria spp. (black head) on wheat; Aphanornycesspp. on sugar beet and vegetables; Ascochyta spp. on cereals andvegetables, for example A. tritici (Ascochyta leaf blight) on wheat andA. hordei on barley; Bipolaris and Drechslera spp. (teleomorph:Cochliobolus spp.) for example leaf spot diseases (D. maydis and B.zeicola) on corn, for example glume blotch (B. sorokiniana) on cerealsand B. oryzae on rice and on lawn; Blumeria (old name: Erysiphe)graminis (powdery mildew) on cereals (for example wheat or barley);Botryosphaeria spp. (‘Black Dead Arm Disease’) on grapevines (forexample B. obtusa); Botrytis cinerea (teleomorph: Botryotiniafuckeliana: gray mold, gray rot) on soft fruit and pomp fruit (interalia strawberries), vegetables (inter alia lettuce, carrots, celeriacand cabbage), oilseed rape, flowers, grapevines, forest crops and wheat(ear mold); Bremia lactucae (downy mildew) on lettuce; Ceratocystis(syn. Ophiostoma) spp. (blue stain fungus) on deciduous trees andconiferous trees, for example C. ulmi (Dutch elm disease) on elms;Cercospora spp. (Cercospora leaf spot) on corn (for example C.zeae-maydis), rice, sugar beet (for example C. beticola), sugar cane,vegetables, coffee, soybeans (for example C. sojina or C. kikuchii) andrice; Cladosporium spp. on tomato (for example C. fulvum: tomato leafmold) and cereals, for example C. herbarum (ear rot) on wheat; Clavicepspurpurea (ergot) on cereals; Cochliobolus (anamorph: Helminthosporium orBipolaris) spp. (leaf spot) on corn (for example C. carbonum), cereals(for example C. sativus, anamorph: B. sorokiniana: glume blotch) andrice (for example C. miyabeanus, anamorph: H. oryzae); Colletotrichum(teleomorph: Glomerella) spp. (anthracnosis) on cotton (for example C.gossypii), corn (for example C. graminicola: stem rot and anthracnosis),soft fruit, potatoes (for example C. coccodes: wilt disease), beans (forexample C. lindemuthianum) and soybeans (for example C. truncatum);Corticium spp., for example C. sasakii (sheath blight) on rice;Corynespora cassiicola (leaf spot) on soybeans and ornamental plants;Cycloconium spp., for example C. oleaginum on olive; Cylindrocarpon spp.(for example fruit tree cancer or black foot disease of grapevine,teleomorph: Nectria or Neonectria spp.) on fruit trees, grapevines (forexample C. liriodendri; teleomorph: Neonectria liriodendri, black footdisease) and many ornamental trees; Dematophora (teleomorph: Rosellinia)necatrix (root/stem rot) on soybeans; Diaporthe spp. for example D.phaseolorum (stem disease) on soybeans; Drechslera (syn.Helminthosporium, teleomorph: Pyrenophora) spp. on corn, cereals, suchas barley (for example D. teres, net blotch) and on wheat (for exampleD. tritici-repentis: DTR leaf spot), rice and lawn; esca disease(dieback of grapevine, apoplexia) on grapevines, caused by Formitiporia(syn. Phellinus) punctata, F. mediterranea, Phaeomoniella chlamydospora(old name Phaeoacremonium chlamydosporum), Phaeoacremonium aleophilumand/or Botryosphaeria obtuse; Elsinoe spp. on pome fruit (E. pyri) andsoft fruit (E. veneta: anthracnosis) and also grapevines (E. ampelina:anthracnosis); Entyloma oryzae (leaf smut) on rice; Epicoccum spp.(black head) on wheat; Erysiphe spp. (powdery mildew) on sugar beet (E.betae), vegetables (for example E. pisi) such as cucumber species (forexample E. cichoracearum) and cabbage species, such as oilseed rape (forexample E. cruciferarum); Eutypa lata (Eutypa cancer or dieback,anamorph: Cytosporina lata, syn. Libertella blepharis) on fruit trees,grapevines and many ornamental trees; Exserohilum (syn.Helminthosporium) spp. on corn (for example E. turcicum); Fusarium(teleomorph: Gibberella) spp. (wilt disease, root and stem rot) onvarious plants, such as for example F. graminearum or F. culmorum (rootrot and silver-top) on cereals (for example wheat or barley), F.oxysporum on tomatoes, F. solani on soybeans and F. verticillioides oncorn; Gaeumannomyces graminis (take-all) on cereals (for example wheator barley) and corn; Gibberella spp. on cereals (for example G. zeae)and rice (for example G. fujikuroi: bakanae disease); Glomerellacingulata on grapevines, pome fruit and other plants and G. gossypii oncotton; Grainstaining complex on rice; Guignardia bidwellii (black rot)on grapevines; Gymnosporangium spp. on Rosaceae and juniper, for exampleG. sabinae (pear rust) on pears; Helminthosporium spp. (syn. Drechslera,teleomorph: Cochliobolus) on corn, cereals and rice; Hemileia spp., forexample H. vastatrix (coffee leaf rust) on coffee; Isariopsis clavispora(syn. Cladosporium vitis) on grapevines; Macrophomina phaseolina (syn.phaseoli) (root/stem rot) on soybeans and cotton; Microdochium (syn.Fusarium) nivale (pink snow mold) on cereals (for example wheat orbarley); Microsphaera diffusa (powdery mildew) on soybeans; Moniliniaspp., for example M. laxa, M. fructicola and M. fructigena (blossom andtwig blight) on stone fruit and other Rosaceae; Mycosphaerella spp. oncereals, bananas, soft fruit and peanuts, such as for example M.graminicola (anamorph: Septoria tritici, Septoria leaf blotch) on wheator M. fijiensis (sigatoka disease) on bananas; Peronospora spp. (downymildew) on cabbage (for example P. brassicae), oilseed rape (for exampleP. parasitica), bulbous plants (for example P. destructor), tobacco (P.tabacina) and soybeans (for example P. manshurica); Phakopsorapachyrhizi and P. meibomiae (soybean rust) on soybeans; Phialophora spp.for example on grapevines (for example P. tracheiphila and P.tetraspora) and soybeans (for example P. gregata: stem disease); Phomalingam (root and stem rot) on oilseed rape and cabbage and P. betae(leaf spot) on sugar beet; Phomopsis spp. on sunflowers, grapevines (forexample P. viticola: dead-arm disease) and soybeans (for example stemcanker/stem blight: P. phaseoli, teleomorph: Diaporthe phaseolorum);Physoderma maydis (brown spot) on corn; Phytophthora spp. (wilt disease,root, leaf, stem and fruit rot) on various plants, such as on bellpeppers and cucumber species (for example P. capsici), soybeans (forexample P. megasperma, syn. P. sojae), potatoes and tomatoes (forexample P. infestans: late blight and brown rot) and deciduous trees(for example P. ramorum: sudden oak death); Plasmodiophora brassicae(club-root) on cabbage, oilseed rape, radish and other plants;Plasmopara spp., for example P. viticola (peronospora of grapevines,downy mildew) on grapevines and P. halstedii on sunflowers; Podosphaeraspp. (powdery mildew) on Rosaceae, hops, pome fruit and soft fruit, forexample P. leucotricha on apple; Polymyxa spp., for example on cereals,such as barley and wheat (P. graminis) and sugar beet (P. betae) and theviral diseases transmitted thereby; Pseudocercosporella herpotrichoides(eyespot/stem break, teleomorph: Tapesia yallundae) on cereals, forexample wheat or barley; Pseudoperonospora (downy mildew) on variousplants, for example P. cubensis on cucumber species or P. humili onhops; Pseudopezicula tracheiphila (angular leaf scorch, anamorph:Phialophora) on grapevines; Puccinia spp. (rust disease) on variousplants, for example P. triticana (also brown rust of wheat), P.striiformis (yellow rust), P. hordei (dwarf leaf rust of barley), P.graminis (black rust) or P. recondita (brown rust of rye) on cereals,such as for example wheat, barley or rye, and on asparagus (for exampleP. asparagi); Pyrenophora (anamorph: Drechslera) tritici-repentis(speckled leaf blotch) on wheat and P. teres (net blotch) on barley;Pyricularia spp., for example P. oryzae (teleomorph: Magnaporthe grisea,rice blast) on rice and P. grisea on lawn and cereals; Pythium spp.(damping-off disease) on lawn, rice, corn, wheat, cotton, oilseed rape,sunflowers, sugar beet, vegetables and other plants (for example P.ultimum or P. aphanidermatum); Ramularia spp., for example R.collo-cygni (Ramularia leaf and awn spot/physiological leaf spot) onbarley and R. beticola on sugar beet; Rhizoctonla spp. on cotton, rice,potatoes, lawn, corn, oilseed rape, potatoes, sugar beet, vegetables andon various other plants, for example R. solani (root and stem rot) onsoybeans, R. solani (sheath blight) on rice or R. cerealis (sharpeyespot) on wheat or barley; Rhizopus stolonifer (soft rot) onstrawberries, carrots, cabbage, grapevines and tomato; Rhynchosporiumsecalis (leaf spot) on barley, rye and triticale; Sarocladium oryzae andS. attenuatum (sheath rot) on rice; Sclerotinia spp. (stem or white rot)on vegetable and field crops, such as oilseed rape, sunflowers (forexample Sclerotinia sclerotiorum) and soybeans (for example S. rolfsii);Septoria spp. on various plants, for example S. glycines (leaf spot) onsoybeans, S. tritici (Septoria leaf blotch) on wheat and S. (syn.Stagonospora) nodorum (leaf blotch and glume blotch) on cereals;Uncinula (syn. Erysiphe) necator (powdery mildew, anamorph: Oidiumtuckeri) on grapevines; Setosphaerla spp. (leaf spot) on corn (forexample S. turcicum, syn. Helminthosporium turcicum) and lawn;Sphacelotheca spp. (head smut) on corn, (for example S. reiliana: kernelsmut), millet and sugar cane; Sphaerotheca fuliginea (powdery mildew) oncucumber species; Spongospora subterranea (powdery scab) on potatoes andthe viral diseases transmitted thereby; Stagonospora spp. on cereals,for example S. nodorum (leaf blotch and glume blotch, teleomorph:Leptosphaeria [syn. Phaeosphaeria] nodorum) on wheat; Synchytriumendobioticum on potatoes (potato wart disease); Taphrina spp., forexample T. deformans (curly-leaf disease) on peach and T. pruni(plum-pocket disease) on plums, Thielaviopsis spp. (black root rot) ontobacco, pome fruit, vegetable crops, soybeans and cotton, for exampleT. basicola (syn. Chalara elegans); Tilletia spp. (bunt or stinkingsmut) on cereals, such as for example T. tritici (syn. T. caries, wheatbunt) and T. controversa (dwarf bunt) on wheat; Typhula incarnata (graysnow mold) on barley or wheat; Urocystis spp., for example U. occulta(flag smut) on rye; Uromyces spp. (rust) on vegetable plants, such asbeans (for example U. appendiculatus, syn. U. phaseoli) and sugar beet(for example U. betae); Ustilago spp. (loose smut) on cereals (forexample U. nuda and U. avaenae), corn (for example U. maydis: corn smut)and sugar cane; Venturia spp. (scab) on apples (for example V.inaequalis) and pears and Verticillium spp. (leaf and shoot wilt) onvarious plants, such as fruit trees and ornamental trees, grapevines,soft fruit, vegetable and field crops, such as for example V. dahliae onstrawberries, oilseed rape, potatoes and tomatoes.

Moreover, the compounds I and the compositions according to theinvention are suitable for controlling harmful fungi in the protectionof materials and buildings (for example wood, paper, paint dispersions,fibers or tissues) and in the protection of stored products. In theprotection of wood and buildings, particular attention is paid to thefollowing harmful fungi: Ascomycetes, such as Ophiostoma spp.,Ceratocystis spp., Aureobasidium pullulans, Sclerophoma spp., Chaetomiumspp., Humicola spp., Petriella spp., Trichurus spp.; Basidiomycetes suchas Coniophora spp., Coriolus spp., Gloeophyllum spp., Lentinus spp.,Pleurotus spp., Poria spp., Serpula spp. and Tyromyces spp.,Deuteromycetes such as Aspergillus spp., Cladosporium spp., Penicilliumspp., Trichoderma spp., Alternaria spp., Paecilomyces spp. andZygomycetes such as Mucor spp., and in addition in the protection ofmaterials to the following yeast fungi: Candida spp. and Saccharomycescerevisae.

The compounds of the formula I may be present in various crystalmodifications which may differ in their biological activity. These areincluded in the scope of the present invention.

The compounds I and the compositions according to the invention aresuitable for improving plant health. Moreover, the invention relates toa method for improving plant health by treating the plants, the plantpropagation material and/or the site at which the plants grow or areintended to grow with an effective amount of the compounds I or thecompositions according to the invention.

The term “plant health” comprises states of a plant and/or its harvestedmaterial which are determined by various indicators individually or incombination, such as, for example, yield (for example increased biomassand/or increased content of utilizable ingredients), plant vitality (forexample increased plant growth and/or greener leaves (“greeningeffect”)), quality (for example increased content or composition ofcertain ingredients) and tolerance to biotic and/or abiotic stress. Theindicators mentioned here for a state of plant health may occurindependently of one another or may influence each other.

The compounds I are employed as such or in the form of a composition bytreating the harmful fungi, their habitat or the plants or plantpropagation materials, for example seed materials to be protectedagainst fungal attack, the soil, areas, materials or spaces with afungicidally effective amount of the compounds I. The application can becarried out both before and after the infection of the plants, plantpropagation materials, for example seed materials, the soil, the areas,materials or spaces by the fungi.

Plant propagation materials can be treated prophylactically during oreven before sowing or during or even before transplanting with compoundsI as such or with a composition comprising at least one compound I.

The invention furthermore relates to agrochemical compositionscomprising a solvent or solid carrier and at least one compound I, andalso to their use for controlling harmful fungi.

An agrochemical composition comprises a fungicidally effective amount ofa mixture of a compound I. The term “effective amount” refers to anamount of the agrochemical composition or of the compound I which issufficient for controlling harmful fungi on crop plants or in theprotection of materials and buildings and does not cause any significantdamage to the treated crop plants. Such an amount may vary within a widerange and is influenced by numerous factors, such as, for example, theharmful fungus to be controlled, the respective crop plant or materialstreated, the climatic conditions and compounds.

The compounds I, their N-oxides and their salts can be converted intothe types customary for agrochemical compositions, for examplesolutions, emulsions, suspensions, dusts, powders, pastes and granules.The type of composition depends on the respective intended purpose; ineach case, it should ensure a fine and even distribution of the compoundaccording to the invention.

Here, examples of types of compositions are suspensions (SC, OD, FS),pastes, pastilles, wettable powders or dusts (WP, SP, SS, WS, DP, DS) orgranules (GR, FG, GG, MG) which may either be water-soluble ordispersible (wettable), and also gels for treating plant propagationmaterials such as seed (GF).

In general, the composition types (for example SC, OD, FS, WG, SG, WP,SP, SS, WS, GF) are used in diluted form. Composition types such as DP,DS, GR, FG, GG and MG are generally employed in undiluted form.

The agrochemical compositions are prepared in a known manner (see, forexample, U.S. Pat. No. 3,060,084, EP-A 707 445 (for liquidconcentrates), Browning, “Agglomeration”, Chemical Engineering, Dec. 4,1967, 147-48, Perry's Chemical Engineer's Handbook, 4th edition,McGraw-Hill, New York, 1963, 8-57 and ff., WO 91/13546, U.S. Pat. Nos.4,172,714, 4,144,050, 3,920,442, 5,180,587, 5,232,701, 5,208,030, GB2,095,558, U.S. Pat. No. 3,299,566, Klingman: Weed Control as a Science(John Wiley & Sons, New York, 1961), Hance et al.: Weed Control Handbook(8th Ed., Blackwell Scientific Publications, Oxford, 1989) and Mollet,H. and Grubemann, A.: Formulation Technology (Wiley VCH Verlag,Weinheim, 2001).

The agrochemical compositions may furthermore also comprise auxiliariescustomary for crop protection compositions, the selection of theauxiliaries depending on the use form or the active compound inquestion.

Examples of suitable auxiliaries are solvents, solid carriers,surfactants (such as further solubilizers, protective colloids, wettingagents and tackifiers), organic and inorganic thickeners, bactericides,antifreeze agents, antifoams, if appropriate colorants and adhesives(for example for the treatment of seed).

Suitable solvents are water, organic solvents, such as mineral oilfractions having a medium to high boiling point, such as kerosene anddiesel oil, furthermore coal tar oils, and also oils of vegetable oranimal origin, aliphatic, cyclic and aromatic hydrocarbons, for exampleparaffins, tetrahydronaphthalene, alkylated naphthalenes and derivativesthereof, alkylated benzenes and derivatives thereof, alcohols, such asmethanol, ethanol, propanol, butanol and cyclohexanol, glycols, ketones,such as cyclohexanone, gamma-butyrolactone, dimethyl fatty amides, fattyacids and fatty acid esters and strongly polar solvents, for exampleamines, such as N-methylpyrrolidone. In principle, it is also possibleto use solvent mixtures, and also mixtures of the solvents mentionedabove and water.

Solid carriers are mineral earths, such as silicic acids, silica gels,silicates, talc, kaolin, limestone, lime, chalk, bole, loess, clay,dolomite, diatomaceous earth, calcium sulfate and magnesium sulfate,magnesium oxide, ground synthetic substances, fertilizers, such asammonium sulfate, ammonium phosphate, ammonium nitrate, ureas andvegetable products, such as cereal meal, tree bark meal, sawdust andnutshell meal, cellulose powder or other solid carriers.

Suitable surfactants (adjuvants, wetting agents, tackifiers, dispersantsor emulsifiers) are the alkali metal, alkaline earth metal and ammoniumsalts of aromatic sulfonic acids, for example of lignosulfonic acid(Borresperse® types, Borregaard, Norway), phenolsulfonic acid,naphthalenesulfonic acid (Morwet® types, Akzo Nobel, USA) anddibutylnaphthalenesulfonic acid (Nekal® types, BASF, Germany), and alsoof fatty acids, alkyl- and alkylarylsulfonates, alkyl, lauryl ether andfatty alcohol sulfates, and also salts of sulfated hexa-, hepta- andoctadecanols, and also of fatty alcohol glycol ethers, condensates ofsulfonated naphthalene and its derivatives with formaldehyde,condensates of naphthalene or of the naphthalenesulfonic acids withphenol and formaldehyde, polyoxyethylene octyl phenol ether, ethoxylatedisooctylphenol, octylphenol or nonylphenol, alkylphenyl polyglycolether, tributylphenyl polyglycol ether, alkylaryl polyether alcohols,isotridecyl alcohol, fatty alcohol/ethylene oxide condensates,ethoxylated castor oil, polyoxyethylene alkyl ethers or polyoxypropylenealkyl ethers, lauryl alcohol polyglycol ether acetate, sorbitol esters,lignosulfide waste liquors, and also proteins, denatured proteins,polysaccharides (for example methylcellulose), hydrophobically modifiedstarches, polyvinyl alcohol (Mowiol® types, Clariant, Switzerland),polycarboxylates (Sokalan® types, BASF, Germany), polyalkoxylates,polyvinylamine (Lupamin® types, BASF, Germany), polyethyleneimine(Lupasol® types, BASF, Germany), polyvinylpyrrolidone and copolymersthereof.

Examples of thickeners (i.e. compounds which impart modified flowproperties to the composition, i.e. high viscosity in the state of restand low viscosity in motion) are polysaccharides and also organic andinorganic sheet minerals, such as xanthan gum (Kelzan®, CP Kelco, USA),Rhodopol® 23 (Rhodia, France) or Veegum® (R.T. Vanderbilt, USA) orAttaclay® (Engelhard Corp., NJ, USA).

Bactericides can be added for stabilizing the composition. Examples ofbactericides are bactericides based on dichlorophen and benzyl alcoholhemiformal (Proxel® from ICI or Acticide® RS from Thor Chemie andKathon® MK from Rohm & Haas), and also isothiazolinone derivatives, suchas alkylisothiazolinones and benzisothiazoiinones (Acticide® MBS fromThor Chemie).

Examples of suitable antifreeze agents are ethylene glycol, propyleneglycol, urea and glycerol.

Examples of antifoams are silicone emulsions (such as, for example,Silikon® SRE, Wacker, Germany or Rhodorsil®, Rhodia, France), long-chainalcohols, fatty acids, salts of fatty acids, organofluorine compoundsand mixtures thereof.

Examples of colorants are both sparingly water-soluble pigments andwater-soluble dyes. Examples which may be mentioned are the dyes andpigments known under the names Rhodarnin B, C. I. Pigment Red 112 and C.I. Solvent Red 1, Pigment blue 15:4, Pigment blue 15:3, Pigment blue15:2, Pigment blue 15:1, Pigment blue 80, Pigment yellow 1, Pigmentyellow 13, Pigment red 48:2, Pigment red 48:1, Pigment red 57:1, Pigmentred 53:1, Pigment orange 43, Pigment orange 34, Pigment orange 5,Pigment green 36, Pigment green 7, Pigment white 6, Pigment brown 25,Basic violet 10, Basic violet 49, Acid red 51, Acid red 52, Acid red 14,Acid blue 9, Acid yellow 23, Basic red 10, Basic red 108.

Examples of adhesives are polyvinylpyrrolidone, polyvinyl acetate,polyvinyl alcohol and cellulose ether (Tylose®, Shin-Etsu, Japan).

Suitable for the preparation of directly sprayable solutions, emulsions,pastes or oil dispersions are mineral oil fractions of medium to highboiling point, such as kerosene or diesel oil, furthermore coal tar oilsand oils of vegetable or animal origin, aliphatic, cyclic and aromatichydrocarbons, for example toluene, xylene, paraffin,tetrahydro-naphthalene, alkylated naphthalenes or their derivatives,methanol, ethanol, propanol, butanol, cyclohexanol, cyclohexanone,isophorone, strongly polar solvents, for example dimethyl sulfoxide,N-methylpyrrolidone and water.

Powders, materials for spreading and dustable products can be preparedby mixing or concomitantly grinding the compounds I and, if presentfurther active compounds with at least one solid carrier.

Granules, for example coated granules, impregnated granules andhomogeneous granules, can be prepared by binding the active compounds toat least one solid carrier. Examples of solid carriers are mineralearths such as silica gels, silicates, talc, kaolin, attaclay,limestone, lime, chalk, bole, loess, clay, dolomite, diatomaceous earth,calcium sulfate, magnesium sulfate, magnesium oxide, ground syntheticmaterials, fertilizers, such as, for example, ammonium sulfate, ammoniumphosphate, ammonium nitrate, ureas, and products of vegetable origin,such as cereal meal, tree bark meal, wood meal and nutshell meal,cellulose powders and other solid carriers.

The following are examples of types of composition:

1. Types of Composition for Dilution with Water

i) Water-Soluble Concentrates (SL, LS)

10 parts by weight of the active compounds are dissolved with 90 partsby weight of water or with a water-soluble solvent. As an alternative,wetters or other auxiliaries are added. The active compound dissolvesupon dilution with water. This gives a composition having an activecompound content of 10% by weight.

ii) Dispersible Concentrates (DC)

20 parts by weight of the active compounds are dissolved in 70 parts byweight of cyclohexanone with addition of 10 parts by weight of adispersant, for example polyvinylpyrrolidone. Dilution with water givesa dispersion. The active compound content is 20% by weight.

iii) Emulsifiable Concentrates (EC)

15 parts by weight of the active compounds are dissolved in 75 parts byweight of xylene with addition of calcium dodecylbenzenesulfonate andcastor oil ethoxylate (in each case 5 parts by weight). Dilution withwater gives an emulsion. The composition has an active compound contentof 15% by weight.

iv) Emulsions (EW, EO, ES)

25 parts by weight of the active compounds are dissolved in 35 parts byweight of xylene with addition of calcium dodecylbenzenesulfonate andcastor oil ethoxylate (in each case 5 parts by weight). This mixture isadded to 30 parts by weight of water by means of an emulsifying machine(e.g. Ultraturrax) and made into a homogeneous emulsion. Dilution withwater gives an emulsion. The composition has an active compound contentof 25% by weight.

v) Suspensions (SC, OD, FS)

In an agitated ball mill, 20 parts by weight of the active compounds arecomminuted with addition of 10 parts by weight of dispersants andwetters and 70 parts by weight of water or an organic solvent to give afine active compound suspension. Dilution with water gives a stablesuspension of the active compound. The active compound content in thecomposition is 20% by weight.

vi) Water-Dispersible Granules and Water-Soluble Granules (WG, SG)

50 parts by weight of the active compounds are ground finely withaddition of 50 parts by weight of dispersants and wetters and made intowater-dispersible or water-soluble granules by means of technicalappliances (for example extrusion, spray tower, fluidized bed). Dilutionwith water gives a stable dispersion or solution of the active compound.The composition has an active compound content of 50% by weight.

vii) Water-Dispersible Powders and Water-Soluble Powders (WP, SP, SS,WS)

75 parts by weight of the active compounds are ground in a rotor-statormill with addition of 25 parts by weight of dispersants, wetters andsilica gel. Dilution with water gives a stable dispersion or solution ofthe active compound. The active compound content of the composition is75% by weight.

viii) Gels (GF)

20 parts by weight of the active compounds, 10 parts by weight ofdispersant, 1 part by weight of gelling agent and 70 parts by weight ofwater or an organic solvent are ground in a ball mill to give a finesuspension. Dilution with water gives a stable suspension with an activecompound content of 20% by weight.

2. Types of Composition to be Applied Undiluted

ix) Dusts (DP, DS)

5 parts by weight of the active compounds are ground finely and mixedintimately with 95 parts by weight of finely divided kaolin. This givesa dustable product with an active compound content of 5% by weight.

x) Granules (GR, FG, GG, MG)

0.5 part by weight of the active compounds is ground finely andassociated with 99.5 parts by weight of carriers. Current methods areextrusion, spray-drying or the fluidized bed. This gives granules withan active compound content of 0.5% by weight to be applied undiluted.

xi) ULV Solutions (UL)

10 parts by weight of the active compounds are dissolved in 90 parts byweight of an organic solvent, for example xylene. This gives acomposition with an active compound content of 10% by weight to beapplied undiluted.

In general, the compositions of the compounds according to the inventioncomprise from 0.01 to 95% by weight, preferably from 0.1 to 90% byweight, of the compounds I. The compounds are preferably employed in apurity of from 90% to 100%, preferably 95% to 100%.

Water-soluble concentrates (LS), suspensions (FS), dusts (DS),water-dispersible and water-soluble powders (WS, SS), emulsions (ES),emulsifiable concentrates (EC) and gels (GF) are usually used for thetreatment of plant propagation materials, in particular seed. Thesecompositions can be applied to the propagation materials, in particularseed, in undiluted or, preferably, diluted form. In this case, thecorresponding composition can be diluted 2 to 10 times so that in thecompositions used for the seed dressing from 0.01 to 60% by weight,preferably from 0.1 to 40% by weight of active compound are present. Theapplication can be carried out before or during sowing. The treatment ofplant propagation material, in particular the treatment of seed, isknown to the person skilled in the art and is carried out by dusting,coating, pelleting, dipping or drenching the plant propagation material,the treatment preferably being carried out by pelleting, coating anddusting or by furrow treatment, such that, for example, prematuregermination of the seed is prevented.

For seed treatment, preference is given to using suspensions. Suchcompositions usually comprise from 1 to 800 g of active compound/l, from1 to 200 g of surfactants/l, from 0 to 200 g of antifreeze agent/l, from0 to 400 g of binders/l, from 0 to 200 g of colorants/l and solvents,preferably water.

The compounds can be used as such or in the form of their compositions,for example in the form of directly sprayable solutions, powders,suspensions, dispersions, emulsions, oil dispersions, pastes, dustableproducts, materials for spreading or granules, by means of spraying,atomizing, dusting, spreading, raking in, immersing or pouring. Thetypes of composition depend entirely on the intended purposes; theintention is to ensure in each case the finest possible distribution ofthe active compounds according to the invention.

Aqueous use forms can be prepared from emulsion concentrates, pastes orwettable powders (sprayable powders, oil dispersions) by adding water.To prepare emulsions, pastes or oil dispersions, the substances, as suchor dissolved in an oil or solvent, can be homogenized in water by meansof a wetter, tackifier, dispersant or emulsifier. Alternatively, it ispossible to prepare concentrates composed of active substance, wetter,tackifier, dispersant or emulsifier and, if appropriate, solvent or oil,and such concentrates are suitable for dilution with water.

The active compound concentrations in the ready-to-use preparations canbe varied within relatively wide ranges. In general, they are from0.0001 to 10%, preferably from 0.01 to 1%.

The active compounds may also be used successfully in theultra-low-volume process (ULV), by which it is possible to applycompositions comprising over 95% by weight of active compound, or evento apply the active compound without additives.

When used in crop protection, the application rates are from 0.001 to2.0 kg of active compound per ha, preferably from 0.005 to 2 kg per ha,particularly preferably from 0.05 to 0.9 kg per ha, especially from 0.1to 0.75 kg per ha, depending on the nature of the desired effect.

In the treatment of plant propagation materials, for example seed, theamounts of active compound used are generally from 0.1 to 1000 g/100 kgof propagation material or seed, preferably from 1 to 1000 g/100 kg,particularly preferably from 1 to 100 g/100 kg, especially from 5 to 100g/100 kg.

When used in the protection of materials or stored products, the activecompound application rate depends on the kind of application area and onthe desired effect. Amounts typically applied in the protection ofmaterials are, for example, from 0.001 g to 2 kg, preferably from 0.005g to 1 kg, of active compound per cubic meter of treated material.

Various types of oils, welters, adjuvants, herbicides, bactericides,other fungicides and/or pesticides may be added to the active compoundsor the compositions comprising them, if appropriate not untilimmediately prior to use (tank mix). These compositions can be admixedwith the compositions according to the invention in a weight ratio offrom 1:100 to 100:1, preferably from 1:10 to 10:1.

The following are particularly suitable as adjuvants in this context:organically modified polysiloxanes, for example Break Thru S 240®;alcohol alkoxylates, for example Atplus 245®, Atplus MBA 1303®, PlurafacLF 300® and Lutensol ON 30®; EO-PO block polymers, for example PluronicRPE 2035® and Genapol B®; alcohol ethoxylates, for example Lutensol XP80®; and sodium dioctylsulfosuccinate, for example Leophen RA®.

The compositions according to the invention in the application form asfungicides can also be present together with other active compounds, forexample with herbicides, insecticides, growth regulators, fungicides orelse with fertilizers, as premix or if appropriate also only immediatelyprior to use (tank mix).

When mixing the compounds I or the compositions comprising them with oneor more further active compounds, in particular fungicides, it is inmany cases possible, for example, to widen the activity spectrum or toprevent the development of resistance. In many cases, synergisticeffects are obtained.

The following list of active compounds with which the compoundsaccording to the invention can be applied together is meant toillustrate the possible combinations, but not to limit them:

-   A) strobilurins:    -   azoxystrobin, dimoxystrobin, enestroburin, fluoxastrobin,        kresoxim-methyl, metominostrobin, orysastrobin, picoxystrobin,        pyraclostrobin, pyribencarb, trifloxystrobin,        2-(2-(6-(3-chloro-2-methylphenoxy)-5-fluoropyrimidin-4-yloxy)phenyl)-2-methoxyimino-N-methylacetamide,        methyl        2-(ortho-((2,5-dimethylphenyloxy-methylene)phenyl)-3-methoxyacrylate,        methyl        3-methoxy-2-(2-(N-(4-methoxyphenyl)-cyclopropanecarboximidoylsulfanylmethyl)phenyl)acrylate,        2-(2-(3-(2,6-dichloro-phenyl)-1-methylallylideneaminooxymethyl)phenyl)-2-methoxyimino-N-methyl-acetamide;-   B) carboxamides:    -   carboxanilides: benalaxyl, benalaxyl-M, benodanil, bixafen,        boscalid, carboxin, fenfuram, fenhexamid, flutolanil,        furametpyr, isopyrazam, isotianil, kiralaxyl, mepronil,        metalaxyl, metalaxyl-M (metenoxam), ofurace, oxadixyl,        oxycarboxin, penthiopyrad, tecloftalam, thifluzamide, tiadinil,        2-amino-4-methylthiazole-5-carboxanilide,        2-chloro-N-(1,1,3-trimethylindan-4-yl)nicotinamide,        N-(2′,4′-difluorobiphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,        N-(2′,4′-dichlorobiphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,        N-(2′,5′-difluorobiphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,        N-(2′,5′-dichlorobiphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,        N-(3′,5′-difluorobiphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,        N-(3′,5′-dichlorobiphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,        N-(3′-fluorobiphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,        N-(3′-chlorobiphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,        N-(2′-fluorobiphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,        N-(2′-chlorobiphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,        N-(3′,4′,5′-trifluorobiphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,        N-(2′,4′,5′-trifluorobiphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,        N-[2-(1,1,2,3,3,3-hexafluoropropoxy)phenyl]-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,        N-[2-(1,1,2,2-tetrafluoroethoxy)phenyl]-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,        N-(4′-trifluoromethylthiobiphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,        N-(2-(1,3-dimethylbutyl)phenyl)-1,3-dimethyl-5-fluoro-1H-pyrazole-4-carboxamide,        N-(2-(1,3,3-trimethylbutyl)phenyl)-1,3-dimethyl-5-fluoro-1H-pyrazole-4-carboxamide,        N-(4′-chloro-3′,5′-difluorobiphenyl-2-yl)-3-di-fluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,        N-(4′-chloro-3′.5′-difluorobi-phenyl-2-yl)-3-trifluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,        N-(3′,4′-dichloro-5′-fluorobiphenyl-2-yl)-3-trifluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,        N-(3′,5′-difluoro-4′-methylbiphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,        N-(3′,5′-difluoro-4′-methylbiphenyl-2-yl)-3-trifluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,        N-(2-bicyclopropyl-2-ylphenyl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,        N-(cis-2-bicyclopropyl-2-ylphenyl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,        N-(trans-2-bicyclopropyl-2-ylphenyl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide,        N-[1,2,3,4-tetrahydro-9-(1-methylethyl)-1,4-methanonaphthalen-5-yl]-3-(difluoromethyl)-1-methyl-1H-pyrazole-4-carboxamide;    -   carboxylic acid morpholides: dimethomorph, flumorph;    -   benzamides: flumetover, fluopicolide, fluopyram, zoxamide,        N-(3-ethyl-3,5,5-tri-mgthylcyclohexyl)-3-formylamino-2-hydroxybenzamide;    -   other carboxamides: carpropamid, diclocymet, mandipropamid,        oxytetracyclin, silthiofam,        N-(6-methoxypyridin-3-yl)cyclopropanecarboxamide;-   C) azoles:    -   triazoles: azaconazole, bitertanole, bromuconazole,        cyproconazole, difenoconazole, diniconazole, diniconazole-M,        epoxiconazole, fenbuconazole, fluquinconazole, flusilazole,        fiutriafole, hexaconazole, imibenconazole, ipconazole,        metconazole, myclobutanil, oxpoconazole, paclobutrazole,        penconazole, propiconazole, prothioconazole, simeconazole,        tebuconazole, tetraconazole, triadimefon, triadimenoie,        triticonazole, uniconazole,        1-(4-chlorophenyl)-2-([1,2,4]triazol-1-yl)cycloheptanol;    -   imidazoles: cyazofamid, imazalil, imazalil sulfate, pefurazoate,        prochloraz, triflumizole;    -   benzimidazoles: benomyl, carbendazim, fuberidazole,        thiabendazole;    -   others: ethaboxam, etridiazole, hymexazole,        2-(4-chlorophenyl)-N-[4-(3,4-dimethoxyphenypisoxazol-5-yl]-2-prop-2-inyloxy-acetamide;-   D) nitrogenous heterocyclyl compounds    -   pyridines: fluazinam, pyrifenox,        3-[5-(4-chlorophenyl)-2,3-dimethylisoxazolidin-3-yl]-pyridine,        3-[5-(4-methylphenyl)-2,3-dimethylisoxazolidin-3-yl]pyridine,        2,3,5,6-tetra-chloro-4-methanesulfonylpyridine,        3,4,5-trichloropyridine-2,6-dicarbonitrile,        N-(1-(5-bromo-3-chloropyridin-2-yl)ethyl)-2,4-dichloronicotinamide,        N-((5-bromo-3-chloro-pyridin-2-yl)methyl)-2,4-dichloronicotinamide;    -   pyrimidines: bupirimate, cyprodinil, diflumetorim, fenarimol,        ferimzone, mepanipyrim, nitrapyrin, nuarimol, pyrimethanil;    -   piperazines: triforine;    -   pyrroles: fludioxonil, fenpiclonil;    -   morpholines: aldimorph, dodemorph, dodemorph acetate,        fenpropimorph, tridemorph;    -   piperidines: fenpropidin;    -   dicarboximides: fluoroimide, iprodione, procymidone,        vinclozolin;    -   nonaromatic 5-membered heterocycles: famoxadone, fenamidone,        flutianil, octhilinone, probenazole, S-allyl        5-amino-2-isopropyl-3-oxo-4-ortho-tolyl-2,3-dihydropyrazole-1-thiocarboxylate;    -   others: acibenzolar-S-methyl, amisuibrom, anilazine,        blasticidin-S, captafol, captan, quinomethionate, dazomet,        debacarb, diclomezine, difenzoquat, difenzoquat methylsulfate,        fenoxanil, folpet, oxolinic acid, piperalin, proquinazid,        pyroquilone, quinoxyfen, triazoxide, tricyclazole,        2-butoxy-6-iodo-3-propylchromen-4-one,        5-chloro-1-(4,6-dimethoxypyrimidin-2-yl)-2-methyl-1H-benzimidazole,        5-chloro-7-(4-methylpiperidin-1-yl)-6-(2,4,6-trifluorophenyl)-[1,2,4]triazolo[1,5-a]pyrimidine,        6-(3,4-dichlorophenyl)-5-methyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-ylamine,        6-(4-tert-butylphenyl)-5-methyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-ylamine,        5-methyl-6-(3,5,5-trimethylhexyl)-[1,2,4]triazolo[1,5-a]pyrimidin-7-ylamine,        5-methyl-6-octyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-ylamine,        6-methyl-5-octyl-[1,2,4]triazolo[1,5-a]-pyrimidin-7-ylamine,        6-ethyl-5-octyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-ylamine,        5-ethyl-6-octyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-ylamine,        5-ethyl-6-(3,5,5-trimethylhexyl)-[1,2,4]triazolo[1,5-a]pyrimidin-7-ylamine,        6-octyl-5-propyl-[1,2,4]triazolo[1,5-a]-pyrimidin-7-ylamine,        5-methoxymethyl-6-octyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-ylamine,        6-octyl-5-trifluoromethyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-ylamine        and        5-trifluoromethyl-6-(3,5,5-trimethylhexyl)-[1,2,4]triazolo[1,5-a]pyrimidin-7-ylamine;-   E) carbamates and dithiocarbamates    -   thio- and dithiocarbamates: ferbam, mancozeb, maneb, metam,        methasulfocarb, metiram, propineb, thiram, zineb, ziram;    -   carbamates: diethofencarb, benthiavalicarb, iprovalicarb,        propamocarb, propamocarb hydrochloride, valiphenal,        4-fluorophenyl        N-(1-(1-(4-cyanophenyl)ethanesulfonyl)but-2-yl)carbamate;-   F) other fungicides    -   guanidines: dodine, dodine free base, guazatine, guazatine        acetate, iminoctadine, iminoctadine triacetate, iminoctadine        tris(albesilate);    -   antibiotics: kasugamycin, kasugamycin hydrochloride hydrate,        polyoxins, streptomycin, validamycin A;    -   nitrophenyl derivatives:    -   binapacryl, dicloran, dinobuton, dinocap, nitrothal isopropyl,        tecnazene;    -   organometallic compounds: fentin salts, such as, for example,        fentin acetate, fentin chloride, fentirr hydroxide;    -   sulfur-containing heterocyclyl compounds: dithianon,        isoprothiolane;    -   organophosphorus compounds: edifenphos, fosetyl, fosetyl        aluminum, iprobenfos, phosphorous acid and its salts,        pyrazophos, tolclofos-methyl;    -   organochlorine compounds: chlorothalonil, dichlofluanid,        dichlorophen, flusulfamide, hexachlorobenzene, pencycuron,        pentachlorophenol and its salts, phthalide, quintozene,        thiophanate methyl, tolylfluanid,        N-(4-chloro-2-nitrophenyl)-N-ethyl-4-methylbenzenesulfonamide;    -   inorganic active compounds: phosphorous acid and its salts,        Bordeaux mixture, copper salts, such as, for example, copper        acetate, copper hydroxide, copper oxy-chloride, basic copper        sulfate, sulfur;    -   others: biphenyl, bronopol, cyflufenamid, cymoxanil,        diphenylamine, metrafenone, mildiomycin, oxine-copper,        prohexadione-calcium, spiroxamine, tolylfluanid,        N-(cyclopropylmethoxyimino-(6-difluoromethoxy-2,3-difluorophenyl)methyl)-2-phenylacetamide,        N′-(4-(4-chloro-3-trifluoromethylphenoxy)-2,5-dimethylphenyl)-N-ethyl-N-methylformamidine,        N′-(4-(4-fluoro-3-trifluoromethylphenoxy)-2,5-dimethylphenyl)-N-ethyl-N-methylformamidine,        N′-(2-methyl-5-trifluoromethyl-4-(3-trimethylsilanylpropoxy)phenyl)-N-ethyl-N-methylformamidine,        N′-(5-difluoromethyl-2-methyl-4-(3-trimethylsilanylpropoxy)phenyl)-N-ethyl-N-methylformamidine,        methyl        N-(1,2,3,4-tetrahydronaphthalen-1-yl)-2-{1-[2-(5-methyl-3-trifluoromethylpyrazol-1-yl)acetyl]piperidin-4-yl}thiazole-4-carboxamide,        methyl        (R)—N-(1,2,3,4-tetrahydronaphthalen-1-yl)-2-{1-[2-(5-methyl-3-trifluoromethylpyrazol-1-yl)acetyl]-piperidin-4-yl}thiazole-4-carboxamide,        6-tert-butyl-8-fluoro-2,3-dimethylquinolin-4-yl acetate,        6-tert-butyl-8-fluoro-2,3-dimethylquinolin-4-yl methoxyacetate;-   G) growth regulators    -   abscisic acid, amidochlor, ancymidol, 6-benzylaminopurine,        brassinolide, butralin, chlormequat (chlormequat chloride),        choline chloride, cyclanilide, daminozide, dikegulac,        dimethipin, 2,6-dimethylpuridine, ethephon, flumetralin,        flurprimidol, fluthiacet, forchlorfenuron, gibberellic acid,        inabenfid, indole-3-acetic acid, maleic hydrazide, mefluidide,        mepiquat (mepiquat chloride), metconazole, naphthalene acetic        acid, N-6-benzyladenine, paclobutrazole, prohexadione        (prohexadione-calcium), prohydrojasmon, thidiazuron,        triapenthenol, tributyl phosphorotrithioate,        2,3,5-triiodobenzoic acid, trinexapac-ethyl and uniconazole;-   H) herbicides    -   acetamides: acetochlor, alachlor, butachlor, dimethachior,        dimethenamid, flufenacet, mefenacet, metolachlor, metazachior,        napropamide, naproanilide, pethoxamid, pretilachlor, propachlor,        thenylchior;    -   amino acid analogues: bilanafos, glyphosate, glufosinate,        sulfosate;    -   aryloxyphenoxypropionates: clodinafop, cyhalofop-butyl,        fenoxaprop, fluazifop, haloxyfop, metamifop, propaquizafop,        quizalofop, quizalofop-p-tefuryl;    -   bipyridyls: diquat, paraquat;    -   carbamates and thiocarbamates: asulam, butylate, carbetamide,        desmedipham, dimepiperate, eptam (EPTC), esprocarb, molinate,        orbencarb, phenmedipham, prosulfocarb, pyributicarb,        thiobencarb, triallate;    -   cyclohexanediones: butroxydim, clethodim, cycloxydim,        profoxydim, sethoxydim, tepraloxydim, tralkoxydim;    -   dinitroanilines: benfluralin, ethaifluralin, oryzalin,        pendimethalin, prodiamine, trifluralin;    -   diphenyl ethers: acifluorfen, aclonifen, bifenox, diclofop,        ethoxyfen, fomesafen, lactofen, oxyfluorfen;    -   hydroxybenzonitriles: bromoxynil, dichlobenil, ioxynil;    -   imidazolinones: imazamethabenz, imazamox, imazapic, imazapyr,        imazaquin, imazethapyr;    -   phenoxyacetic acids: clomeprop, 2,4-dichlorophenoxyacetic acid        (2,4-D), 2,4-DB, dichlorprop, MCPA, MCPA-thioethyl, MCPB,        mecoprop;    -   pyrazines: chloridazone, flufenpyr-ethyl, fluthiacet,        norflurazone, pyridate;    -   pyridines: aminopyralid, clopyralid, diflufenican, dithiopyr,        fluridone, fluoroxypyr, picloram, picolinafen, thiazopyr;    -   sulfonylureas: amidosulfuron, azimsulfuron, bensulfuron,        chlorimuron-ethyl, chiorsulfuron, cinosulfuron, cyclosulfamuron,        ethoxysuifuron, flazasulfuron, fluce-tosulfuron, flupyrsulfuron,        foramsulfuron, halosulfuron, imazosulfuron, iodosulfuron,        mesosulfuron, metsulfuron-methyl, nicosulfuron, oxasulfuron,        primisulfuron, prosul-furon, pyrazosulfuron, rimsulfuron,        sulfometuron, sulfosulfuron, thifensulfuron, tria-sulfuron,        tribenuron, trifloxysulfuron, triflusulfuron, tritosulfuron,        1-((2-chloro-6-propyl-imidazo[1,2-b]pyridazin-3-yl)sulfonyl)-3-(4,6-dimethoxypyrimidin-2-yl)urea;    -   triazines: ametryn, atrazine, cyanazine, dimethametryn,        ethiozine, hexazinone, meta-mitron, metribuzin, prometryn,        simazine, terbuthylazine, terbutryn, triaziflam;    -   ureas: chlorotoluron, daimuron, diuron, fluometuron,        isoproturon, linuron, methabenzthiazuron, tebuthiuron;    -   other inhibitors of acetolactate synthase: bispyribac-sodium,        cloransuiam-methyl, diclosulam, florasulam, flucarbazone,        flumetsulam, metosulam, ortho-sulfamuron, penoxsulam,        propoxycarbazone, pyribambenz-propyl, pyribenzoxim, pyriftalid,        pyriminobac-methyl, pyrimisulfan, pyrithiobac, pyroxasulfone,        pyroxsuiam;    -   others: amicarbazone, aminotriazole, anilofos, beflubutamid,        benazolin, bencarbazone, benfluresate, benzofenap, bentazone,        benzobicyclon, bromacil, bromobutide, butafenacil, butamifos,        cafenstrole, carfentrazone, cinidon-ethlyl, chlorthal,        cinmethylin, clomazone, cumyluron, cyprosulfamide, dicamba,        difenzoquat, diflufenzopyr, Drechslera monoceras, endothal,        ethofumesate, etobenzanid, fentrazamide, flumiciorac-pentyl,        flumioxazin, flupoxam, fluorochloridone, flurtamone, indanofan,        isoxaben, isoxaflutole, lenacil, propanil, propyzamide,        quinclorac, quinmerac, mesotrione, methylarsenic acid, naptalam,        oxadiargyl, oxadiazon, oxaziclomefone, pentoxazone, pinoxaden,        pyraclonil, pyraflufen-ethyl, pyrasulfotol, pyrazoxyfen,        pyrazolynate, quinoclamine, saflufenacil, sulcotrion,        sulfentrazone, terbacil, tefuryltrione, tembotrione,        thiencarbazone, topramezone,        4-hydroxy-3-[2-(2-methoxyethoxymethyl)-6-trifluoromethylpyridine-3-carbonyl]ibicyclo[3.2.1]oct-3-ene-2-one,        ethyl        (3-[2-chloro-4-fluoro-5-(3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydro-2H-pyrimidin-1-yl)phenoxy]pyridin-2-yloxy)acetate,        methyl 6-amino-5-chloro-2-cyclopropylpyrimidine-4-carboxylate,        6-chloro-3-(2-cyclopropyl-6-methylphenoxy)-pyridazin-4-ol,        4-amino-3-chloro-6-(4-chlorophenyl)-5-fluoropyridine-2-carboxylic        acid, methyl        4-amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylate        and methyl        4-amino-3-chloro-6-(4-chloro-3-dimethylamino-2-fluorophenyl)pyridine-2-carboxylate;-   I) insecticides    -   organo(thio)phosphates: acephate, azamethiphos, azinphos-methyl,        chlorpyrifos, chlorpyrifos-methyl, chlorfenvinphos, diazinon,        dichlorvos, dicrotophos, dimethoate, disulfoton, ethion,        fenitrothion, fenthion, isoxathion, malathion, methamidophos,        methidathion, methyl-parathion, mevinphos, monocrotophos,        oxydemeton-methyl, paraoxon, parathion, phenthoate, phosalone,        phosmet, phosphamidon, phorate, phoxim, pirimiphos-methyl,        profenofos, prothiofos, suiprophos, tetrachlorvinphos, terbufos,        triazophos, trichlorfon;    -   carbamates: alanycarb, aldicarb, bendiocarb, benfuracarb,        carbaryl, carbofuran, carbosulfan, fenoxycarb, furathiocarb,        methiocarb, methomyl, oxamyl, pirimicarb, propoxur, thiodicarb,        triazamate;    -   pyrethroids: allethrin, bifenthrin, cyfluthrin, cyhalothrin,        cyphenothrin, cypermethrin, alpha-cypermethrin,        beta-cypermethrin, zeta-cypermethrin, deltamethrin,        esfenvalerate, etofenprox, fenpropathrin, fenvalerate,        imiprothrin, lambda-cyha-lothrin, permethrin, prallethrin,        pyrethrin I and II, resmethrin, silafluofen, tau-fluvalinate,        tefluthrin, tetramethrin, tralomethrin, transfluthrin,        profluthrin, dimefluthrin,    -   inhibitors of insect growth: a) chitin synthesis inhibitors:        benzoylureas: chlorfluazuron, cyromazine, diflubenzuron,        flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron,        teflubenzuron, triflumuron; buprofezin, diofenolan, hexythiazox,        etoxazole, clofentazin; b) ecdysone antagonists: halofenozide,        methoxyfenozide, tebufenozide, azadirachtin; c) juvenoids:        pyriproxyfen, methoprene, fenoxycarb; d) lipid biosynthesis        inhibitors: spirodiclofen, spiromesifen, spirotetramate;    -   nicotine receptor agonists/antagonists: clothianidin,        dinotefuran, imidacloprid, thiamethoxam, nitenpyram,        acetamiprid, thiacloprid,        1-(2-chlorothiazol-5-ylmethyl)-2-nitrimino-3,5-dimethyl-[1,3,5]triazinane;    -   GABA antagonists: endosulfan, ethiprol, fipronil, vaniliprol,        pyrafluprol, pyriprol,        5-amino-1-(2,6-dichloro-4-methylphenyl)-4-sulfinamoyl-1H-pyrazole-3-thiocarboxamide;    -   macrocyclic lactones: abamectin, emamectin, milbemectin,        lepimectin, spinosad, spinetoram;    -   mitochondrial electron transport chain inhibitors (METI) I        acaricides: fenazaquin, pyridaben, tebufenpyrad, tolfenpyrad,        flufenerim;    -   METI II and III substances: acequinocyl, fluacyprim,        hydramethylnon;    -   decouplers: chlorfenapyr;    -   inhibitors of oxidative phosphorylation: cyhexatin,        diafenthiuron, fenbutatin oxide, propargite;    -   insect molting inhibitors: cryomazine;    -   mixed function oxidase inhibitors: piperonyl butoxide;    -   sodium channel blockers: indoxacarb, metaflumizone;    -   others: benclothiaz, bifenazate, cartap, fionicamid, pyridalyl,        pymetrozine, sulfur, thiocyclam, flubendiamid,        chlorantraniliprol, cyazypyr (HGW86); cyenopyrafen,        flupyrazofos, cyflumetofen, amidoflumet, imicyafos,        bistrifiuron, and pyrifluquinazon.

The present invention relates in particular also to fungicidalcompositions which comprise at least one compound of the general formulaI and at least one further crop protection agent, in particular at leastone fungicidal active compound, for example one or more, for example 1or 2, active compounds of groups A) to F) mentioned above and, ifappropriate, one or more agriculturally suitable carriers. With a viewto reducing the application rates, these mixtures are of interest, sincemany show, at a reduced total amount of active compounds applied, animproved activity against harmful fungi, in particular for certainindications. By simultaneous joint or separate application ofcompound(s) I with at least one active compound of groups A) to I), thefungicidal activity can be increased in a superadditive manner.

In the sense of the present application, joint application means thatthe at least one compound of the formula I and the at least one furtheractive compound are present simultaneously at the site of action (i.e.the plant-damaging fungi to be controlled and their habitat, such asinfected plants, plant propagation materials, in particular seed, soils,materials or spaces and also plants, plant propagation materials, inparticular seed, soils, materials or spaces to be protected againstfungal attack) in an amount sufficient for an effective control offungal growth. This can be achieved by applying the compounds I and atleast one further active compound jointly in a joint active compoundpreparation or in at least two separate active compound preparationssimultaneously, or by applying the active compounds successively to thesite of action, the interval between the individual active compoundapplications being chosen such that the active compound applied firstis, at the time of application of the further active compound(s),present at the site of action in a sufficient amount. The order in whichthe active compounds are applied is of minor importance.

In binary mixtures, i.e. compositions according to the inventioncomprising a compound I and a further active compound, for example anactive compound of groups A) to I), the weight ratio of compound I tothe further active compound lies the weight ratio of compound I to the1st further active compound depends on the properties of the activecompounds in question; usually, it is in the range of from 1:100 to100:1, frequently in the range of from 1:50 to 50:1, preferably in therange of from 1:20 to 20:1, particularly preferably in the range of from1:10 to 10:1, especially in the range of from 1:3 to 3:1.

In ternary mixtures, i.e. compositions according to the inventioncomprising an active compound I and a 1st further active compound and a2nd further active compound, for example two different active compoundsfrom groups A) to I), the weight ratio of compound I to the 1st furtheractive compound depends on the properties of the respective activecompounds; preferably, it is in the range of from 1:50 to 50:1 and inparticular in the range of from 1:10 to 10:1. The weight ratio ofcompound I to the 2nd further active compound is preferably in the rangeof from 1:50 to 50:1, in particular in the range of from 1:10 to 10:1.The weight ratio of 1st further active compound to 2nd further activecompound is preferably in the range of from 1:50 to 50:1, in particularin the range of from 1:10 to 10:1.

The components of the composition according to the invention can bepackaged and used individually or as a ready-mix or as a kit of parts.

In one embodiment of the invention, the kits may comprise one or more,and even all, components used for preparing an agrochemical compositionaccording to the invention. For example, these kits may comprise one ormore fungicide components and/or an adjuvant component and/or aninsecticide component and/or a growth regulator component and/or aherbicide. One or more components may be present combined orpreformulated with one another. In the embodiments where more than twocomponents are provided in a kit, the components can be combined withone another and be packaged in a single container, such as a vessel, abottle, a tin, a bag, a sack or canister. In other embodiments, two ormore components of a kit may be packaged separately, i.e. notpreformulated or mixed. Kits may comprise one or more separatecontainers, such as vessels, bottles, tins, bags, sacks or canisters,each container comprising a separate component of the agrochemicalcomposition. The components of the composition according to theinvention may be packaged and used individually or as a ready-mix or asa kit of parts. In both forms, a component may be used separately ortogether with the other components or as a part of a kit of partsaccording to the invention for preparing the mixture according to theinvention.

The user uses the composition according to the invention usually for usein a predosage device, a knapsack sprayer, a spray tank or a sprayplane. Here, the agrochemical composition is diluted with water and/orbuffer to the desired application concentration, with furtherauxiliaries being added, if appropriate, thus giving the ready-to-usespray liquor or the agrochemical composition according to the invention.Usually, from 50 to 500 liters of the ready-to-use spray liquor areapplied per hectare of agricultural utilized area, preferably from 100to 400 liters.

According to one embodiment, the user may himself mix individualcomponents, such as, for example, parts of a kit or a two- orthree-component mixture of the composition according to the invention ina spray tank and, if appropriate, add further auxiliaries (tank mix).

In a further embodiment, the user may mix both individual components ofthe composition according to the invention and partially pre-mixedcomponents, for example components comprising compounds I and/or activecompounds from groups A) to I), in a spray tank and, if appropriate, addfurther auxiliaries (tank mix).

In a further embodiment, the user may use both individual components ofthe composition according to the invention and partially pre-mixedcomponents, for example components comprising compounds I and/or activecompounds from groups A) to I), jointly (for example as a tank mix) orin succession.

Preference is given to compositions of a compound I (component 1) withat least one active compound from group A) (component 2) of thestrobilurins and in particular selected from the group consisting ofazoxystrobin, dimoxystrobin, fluoxastrobin, kresoxim-methyl,orysastrobin, picoxystrobin, pyraclostrobin and trifloxystrobin.

Preference is also given to compositions of a compound I (component 1)with at least one active compound selected from group B) (component 2)of the carboxamides and in particular selected from the group consistingof fenhexamid, metalaxyl, mefenoxam, ofurace, dimethomorph, flumorph,fluopicolid (picobenzamid), zoxamide, carpropamid and mandipropamid.

Preference is also given to compositions of a compound I (component I)with at least one active compound selected from group C) (component 2)of the azoles and in particular selected from the group consisting ofcyproconazole, difenoconazole, epoxiconazole, fluquinconazole,flusilazole, flutriafole, metconazole, myclobutanil, penconazole,propiconazole, prothioconazole, triadimefon, triadimenol, tebuconazole,tetraconazole, triticonazole, prochloraz, cyazofamid, benomyl,carbendazim and ethaboxam.

Preference is also given to compositions of a compound I (component 1)with at least one active compound selected from group D) (component 2)of the nitrogenous heterocyclyl compounds and in particular selectedfrom the group consisting of fluazinam, cyprodinil, fenarimol,mepanipyrim, pyrimethanil, triforin, fludioxonil, fodemorph,fenpropimorph, tridemorph, fenpropidin, iprodion, vinclozolin,famoxadone, fenamidone, probenazole, proquinazid, acibenzolar-s-methyl,captafol, folpet, fenoxanil and quinoxyfen.

Preference is also given to compositions of a compound I (component 1)with at least one active compound selected from group E) (component 2)of the carbamates and in particular selected from the group consistingof mancozeb, metiram, propineb, thiram, iprovalicarb, flubenthiavalicarband propamocarb.

Preference is also given to compositions of a compound I (component 1)with at least one active compound selected from the fungicides of groupF) (component 2) and in particular selected from the group consisting ofdithianon, fentin salts, such as fentin acetate, fosetyl,fosetyl-aluminum, H₃PO₃ and salts thereof, chlorothalonil,dichlofluanid, thiophanate-methyl, copper acetate, copper hydroxide,copper oxychloride, copper sulfate, sulfur, cymoxanil, metrafenone,spiroxamine and5-chloro-7-(4-methylpiperidin-1-yl)-6-(2,4,6-trifluorophenyl)-[1,2,4]triazolo[1,5-a]pyrimidine.

Accordingly, the present invention furthermore relates to compositionsof a compound I (component 1) with a further active compound (component2), the latter being selected from rows B-1 to B-378 in the column“component 2” of table B.

A further embodiment of the invention relates to the compositions B-1 toB-378 listed in Table B, where a row of Table B corresponds in each caseto an agrochemical composition comprising one of the compounds of theformula I individualized in the present description (component 1) andthe respective further active compound from the groups A) to F)(component 2) stated in the row in question. The active compounds in thedescribed compositions are in each case preferably present insynergistically active amounts.

TABLE B Active compound composition, comprising an individualizedcompound I and a further active compounds from the groups A) to F) RowComponent 1 Component 2 B-1 an individualized compound I azoxystrobinB-2 an individualized compound I dimoxystrobin B-3 an individualizedcompound I enestroburin B-4 an individualized compound I fluoxastrobinB-5 an individualized compound I kresoxim-methyl B-6 an individualizedcompound I metominostrobin B-7 an individualized compound I orysastrobinB-8 an individualized compound I picoxystrobin B-9 an individualizedcompound I pyraclostrobin B-10 an individualized compound I pyribencarbB-11 an individualized compound I trifloxystrobin B-12 an individualizedcompound I 2-(2-(6-(3-chloro-2-methylphenoxy)-5-fluoropyrimidin-4-yloxy)phenyl)-2-methoxyimino- N-methylacetamide B-13an individualized compound I 2-(ortho-((2,5-dimethylphenyloxy-methylene)phenyl)-3-methoxyacrylic acid methyl ester B-14 anindividualized compound I 3-methoxy-2-(2-(N-(4-methoxyphenyl)-cyclopropanecarboximidoylsulfanyl- methyl)phenyl)acrylic acid methylester B-15 an individualized compound I2-(2-(3-(2,6-dichlorophenyl)-1-methyallylidene-aminooxymethyl)phenyl)-2-methoxyimino-N- methylacetamide B-16 anindividualized compound I benalaxyl B-17 an individualized compound Ibenalaxyl-M B-18 an individualized compound I benodanil B-19 anindividualized compound I bixafen B-20 an individualized compound Iboscalid B-21 an individualized compound I carboxin B-22 anindividualized compound I fenfuram B-23 an individualized compound Ifenhexamid B-24 an individualized compound I flutolanil B-25 anindividualized compound I furametpyr B-26 an individualized compound Iisopyrazam B-27 an individualized compound I isotianil B-28 anindividualized compound I kiralaxyl B-29 an individualized compound Imepronil B-30 an individualized compound I metalaxyl B-31 anindividualized compound I metalaxyl-M B-32 an individualized compound Iofurace B-33 an individualized compound I oxadixyl B-34 anindividualized compound I oxycarboxin B-35 an individualized compound Ipenthiopyrad B-36 an individualized compound I tecloftalam B-37 anindividualized compound I thifluzamide B-38 an individualized compound Itiadinil B-39 an individualized compound I2-amino-4-methylthiazole-5-carboxanilide B-40 an individualized compoundI 2-chloro-N-(1,1,3-trimethylindan-4-yl)-nicotinamide B-41 anindividualized compound IN-(2′,4′-difluorobiphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide B-42 an individualized compound IN-(2′,4′-dichlorobiphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide B-43 an individualized compound IN-(2′,5′-difluorobiphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide B-44 an individualized compound IN-(2′,5′-dichlorobiphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide B-45 an individualized compound IN-(3′,5′-difluorobiphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide B-46 an individualized compound IN-(3′,5′-dichlorobiphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamid B-47 an individualized compound IN-(3′-fluorobiphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide B-48 an individualized compound IN-(3′-chlorobiphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide B-49 an individualized compound IN-(2′-fluorobiphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide B-50 an individualized compound IN-(2′-chlorobiphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide B-51 an individualized compound IN-(3′,4′,5′-trifluorobiphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide B-52 an individualized compound IN-(2′,4′,5′-trifluorobiphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide B-53 an individualized compound IN-[2-(1,1,2,3,3,3-hexafluoropropoxy)phenyl]-3-difluoromethyl-1-methyl-1H-pyrazole-4- carboxamide B-54 anindividualized compound I N-[2-(1,1,2,2-tetrafluoroethoxy)phenyl]-3-difluoromethyl-1-methyl-1H-pyrazole-4- carboxamide B-55 anindividualized compound I N-(4′-trifluoromethylthiobiphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole-4- carboxamide B-56 anindividualized compound IN-(2-(1,3-dimethylbutyl)phenyl)-1,3-dimethyl-5-fluoro-1H-pyrazole-4-carboxamide B-57 an individualized compound IN-(2-1,3,3-trimethylbutyl)phenyl)-1,3-dimethyl-5-fluoro-1H-pyrazole-4-carboxamide B-58 an individualized compound IN-(4′-chloro-3′,5′-difluorobiphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole- 4-carboxamide B-59 anindividualized compound I N-(4′-chloro-3′,5′-difluorobiphenyl-2-yl)-3-trifluoromethyl-1-methyl-1H-pyrazole- 4-carboxamide B-60 anindividualized compound I N-(3′,4′-dichloro-5′-fluorobiphenyl-2-yl)-3-trifluoromethyl-1-methyl-1H-pyrazole- 4-carboxamide B-61 anindividualized compound I N-(3′,5′-difluoro-4′-methylbiphenyl-2-yl)-3-difluoromethyl-1-methyl-1H-pyrazole- 4-carboxamide B-62 anindividualized compound I N-(3′,5′-difluoro-4′-methylbiphenyl-2-yl)-3-trifluoromethyl-1-methyl-1H-pyrazole- 4-carboxamide B-63 anindividualized compound IN-(2-bicyclopropyl-2-ylphenyl)-3-difluoromethyl-1-methyl-1H-pyrazole-4-carboxamide B-64 an individualized compound IN-(cis-2-bicyclopropyl-2-ylphenyl)-3-difluoromethyl-1-methyl-1H-pyrazole- 4-carboxamide B-65 anindividualized compound I N-(trans-2-bicyclopropyl-2-ylphenyl)-3-difluoromethyl-1-methyl-1H-pyrazole- 4-carboxamide B-66 anindividualized compound I N-[1,2,3,4-tetrahydro-9-(1-methylethyl)-1,4-methanonaphthalen-5-yl]-3-(difluoromethyl)-1-methyl-1H-pyrazole-4-carboxamide B-67 an individualized compound Idimethomorph B-68 an individualized compound I flumorph B-69 anindividualized compound I flumetover B-70 an individualized compound Ifluopicolide B-71 an individualized compound I fluopyram B-72 anindividualized compound I zoxamide B-73 an individualized compound IN-(3-ethyl-3,5,5-trimethylcyclohexyl)- 3-formylamino-2-hydroxybenzamideB-74 an individualized compound I carpropamid B-75 an individualizedcompound I diclocymet B-76 an individualized compound I mandipropamidB-77 an individualized compound I oxytetracyclin B-78 an individualizedcompound I silthiofam B-79 an individualized compound IN-(6-methoxypyridin-3-yl)cyclopropane- carboxamide B-80 anindividualized compound I azaconazole B-81 an individualized compound Ibitertanol B-82 an individualized compound I bromuconazole B-83 anindividualized compound I cyproconazole B-84 an individualized compoundI difenoconazole B-85 an individualized compound I diniconazole B-86 anindividualized compound I diniconazole-M B-87 an individualized compoundI epoxiconazole B-88 an individualized compound I fenbuconazole B-89 anindividualized compound I fluquinconazole B-90 an individualizedcompound I flusilazole B-91 an individualized compound I flutriafol B-92an individualized compound I hexaconazol B-93 an individualized compoundI imibenconazole B-94 an individualized compound I ipconazole B-95 anindividualized compound I metconazol B-96 an individualized compound Imyclobutanil B-97 an individualized compound I oxpoconazol B-98 anindividualized compound I paclobutrazol B-99 an individualized compoundI penconazole B-100 an individualized compound I propiconazole B-101 anindividualized compound I prothioconazole B-102 an individualizedcompound I simeconazole B-103 an individualized compound I tebuconazoleB-104 an individualized compound I tetraconazole B-105 an individualizedcompound I triadimefon B-106 an individualized compound I triadimenolB-107 an individualized compound I triticonazole B-108 an individualizedcompound I uniconazol B-109 an individualized compound I1-(4-chlorophenyl)-2-([1,2,4]triazol-1-yl)- cycloheptanol B-110 anindividualized compound I cyazofamid B-111 an individualized compound Iimazalil B-112 an individualized compound I imazalil-sulfate B-113 anindividualized compound I pefurazoat B-114 an individualized compound Iprochloraz B-115 an individualized compound I triflumizole B-116 anindividualized compound I benomyl B-117 an individualized compound Icarbendazim B-118 an individualized compound I fuberidazole B-119 anindividualized compound I thiabendazole B-120 an individualized compoundI ethaboxam B-121 an individualized compound I etridiazole B-122 anindividualized compound I hymexazole B-123 an individualized compound I2-(4-chlorophenyl)-N-[4-(3,4- dimethoxyphenyl)isoxazol-5-yl)-2-prop-2-ynyloxyacetamide B-124 an individualized compound I fluazinam B-125 anindividualized compound I pyrifenox B-126 an individualized compound I3-[5-(4-chlorophenyl)-2,3-dimethylisoxazolidin-3- yl]pyridine B-127 anindividualized compound I3-[5-(4-methylphenyl)-2,3-dimethylisoxazolidin-3- yl]pyridine B-128 anindividualized compound I 2,3,5,6-tetrachloro-4-methanesulfonylpyridineB-129 an individualized compound I3,4,5-trichloropyridine-2,6-dicarbonitrile B-130 an individualizedcompound I N-(1-(5-bromo-3-chloropyridin-2-yl)ethyl)-2,4-dichloronicotinamide B-131 an individualized compound IN-((5-bromo-3-chloropyridin-2-yl)methyl)- 2,4-dichloronicotinamide B-132an individualized compound I bupirimate B-133 an individualized compoundI cyprodinil B-134 an individualized compound I diflumetorim B-135 anindividualized compound I fenarimol B-136 an individualized compound Iferimzone B-137 an individualized compound I mepanipyrim B-138 anindividualized compound I nitrapyrin B-139 an individualized compound Inuarimol B-140 an individualized compound I pyrimethanil B-141 anindividualized compound I triforine B-142 an individualized compound Ifenpiclonil B-143 an individualized compound I fludioxonil B-144 anindividualized compound I aldimorph B-145 an individualized compound Idodemorph B-146 an individualized compound I dodemorph acetate B-147 anindividualized compound I fenpropimorph B-148 an individualized compoundI tridemorph B-149 an individualized compound I fenpropidin B-150 anindividualized compound I fluorimid B-151 an individualized compound Iiprodione B-152 an individualized compound I procymidon B-153 anindividualized compound I vinclozolin B-154 an individualized compound Ifamoxadon B-155 an individualized compound I fenamidon B-156 anindividualized compound I flutianil B-157 an individualized compound Iocthilinon B-158 an individualized compound I probenazole B-159 anindividualized compound I S-allyl5-amino-2-isopropyl-4-orthotoluylpyrazol-3- one-1-thiocarboxylate B-160an individualized compound I acibenzolar-S-methyl B-161 anindividualized compound I amisulbrom B-162 an individualized compound Ianilazin B-163 an individualized compound I blasticidin-S B-164 anindividualized compound I captafol B-165 an individualized compound Icaptan B-166 an individualized compound I chinomethionat B-167 anindividualized compound I dazomet B-168 an individualized compound Idebacarb B-169 an individualized compound I diclomezine B-170 anindividualized compound I difenzoquat B-171 an individualized compound Idifenzoquat methylsulfate B-172 an individualized compound I fenoxanilB-173 an individualized compound I folpet B-174 an individualizedcompound I oxolinic acid B-175 an individualized compound I piperalinB-176 an individualized compound I proquinazid B-177 an individualizedcompound I pyroquilon B-178 an individualized compound I quinoxyfenB-179 an individualized compound I triazoxid B-180 an individualizedcompound I tricyclazole B-181 an individualized compound I2-butoxy-6-iodo-3-propylchromen-4-one B-182 an individualized compound I5-chloro-1-(4,6-dimethoxypyrimidin-2-yl)-2-methyl- 1H-benzoimidazoleB-183 an individualized compound I5-chloro-7-(4-methylpiperidin-1-yl)-6-(2,4,6-trifluorophenyl)-[1,2,4]triazolo[1,5-a]pyrimidine B-184 anindividualized compound I6-(3,4-dichlorophenyl)-5-methyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-ylamine B-185 an individualized compound I6-(4-tert-butylphenyl)-5-methyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-ylamine B-186 an individualized compound I5-methyl-6-(3,5,5-trimethylhexyl)-[1,2,4]triazolo-[1,5-a]pyrimidin-7-ylamine B-187 an individualized compound I5-methyl-6-octyl-[1,2,4]triazolo[1,5-a]pyrimidin-7- ylamine B-188 anindividualized compound I6-methyl-5-octyl-[1,2,4]triazolo[1,5-a]pyrimidin-7- ylamine B-189 anindividualized compound I6-ethyl-5-octyl-[1,2,4]triazolo[1,5-a]pyrimidin-7- ylamine B-190 anindividualized compound I5-ethyl-6-octyl-[1,2,4]triazolo[1,5-a]pyrimidin-7- ylamine B-191 anindividualized compound I5-ethyl-6-(3,5,5-trimethylhexyl)-[1,2,4]triazolo[1,5-a]pyrimidin-7-ylamine B-192 an individualized compound I6-octyl-5-propyl-[1,2,4]triazolo[1,5-a]pyrimidin-7- ylamine B-193 anindividualized compound I5-methoxymethyl-6-octyl-[1,2,4]triazolo[1,5-a]- pyrimidin-7-ylamineB-194 an individualized compound I6-octyl-5-trifluoromethyl-[1,2,4]triazolo[1,5-a]- pyrimidin-7-ylamineB-195 an individualized compound I5-trifluoromethyl-6-(3,5,5-trimethylhexyl)-[1,2,4]-triazolo[1,5-a]pyrimidin-7-ylamine B-196 an individualized compound Iferbam B-197 an individualized compound I mancozeb B-198 anindividualized compound I maneb B-199 an individualized compound I metamB-200 an individualized compound I methasulphocarb B-201 anindividualized compound I metiram B-202 an individualized compound Ipropineb B-203 an individualized compound I thiram B-204 anindividualized compound I zineb B-205 an individualized compound I ziramB-206 an individualized compound I diethofencarb B-207 an individualizedcompound I benthiavalicarb B-208 an individualized compound Iflubenthiavalicarb B-209 an individualized compound I iprovalicarb B-210an individualized compound I propamocarb B-211 an individualizedcompound I propamocarb hydrochloride B-212 an individualized compound Ivaliphenal B-213 an individualized compound I 4-fluorophenylN-(1-(1-(4-cyanophenyl)- ethanesulfonyl)but-2-yl)carbamate B-214 anindividualized compound I dodin B-215 an individualized compound I dodinfree base B-216 an individualized compound I guazatine B-217 anindividualized compound I guazatine acetate B-218 an individualizedcompound I iminoctadine B-219 an individualized compound I iminoctadinetriacetate B-220 an individualized compound I iminoctadinetris(albesilate) B-221 an individualized compound I kasugamycin B-222 anindividualized compound I kasugamycin hydrochloride hydrate B-223 anindividualized compound I polyoxin B-224 an individualized compound Istreptomycin B-225 an individualized compound I validamycin A B-226 anindividualized compound I binapacryl B-227 an individualized compound Idicloran B-228 an individualized compound I dinobuton B-229 anindividualized compound I dinocap B-230 an individualized compound Initrothal-isopropyl B-231 an individualized compound I tecnazen B-232 anindividualized compound I fentin salts B-233 an individualized compoundI dithianon B-234 an individualized compound I isoprothiolan B-235 anindividualized compound I edifenphos B-236 an individualized compound Ifosetyl, fosetyl aluminum B-237 an individualized compound I iprobenfosB-238 an individualized compound I phosphorous acid and derivativesB-239 an individualized compound I pyrazophos B-240 an individualizedcompound I tolclofos-methyl B-241 an individualized compound Ichlorthalonil B-242 an individualized compound I dichlofluanid B-243 anindividualized compound I dichlorphen B-244 an individualized compound Iflusulfamide B-245 an individualized compound I hexachlorobenzene B-246an individualized compound I pencycuron B-247 an individualized compoundI pentachlorophenol and salts B-248 an individualized compound Iphthalide B-249 an individualized compound I quintozene B-250 anindividualized compound I thiophanate methyl B-251 an individualizedcompound I tolylfluanid B-252 an individualized compound IN-(4-chloro-2-nitrophenyl)-N-ethyl- 4-methylbenzenesulfonamide B-253 anindividualized compound I Bordeaux mixture B-254 an individualizedcompound I copper acetate B-255 an individualized compound I copperhydroxide B-256 an individualized compound I copper oxychloride B-257 anindividualized compound I basic copper sulfate B-258 an individualizedcompound I sulfur B-259 an individualized compound I biphenyl B-260 anindividualized compound I bronopol B-261 an individualized compound Icyflufenamid B-262 an individualized compound I cymoxanil B-263 anindividualized compound I diphenylamin B-264 an individualized compoundI metrafenon B-265 an individualized compound I mildiomycin B-266 anindividualized compound I oxine-copper B-267 an individualized compoundI prohexadione-calcium B-268 an individualized compound I spiroxaminB-269 an individualized compound I tolylfluanid B-270 an individualizedcompound I N-(cyclopropylmethoxyimino-(6-difluoromethoxy-2,3-difluorophenyl)methyl)-2-phenylacetamide B-271 an individualizedcompound I N′-(4-(4-chloro-3-trifluoromethylphenoxy)-2,5-dimethylphenyl)-N-ethyl-N-methylformamidine B-272 an individualizedcompound I N′-(4-(4-fluoro-3-trifluoromethylphenoxy)-2,5-dimethylphenyl)-N-ethyl-N-methylformamidine B-273 an individualizedcompound I N′-(2-methyl-5-trifluoromethyl-4-(3-tri-methylsilanylpropoxy)phenyl)-N-ethyl- N-methylformamidine B-274 anindividualized compound I N′-(5-difluoromethyl-2-methyl-4-(3-tri-methylsilanylpropoxy)phenyl)-N-ethyl- N-methylformamidine B-275 anindividualized compound I methylN-(1,2,3,4-tetrahydronaphthalene-1-yl)-2-{1-[2-(5-methyl-3-trifluoromethyl-pyrazol-1-yl)acetyl]piperidin-4-yl}thiazole-4-carboxamide B-276 an individualizedcompound I methyl N—(R)-(1,2,3,4-tetrahydronaphthalene-1-yl)-2-{1-[2-(5-methyl-3-trifluoromethylpyrazol-1-yl)acetyl}piperidin-4-yl}thiazole-4-carboxamide B-277 an individualizedcompound I 6-tert-butyl-8-fluoro-2,3-dimethylquinolin-4-y acetate B-278an individualized compound I6-tert-butyl-8-fluoro-2,3-dimethylquinolin-4-yl methoxyacetate B-279 anindividualized compound I carbaryl B-280 an individualized compound Icarbofuran B-281 an individualized compound I carbosulfan B-282 anindividualized compound I methomylthiodicarb B-283 an individualizedcompound I bifenthrin B-284 an individualized compound I cyfluthrinB-285 an individualized compound I cypermethrin B-286 an individualizedcompound I alpha-cypermethrin B-287 an individualized compound Izeta-cypermethrin B-288 an individualized compound I deltamethrin B-289an individualized compound I esfenvalerate B-290 an individualizedcompound I lambda-cyhalothrin B-291 an individualized compound Ipermethrin B-292 an individualized compound I tefluthrin B-293 anindividualized compound I diflubenzuron B-294 an individualized compoundI flufenoxuron B-295 an individualized compound I lufenuron B-296 anindividualized compound I teflubenzuron B-297 an individualized compoundI spirotetramate B-298 an individualized compound I clothianidin B-299an individualized compound I dinotefuran B-300 an individualizedcompound I imidacloprid B-301 an individualized compound I thiamethoxamB-302 an individualized compound I acetamiprid B-303 an individualizedcompound I thiacloprid B-304 an individualized compound I endosulfanB-305 an individualized compound I fipronil B-306 an individualizedcompound I abamectin B-307 an individualized compound I emamectin B-308an individualized compound I spinosad B-309 an individualized compound Ispinetoram B-310 an individualized compound I hydramethylnon B-311 anindividualized compound I chlorfenapyr B-312 an individualized compoundI fenbutatin oxide B-313 an individualized compound I indoxacarb B-314an individualized compound I metaflumizon B-315 an individualizedcompound I flonicamid B-316 an individualized compound I lubendiamidB-317 an individualized compound I chlorantraniliprol B-318 anindividualized compound I cyazypyr (HGW86) B-319 an individualizedcompound I cyflumetofen B-320 an individualized compound I acetochlorB-321 an individualized compound I dimethenamid B-322 an individualizedcompound I metolachlor B-323 an individualized compound I metazachlorB-324 an individualized compound I glyphosate B-325 an individualizedcompound I glufosinate B-326 an individualized compound I sulfosateB-327 an individualized compound I clodinafop B-328 an individualizedcompound I fenoxaprop B-329 an individualized compound I fluazifop B-330an individualized compound I haloxyfop B-331 an individualized compoundI paraquat B-332 an individualized compound I phenmedipham B-333 anindividualized compound I clethodim B-334 an individualized compound Icycloxydim B-335 an individualized compound I profoxydim B-336 anindividualized compound I sethoxydim B-337 an individualized compound Itepraloxydim B-338 an individualized compound I pendimethalin B-339 anindividualized compound I prodiamine B-340 an individualized compound Itrifluralin B-341 an individualized compound I acifluorfen B-342 anindividualized compound I bromoxynil B-343 an individualized compound Iimazamethabenz B-344 an individualized compound I imazamox B-345 anindividualized compound I imazapic B-346 an individualized compound Iimazapyr B-347 an individualized compound I imazaquin B-348 anindividualized compound I imazethapyr B-349 an individualized compound I2,4-dichlorophenoxyacetic acid (2,4-D) B-350 an individualized compoundI chloridazon B-351 an individualized compound I clopyralid B-352 anindividualized compound I fluroxypyr B-353 an individualized compound Ipicloram B-354 an individualized compound I picolinafen B-355 anindividualized compound I bensulfuron B-356 an individualized compound Ichlorimuron-ethyl B-357 an individualized compound I cyclosulfamuronB-358 an individualized compound I iodosulfuron B-359 an individualizedcompound I mesosulfuron B-360 an individualized compound Imetsulfuron-methyl B-361 an individualized compound I nicosulfuron B-362an individualized compound I rimsulfuron B-363 an individualizedcompound I triflusulfuron B-364 an individualized compound I atrazineB-365 an individualized compound I hexazinone B-366 an individualizedcompound I diuron B-367 an individualized compound I florasulam B-368 anindividualized compound I pyroxasulfon B-369 an individualized compoundI bentazone B-370 an individualized compound I cinidon-ethlyl B-371 anindividualized compound I cinmethylin B-372 an individualized compound Idicamba B-373 an individualized compound I diflufenzopyr B-374 anindividualized compound I quinclorac B-375 an individualized compound Iquinmerac B-376 an individualized compound I mesotrione B-377 anindividualized compound I saflufenacil B-378 an individualized compoundI topramezone

The active compounds specified above as component 2, their preparation,and their action against harmful fungi are known (cf.http://www.alanwood.net/pesticides/); they are available commercially.The compounds with IUPAC nomenclature, their preparation, and theirfungicidal activity are likewise known (cf. Can. J. Plant Sci. 48(6),587-94, 1968; EP-A 141 31.7; EP-A 152 031; EP-A 226 917; EP-A 243 970;EP-A 256 503; EP-A 428 941; EP-A 532 022; EP-A 1 028 125; EP-A 1 035122; EP-A 1 201 648; EP-A 1 122 244, JP 2002316902; DE 19650197; DE10021412; DE 102005009458; U.S. Pat. Nos. 3,296,272; 3,325,503; WO98/46608; WO 99/14187; WO 99/24413; WO 99/27783; WO 00/29404; WO00/46148; WO 00/65913; WO 01/54501; WO 01/56358; WO 02/22583; WO02/40431; WO 03/10149; WO 03/11853; WO 03/14103; WO 03/16286; WO03/53145; WO 03/61388; WO 03/66609; WO 03/74491; WO 04/49804; WO05/120234; WO 05/123689; WO 05/123690; WO 05/63721; WO 05/87772; WO05/87773; WO 06/15866; WO 06/87325; WO 06/87343; WO 07/82098; WO07/90624).

The compositions for mixtures of active compounds are prepared in aknown manner in the form of compositions comprising, in addition to theactive compounds, a solvent or a solid carrier, for example in themanner stated for compositions of the compounds I.

With respect to the customary ingredients of such compositions,reference is made to what was said about the compositions comprising thecompounds I.

The compositions for mixtures of active compounds are suitable asfungicides for controlling harmful fungi. They have excellent activityagainst a broad spectrum of phytopathogenic fungi including soil-bornepathogens originating in particular from the classes of thePlasmodiophoromycetes, Peronosporomycetes (syn. Oomycetes),Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes andDeuteromycetes (syn. Fungi imperfecti). Furthermore, reference is madeto what was said about the activity of the compounds I and thecompositions comprising the compounds I.

SYNTHESIS EXAMPLES

With appropriate modification of the starting materials, the proceduresgiven in the synthesis examples below were used to obtain furthercompounds I. The compounds produced in this manner are listed in Table Cbelow. The corresponding physical data can be found in Table D.

Example 1 Preparation ofN′-(4-{3-(3,4-dichlorophenoxy)-2-[methoxyimino]propoxy}-2,5-dimethylphenyl)-N-ethyl-N-methylformamidine(I-9)

1a) Preparation of O-methyl 1,3-dichloropropan-2-one oxime

7.0 g (55.1 mmol) of 1,3-dichloropropan-2-one were initially charged in50 ml of ethanol, and 4.6 g (55.1 mmol) of O-methyl hydroxylaminehydrochloride were added with stirring at from 20 to 25° C. This mixturewas stirred at from 20 to 25° C. for about 20 hours, adjusted to a pHbetween 8 and 9 using sat. NaHCO₃ solution and extracted with a methyltert-butyl ether (MTBE)/n-pentane mixture (4:1). After washing withwater, the combined organic phases were dried and then freed from thesolvent. The title compound (7.2 g) was directly used further.

1b) Preparation ofN′-(4-{3-chloro-2-[(E)-methoxyimino]propoxy}-2,5-dimethyl-phenyl)-N-ethyl-N-methylformamidine

At from 0 to 5° C., 1.16 g (48.5 mmol) of sodium hydride were added alittle at a time with stirring to 10.0 g (48.5 mmol) ofN-ethyl-N′-(4-hydroxy-2,5-dimethylphenyl)-N-methylformamidine (cf. WO2007/031513) in 50 ml of dimethylformamide (DMF), and the mixture wasstirred for one hour. At from 0 to 5° C., this solution was added withstirring to a mixture of 15.1 g (97.0 mmol) of O-methyl1,3-dichloropropan-2-one oxime and 5 ml of DMF, and stirring wascontinued at from 20 to 25° C. for about 5 hours. The mixture was addedto 500 ml of water and extracted with MTBE. The combined organic phaseswere dried and then freed from the solvent. Chromatography on aluminausing cyclohexane/MTBE mixtures gave 7.5 g of the title compound.

1c) Preparation ofN″-(4-{3-(3,4-dichlorophenoxy)-2-[methoxyimino]propoxy}-2,5-dimethylphenyl)-N-ethyl-N-methylformamidine

At from 20 to 25° C., 2.56 g (22.8 mmol) of potassium tert-butoxide wereadded a little at a time and with stirring to 3.72 g (22.8 mmol) of3,4-dichlorophenol dissolved in 10 ml of dimethyl sulfoxide (DMSO), andstirring was continued for 4 hours at from 20 to 25° C. With stirring,this mixture was added dropwise to 6.2 g (19.2 mmol) of the titlecompound from Example 1b) in 10 ml of DMSO, and stirring was continuedfor about 20 hours. The reaction mixture was added to 200 ml of water,the pH was adjusted to 10 using Na₂CO₃ and the mixture was extractedwith MTBE. The combined organic phases were dried and then freed fromthe solvent. Chromatography on alumina using cyclohexane/ethyl acetatemixtures gave 6.4 g of the title compound.

Example 2 Preparation ofN′-(4-{2-(3,4-dichlorophenyl)-2-[methoxyimino]-1-methyl-ethoxy}-2,5-dimethylphenyl)-N-ethyl-N-methylformamidine(I-97)

2a) Preparation of 2-chloro-1-(3,4-dichlorophenyl)propan-1-one O-methyloxime 2.0 g (8.4 mmol) of 2-chloro-1-(3,4-dichlorophenyl)propan-1-onewere initially charged in 15 ml of ethanol, and 0.7 g (8.4 mmol) ofO-methyl hydroxylamine hydrochloride were added with stirring at from 20to 25° C. The mixture was stirred for about 20 hours, adjusted to a pHof from 8 to 9 using sat. NaHCO₃ solution and extracted with anMTBE/n-pentane mixture (4:1). After washing with water, the combinedorganic phases were dried and then freed from the solvent. The titlecompound (1.3 g) was directly used further.

2b) Preparation ofN′-(4-{2-(3,4-dichlorophenyl)-2-[methoxyimino]-1-methylethoxy}-2,5-dimethylphenyl)-N-ethyl-N-methylformamidine

At from 20 to 25° C., 0.23 g (2.08 mmol) of potassium tert-butoxide wereadded a little at a time with stirring to 0.43 g (2.08 mmol) ofN-ethyl-N′-(4-hydroxy-2,5-dimethyl-phenyl)-N-methylformamidine dissolvedin 5 ml of DMSO, and the mixture was stirred at from 20 to 25° C. forabout one hour. With stirring, this mixture was added dropwise to 1.11 g(4.17 mmol) of the title compound from Example 2a) in 0.5 ml of DMSO,and the mixture was stirred for about 5 hours. The reaction mixture wasadded to 40 ml of water and extracted with MTBE. The combined organicphases were dried and then freed from the solvent. Chromatography onalumina using cyclohexane/ethyl acetate mixtures gave 1.26 g of thetitle compound.

Example 3 Preparation ofN-ethyl-N′-(4-{2-[methoxyimino]cyclohexyloxy}-2,5-dimethyl-phenyl)-N-methylformamidine(I-259)

3a) Preparation of 2-chlorocyclohexanone O-methyl oxime

3.0 g (22.6 mmol) of 2-chlorocyclohexanone were initially charged in 30ml of ethanol, and 1.9 g (22.6 mmol) of O-methyl hydroxylaminehydrochloride were added with stirring at from 20 to 25° C. This mixturewas stirred for about 20 hours at from 20 to 25° C., adjusted with sat.NaHCO₃ solution to a pH between 7 and 8 and extracted with ethylacetate. After washing with sat. NaCl solution, the combined organicphases were dried and then freed from the solvent. The title compound(3.4 g) was directly used further.

3b) Preparation ofN-ethyl-N′-(4-{2-[methoxyimino]cyclohexyloxy}-2,5-dimethyl-phenyl)-N-methylformamidine

At from 0 to 5° C., 239 mg (2.13 mmol) of potassium tert-butoxide and 26mg 18-crown-6 (0.10 mmol) were added a little at a time and withstirring to 200 mg (0.97 mmol) ofN-ethyl-N′-(4-hydroxy-2,5-dimethylphenyl)-N-methylformamidine (cf. WO2007/031513) in 3 ml of DMSO, and stirring was continued for about 15minutes. At from 0 to 5° C., a solution of 313 mg (1.94 mmol) of2-chlorocyclohexanone O-methyl oxime in 0.5 ml of DMSO was added to thismixture with stirring, and stirring was continued for about 20 hours atfrom 20 to 25° C. With cooling and a little at a time, 50 ml of waterwere added, and the mixture was extracted with MTBE. The combinedorganic phases were dried and then freed from the solvent.Cheomatography on alumina using cyclohexane/MTBE mixtures gave 100 mg ofthe title compound.

TABLE C Compounds of the formula I.9 I.9

No. R¹ R² (# defines the bond to the skeleton) R³ R⁵ R⁶ L¹ L² L³ C-1 CH₃pyrazol-1-yl H CH₃ CH₂CH₃ CH₃ CH₃ H C-2 CH₃1-methylpyrazol-5-yloxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-3 CH₃[1,2,4]-triazol-1-ylmethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-4 CH₃ COOCH₂CH₃ HCH₃ CH₂CH₃ CH₃ CH₃ H C-5 CH₃ CH₂OCH₃ H CH₃ CH₂CH₃ CH₃ CH₃ H C-6 CH₃COOCH₃ H CH₃ CH₂CH₃ CH₃ CH₃ H C-7 CH₃ 3-bromophenoxymethyl H CH₃ CH₂CH₃CH₃ CH₃ H C-8 CH₃ 3-chlorophenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-9 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-10 CH₃3-trifluoromethylphenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-11 CH₃4-chlorophenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-12 CH₃3-fluorophenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-13 CH₃4-fluorophenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-14 CH₃2,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-15 CH₃2-chloro-6-fluorophenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-16 CH₃3,5-dimethoxyphenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-17 CH₃3,4-dimethoxyphenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-18 CH₃3,4-methylenedioxyphenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-19 CH₃

H CH₃ CH₂CH₃ CH₃ CH₃ H C-20 CH₃

H CH₃ CH₂CH₃ CH₃ CH₃ H C-21 CH₃ 3-difluoromethoxyphenoxymethyl H CH₃CH₂CH₃ CH₃ CH₃ H C-22 CH₃ 4-chloro-3-(phenylcarbonyl)phenoxy- H CH₃CH₂CH₃ CH₃ CH₃ H methyl C-23 CH₃ 4-chloro-3-trifluoromethoxyphenoxy- HCH₃ CH₂CH₃ CH₃ CH₃ H methyl C-24 CH₃ 2,3-dichlorophenoxymethyl H CH₃CH₂CH₃ CH₃ CH₃ H C-25 CH₃ 3,5-dichlorophenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃H C-26 CH₃ 3-chloro-4-fluorophenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-27CH₃ 3-chloro-4-ethoxycarbonylphenoxy- H CH₃ CH₂CH₃ CH₃ CH₃ H methyl C-28CH₃ 3-chloro-4-(phenylcarbonyl)- H CH₃ CH₂CH₃ CH₃ CH₃ H phenoxymethylC-29 CH₃ 3-isopropylphenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-30 CH₃4-tert-butylphenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-31 CH₃(4-methylpyrazol-1-yl)methyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-32 CH₃

H CH₃ CH₂CH₃ CH₃ CH₃ H C-33 CH₃

H CH₃ CH₂CH₃ CH₃ CH₃ H C-34 CH₃ (imidazolazol-1-yl)methyl H CH₃ CH₂CH₃CH₃ CH₃ H C-35 CH₃ (pyrazol-1-yl)methyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-36 CH₃(pyridyl-3-oxy)methyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-37 CH₃(2-methylpyridyl-5-oxy)methyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-38 CH₃(3-chloropyridyl-5-oxy)methyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-39 CH₃(2-trifluoromethylpyridyl-5-oxy)- H CH₃ CH₂CH₃ CH₃ CH₃ H methyl C-40 CH₃(3-chloro-2-fluoropyridyl-5-oxy)- H CH₃ CH₂CH₃ CH₃ CH₃ H methyl C-41 CH₃(pyrimidinyl-5-oxy)methyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-42 CH₃(4-(4-methylphenyl)pyrazol-1-yl)- H CH₃ CH₂CH₃ CH₃ CH₃ H methyl C-43 CH₃(3-(4-chlorophenyl)-4-methylpyrazol- H CH₃ CH₂CH₃ CH₃ CH₃ H 1-yl)-methylC-44 CH₃ (3,4-dimethylpyrazol-1-yl)methyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-45CH₃ 3-phenylphenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-46 CH₃3-cyanophenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-47 CH₃4-cyanophenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-48 CH₃ isopropyloxymethylH CH₃ CH₂CH₃ CH₃ CH₃ H C-49 CH₃ cyanoaminomethyl H CH₃ CH₂CH₃ CH₃ CH₃ HC-50 CH₃ 2,2,2-trifluoroethoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-51 CH₃piperidin-1-ylmethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-52 CH₃morpholin-4-ylmethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-53 CH₃(4-chlorophenyl)methoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-54 CH₃(s)-1-methyl-2,2,2-trifluoroethyl- H CH₃ CH₂CH₃ CH₃ CH₃ H aminomethylC-55 CH₃ (r)-1-methyl-2,2,2-trifluoroethyl- H CH₃ CH₂CH₃ CH₃ CH₃ Haminomethyl C-56 CH₃ 2-(3,4-dimethoxyphenyl)ethoxy- H CH₃ CH₂CH₃ CH₃ CH₃H methyl C-57 CH₃ 2-(3,4-dimethoxyphenyl)ethylamino- H CH₃ CH₂CH₃ CH₃CH₃ H methyl C-58 CH₃ 2-propaneiminoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-59CH₃ 4-fluoro-3- H CH₃ CH₂CH₃ Cl H H trifluoromethylphenoxymethyl C-60CH₃ CH₂CN H CH₃ CH₂CH₃ CH₃ CH₃ H C-61 CH₂CH═CH₂ COOCH₂CH₃ H CH₃ CH₂CH₃CH₃ CH₃ H C-62 benzyl 2,4-dichlorophenyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-63 CH₃CH₃ COOCH₂CH₃ CH₃ CH₂CH₃ CH₃ CH₃ H C-64 CH₂CH═CH₂ CH₃ H CH₃ CH₂CH₃ CH₃CH₃ H C-65 CH₃ CH₂COOCH₂CH₃ H CH₃ CH₂CH₃ CH₃ CH₃ H C-66 E-3-chloroallylCH₃ H CH₃ CH₂CH₃ CH₃ CH₃ H C-67 4-chlorobenzyl CH₃ H CH₃ CH₂CH₃ CH₃ CH₃H C-68 CH₂CH₃ COOCH₂CH₃ H CH₃ CH₂CH₃ CH₃ CH₃ H C-69 CH₂CH₃3-trifluoromethylphenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-70E-3-chloroallyl 3-trifluoromethylphenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ HC-71 benzyl 3-trifluoromethylphenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-72CH₂COOCH₃ 3-trifluoromethylphenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-73C(CH₃)₃ 3-trifluoromethylphenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-74CH(CH₃)₂ 3-trifluoromethylphenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-75CH₂CH₂CH₃ 3-trifluoromethylphenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-76CH₂CF₃ 3-trifluoromethylphenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-77CH₂OCH₃ 3-trifluoromethylphenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-78CH₂CH₃ 3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-79E-3-chloroallyl 3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-80benzyl 3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-81 CH₂COOCH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-82 C(CH₃)₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-83 CH(CH₃)₂3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-84 CH₂CH₂CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-85 CH₂CF₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-86 CH₂OCH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-87 CH₂CH₃4-chloro-3-trifluoromethylphenoxy- H CH₃ CH₂CH₃ CH₃ CH₃ H methyl C-88E-3-chloroallyl 4-chloro-3-trifluoromethylphenoxy- H CH₃ CH₂CH₃ CH₃ CH₃H methyl C-89 benzyl 4-chloro-3-trifluoromethylphenoxy- H CH₃ CH₂CH₃ CH₃CH₃ H methyl C-90 CH₂COOCH₃ 4-chloro-3-trifluoromethylphenoxy- H CH₃CH₂CH₃ CH₃ CH₃ H methyl C-91 C(CH₃)₃ 4-chloro-3-trifluoromethylphenoxy-H CH₃ CH₂CH₃ CH₃ CH₃ H methyl C-92 CH(CH₃)₂4-chloro-3-trifluoromethylphenoxy- H CH₃ CH₂CH₃ CH₃ CH₃ H methyl C-93CH₂CH₂CH₃ 4-chloro-3-trifluoromethylphenoxy- H CH₃ CH₂CH₃ CH₃ CH₃ Hmethyl C-94 CH₂CF₃ 4-chloro-3-trifluoromethylphenoxy- H CH₃ CH₂CH₃ CH₃CH₃ H methyl C-95 CH₂OCH₃ 4-chloro-3-trifluoromethyl- H CH₃ CH₂CH₃ CH₃CH₃ H phenoxymethyl C-96 CH₃ 2,4-dichlorophenyl H CH₃ CH₂CH₃ CH₃ CH₃ HC-97 CH₃ 3,4-dichlorophenyl CH₃ CH₃ CH₂CH₃ CH₃ CH₃ H C-98 CH₃4-(methylsulfonylamino)phenyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-99 CH₃2,5-difluorophenyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-100 CH₃5-chloro-2-methoxyphenyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-101 CH₃4-tert-butylphenyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-102 CH₃ 2-methoxyphenyl HCH₃ CH₂CH₃ CH₃ CH₃ H C-103 CH₃ 4-chloro-2-fluoro-5-methylphenyl H CH₃CH₂CH₃ CH₃ CH₃ H C-104 CH₃ 4-methoxyphenyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-105CH₃ 4-trifluoromethylphenyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-106 CH₃ phenyl HCH₃ CH₂CH₃ CH₃ CH₃ H C-107 CH₃ 4-phenoxyphenyl H CH₃ CH₂CH₃ CH₃ CH₃ HC-108 CH₃ 4-(4-chlorophenoxy)phenyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-109 CH₃4-(3-chloro-5-trifluoromethylpyridin- H CH₃ CH₂CH₃ CH₃ CH₃ H2-yloxy)phenyl C-110 CH₃ 3-chlorophenyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-111 CH₃4-chlorophenyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-112 CH₃

H CH₃ CH₂CH₃ CH₃ CH₃ H C-113 CH₃ 4-phenylphenyl H CH₃ CH₂CH₃ CH₃ CH₃ HC-114 CH₃ 4-(4-chlorophenyl)phenyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-115 CH₃3,4-dichlorophenyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-116 CH₃3,4-ethylenedioxyphenyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-117 CH₃4-chloro-3-trifluoromethylphenoxy- H CH₃ CH₂CH₃ CH₃ CH₃ H methyl C-118CH₃ 4-fluoro-3-trifluoromethylphenoxy- H CH₃ CH₂CH₃ CH₃ CH₃ H methylC-119 CH₃ 3,5-bistrifluoromethylphenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ HC-120 CH₃ 2-chloro-5-trifluoromethylphenoxy- H CH₃ CH₂CH₃ CH₃ CH₃ Hmethyl C-121 CH₃ 2-fluoro-5-trifluoromethylphenoxy- H CH₃ CH₂CH₃ CH₃ CH₃H methyl C-122 CH₃ 3-fluoro-5-trifluoromethylphenoxy- H CH₃ CH₂CH₃ CH₃CH₃ H methyl C-123 CH₃ 2-fluoro-3-trifluoromethylphenoxy- H CH₃ CH₂CH₃CH₃ CH₃ H methyl C-124 CH₃ 2-chloro-3-trifluoromethylphenoxy- H CH₃CH₂CH₃ CH₃ CH₃ H methyl C-125 CH₃ 3-chloro-2-fluoro-5-trifluoromethyl- HCH₃ CH₂CH₃ CH₃ CH₃ H phenoxymethyl C-126 CH₃3-trifluoromethylphenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-127 CH₃3-trifluoromethyl-4- H CH₃ CH₂CH₃ CH₃ CH₃ H cyanophenoxymethyl C-128 CH₃2,5-dichlorophenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-129 CH₃2,3,6-trichlorophenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-130 CH₃3,4,5-trichlorophenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-131 CH₃2,4,5-trichlorophenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-132 CH₃2,3,4-trichlorophenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-133 CH₃

H CH₃ CH₂CH₃ CH₃ CH₃ H C-134 CH₃ 3-chloro-4-(3-chloro-5-trifluoro- H CH₃CH₂CH₃ CH₃ CH₃ H methylpyridin-2- yloxy)phenoxymethyl C-135 CH₃3-chloro-4-bromophenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-136 CH₃3-chloro-4-methylphenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-137 CH₃2-chloro-4-trifluoromethylphenoxy- H CH₃ CH₂CH₃ CH₃ CH₃ H methyl C-138CH₃ 4-methyl-2,3,5,6-tetrafluorophenoxy- H CH₃ CH₂CH₃ CH₃ CH₃ H methylC-139 CH₃ 2,3,5,6-tetrafluoro-4-trifluoromethyl- H CH₃ CH₂CH₃ CH₃ CH₃ Hphenoxymethyl C-140 CH₃ 4-methylphenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ HC-141 CH₃

H CH₃ CH₂CH₃ CH₃ CH₃ H C-142 CH₃ 4-chloro-2-phenylphenoxymethyl H CH₃CH₂CH₃ CH₃ CH₃ H C-143 CH₃ 4-chloro-3,5-dimethylphenoxymethyl H CH₃CH₂CH₃ CH₃ CH₃ H C-144 CH₃ 4-chloro-3-methylphenoxymethyl H CH₃ CH₂CH₃CH₃ CH₃ H C-145 CH₃ 4-chloro-3-ethylphenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ HC-146 CH₃ 2,4-dichloro-5-methoxyphenoxy- H CH₃ CH₂CH₃ CH₃ CH₃ H methylC-147 CH₃ 4-chloro-1-naphthoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-148 CH₃4-chloro-2,5-dimethylphenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-149 CH₃3,4-difluorophenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-150 CH₃5-bromo-2-chloro-4-iodophenoxy- H CH₃ CH₂CH₃ CH₃ CH₃ H methyl C-151 CH₃5-bromo-2-chloro-4-fluorophenoxy- H CH₃ CH₂CH₃ CH₃ CH₃ H methyl C-152CH₃ 3-phenoxyphenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-153 CH₃3-(4-chlorophenoxy)phenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₃ H C-154 CH₃3,4-dichlorophenoxymethyl H —CH₂CH₂CH₂CH(CH₃)— CH₃ CH₃ CH₃ C-155 CH₃N-ethyl-N-methylarninomethyl H —CH₂CH₂CH₂CH(CH₃)— CH₃ CH₃ CH₃ C-156 CH₃CH₂OCH₃ H —CH₂CH₂CH₂CH(CH₃)— CH₃ CH₃ CH₃ C-157 CH₃ NH₂ H CH₃ CH₂CH₃ CH₃CH₃ H C-158 CH₃

H CH₃ CH₂CH₃ CH₃ CH₃ H C-159 CH₃ 3-bromophenoxymethyl H CH₃ CH(CH₃)₂ CH₃CH₃ H C-160 CH₃ 3,4-dichlorophenoxymethyl H CH₃ CH(CH₃)₂ CH₃ CH₃ H C-161CH₃ 3-trifluoromethylphenoxymethyl H CH₃ CH(CH₃)₂ CH₃ CH₃ H C-162 CH₃3-bromophenoxymethyl H CH₃ (CH₂)₂CH₃ CH₃ CH₃ H C-163 CH₃3,4-dichlorophenoxymethyl H CH₃ (CH₂)₂CH₃ CH₃ CH₃ H C-164 CH₃3-trifluoromethylphenoxymethyl H CH₃ (CH₂)₂CH₃ CH₃ CH₃ H C-165 CH₃3-bromophenoxymethyl H CH₃ sec-butyl CH₃ CH₃ H C-166 CH₃3,4-dichlorophenoxymethyl H CH₃ sec-butyl CH₃ CH₃ H C-167 CH₃3-trifluoromethylphenoxymethyl H CH₃ sec-butyl CH₃ CH₃ H C-168 CH₃3-bromophenoxymethyl H CH₃ CH₂CH═CH₂ CH₃ CH₃ H C-169 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH═CH₂ CH₃ CH₃ H C-170 CH₃3-trifluoromethylphenoxymethyl H CH₃ CH₂CH═CH₂ CH₃ CH₃ H C-171 CH₃3-bromophenoxymethyl H CH₃ cyclopropyl CH₃ CH₃ H C-172 CH₃3,4-dichlorophenoxymethyl H CH₃ cyclopropyl CH₃ CH₃ H C-173 CH₃3-trifluoromethylphenoxymethyl H CH₃ cyclopropyl CH₃ CH₃ H C-174 CH₃3-bromophenoxymethyl H H CH(CH₃)CF₃ CH₃ CH₃ H C-175 CH₃3,4-dichlorophenoxymethyl H H CH(CH₃)CF₃ CH₃ CH₃ H C-176 CH₃3-trifluoromethylphenoxymethyl H H CH(CH₃)CF₃ CH₃ CH₃ H C-177 CH₃3-bromophenoxymethyl H —CH₂CH₂CH₂CH₂— CH₃ CH₃ CH₃ C-178 CH₃3,4-dichlorophenoxymethyl H —CH₂CH₂CH₂CH₂— CH₃ CH₃ CH₃ C-179 CH₃3-trifluoromethylphenoxymethyl H —CH₂CH₂CH₂CH₂— CH₃ CH₃ CH₃ C-180 CH₃3-bromophenoxymethyl H —CH₂CH₂CH₂CH₂CH₂— CH₃ CH₃ CH₃ C-181 CH₃3,4-dichlorophenoxymethyl H —CH₂CH₂CH₂CH₂CH₂— CH₃ CH₃ CH₃ C-182 CH₃3-trifluoromethylphenoxymethyl H —CH₂CH₂CH₂CH₂CH₂— CH₃ CH₃ CH₃ C-183 CH₃3-bromophenoxymethyl H —CH(CH₃)CH₂CH₂CH₂CH₂— CH₃ CH₃ CH₃ C-184 CH₃3,4-dichlorophenoxymethyl H —CH(CH₃)CH₂CH₂CH₂CH₂— CH₃ CH₃ CH₃ C-185 CH₃3-trifluoromethylphenoxymethyl H —CH(CH₃)CH₂CH₂CH₂CH₂— CH₃ CH₃ CH₃ C-186CH₃ 3-bromophenoxymethyl H —CH₂CH₂CH(CH₃)CH₂CH₂— CH₃ CH₃ CH₃ C-187 CH₃3,4-dichlorophenoxymethyl H —CH₂CH₂CH(CH₃)CH₂CH₂— CH₃ CH₃ CH₃ C-188 CH₃3-trifluoromethylphenoxymethyl H —CH₂CH₂CH(CH₃)CH₂CH₂— CH₃ CH₃ CH₃ C-189CH₃ 3-bromophenoxymethyl H —CH₂CH₂OCH₂CH₂— CH₃ CH₃ CH₃ C-190 CH₃3,4-dichlorophenoxymethyl H —CH₂CH₂OCH₂CH₂— CH₃ CH₃ CH₃ C-191 CH₃3-trifluoromethylphenoxymethyl H —CH₂CH₂OCH₂CH₂— CH₃ CH₃ CH₃ C-192 CH₃3-bromophenoxymethyl H CH₃ OCH₃ CH₃ CH₃ H C-193 CH₃3,4-dichlorophenoxymethyl H CH₃ OCH₃ CH₃ CH₃ H C-194 CH₃3-trifluoromethylphenoxymethyl H CH₃ OCH₃ CH₃ CH₃ H C-195 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ H H H C-196 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ CH₃ H H C-197 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ CH₂CH₃ H H C-198 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ Cl H H C-199 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ CF₃ H H C-200 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ CHF₂ H H C-201 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ CH₂F H H C-202 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ H CH₃ H C-203 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ CH₂CH₃ CH₃ H C-204 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ CH(CH₃)₂ CH₃ H C-205 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ C(CH₃)₃ CH₃ H C-206 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ OCH₃ CH₃ H C-207 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ OCH₂CH₃ CH₃ H C-208 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ Cl CH₃ H C-209 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ Br CH₃ H C-210 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ F CH₃ H C-211 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ CN CH₃ H C-212 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ CF₃ CH₃ H C-213 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ CHF₂ CH₃ H C-214 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ CH₂F CH₃ H C-215 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ CH₂CF₃ CH₃ H C-216 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ CHFCHF₂ CH₃ H C-217 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ OCF₃ CH₃ H C-218 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ OCHF₂ CH₃ H C-219 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ CCl₃ CH₃ H C-220 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ CHCl₂ CH₃ H C-221 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ H CH₂CH₃ H C-222 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ CH₃ CH₂CH₃ H C-223 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ CH₃ CH(CH₃)₂ H C-224 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ CH₃ OCH₃ H C-225 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ OCH₃ OCH₃ H C-226 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ CH₃ Cl H C-227 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ H Cl H C-228 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ CF₃ Cl H C-229 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ OCH₃ Cl H C-230 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ CHF₂ Cl H C-231 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ CFH₂ Cl H C-232 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ Cl Cl H C-233 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ CH₃ Br H C-234 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ H Br H C-235 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ CF₃ Br H C-236 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ OCH₃ Br H C-237 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ CHF₂ Br H C-238 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ CH₂F Br H C-239 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ Cl Br H C-240 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ OCF₃ Br H C-241 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ CH₃ F H C-242 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ H F H C-243 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ CH₃ CF₃ H C-244 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ H CF₃ H C-245 —CH₂CH₂— H CH₃CH₂CH₃ CH₃ CH₃ CH₃ C-246 —CH₂CH₂CH₂— H CH₃ CH₂CH₃ CH₃ CH₃ CH₃ C-247—CH₂CH₂CH₂CH₂— H CH₃ CH₂CH₃ CH₃ CH₃ CH₃ C-248 CH₃ —CH₂CH₂CH₂— CH₃ CH₂CH₃CH₃ CH₃ CH₃ C-249 CH₂CH₃ —CH₂CH₂CH₂— CH₃ CH₂CH₃ CH₃ CH₃ CH₃ C-250CH₂CH₂CH₃ —CH₂CH₂CH₂— CH₃ CH₂CH₃ CH₃ CH₃ CH₃ C-251 CH(CH₃)₂ —CH₂CH₂CH₂—CH₃ CH₂CH₃ CH₃ CH₃ CH₃ C-252 CH₂CH₂CH₂CH₃ —CH₂CH₂CH₂— CH₃ CH₂CH₃ CH₃ CH₃CH₃ C-253 C(CH₃)₃ —CH₂CH₂CH₂— CH₃ CH₂CH₃ CH₃ CH₃ CH₃ C-254E-3-chloroallyl —CH₂CH₂CH₂— CH₃ CH₂CH₃ CH₃ CH₃ CH₃ C-255 benzyl—CH₂CH₂CH₂— CH₃ CH₂CH₃ CH₃ CH₃ CH₃ C-256 phenyl —CH₂CH₂CH₂— CH₃ CH₂CH₃CH₃ CH₃ CH₃ C-257 CH₂OCH₃ —CH₂CH₂CH₂— CH₃ CH₂CH₃ CH₃ CH₃ CH₃ C-258CH₂CF₃ —CH₂CH₂CH₂— CH₃ CH₂CH₃ CH₃ CH₃ CH₃ C-259 CH₃ —CH₂CH₂CH₂CH₂— CH₃CH₂CH₃ CH₃ CH₃ CH₃ C-260 CH₂CH₃ —CH₂CH₂CH₂CH₂— CH₃ CH₂CH₃ CH₃ CH₃ CH₃C-261 CH₂CH₂CH₃ —CH₂CH₂CH₂CH₂— CH₃ CH₂CH₃ CH₃ CH₃ CH₃ C-262 CH(CH₃)₂—CH₂CH₂CH₂CH₂— CH₃ CH₂CH₃ CH₃ CH₃ CH₃ C-263 CH₂CH₂CH₂CH₃ —CH₂CH₂CH₂CH₂—CH₃ CH₂CH₃ CH₃ CH₃ CH₃ C-264 C(CH₃)₃ —CH₂CH₂CH₂CH₂— CH₃ CH₂CH₃ CH₃ CH₃CH₃ C-265 E-3-chloroallyl —CH₂CH₂CH₂CH₂— CH₃ CH₂CH₃ CH₃ CH₃ CH₃ C-266benzyl —CH₂CH₂CH₂CH₂— CH₃ CH₂CH₃ CH₃ CH₃ CH₃ C-267 phenyl —CH₂CH₂CH₂CH₂—CH₃ CH₂CH₃ CH₃ CH₃ CH₃ C-268 CH₂OCH₃ —CH₂CH₂CH₂CH₂— CH₃ CH₂CH₃ CH₃ CH₃CH₃ C-269 CH₂CF₃ —CH₂CH₂CH₂CH₂— CH₃ CH₂CH₃ CH₃ CH₃ CH₃ C-270 CH₃—CH₂CH₂CH₂CH₂CH₂— CH₃ CH₂CH₃ CH₃ CH₃ CH₃ C-271 CH₂CH₃ —CH₂CH₂CH₂CH₂CH₂—CH₃ CH₂CH₃ CH₃ CH₃ CH₃ C-272 CH₂CH₂CH₃ —CH₂CH₂CH₂CH₂CH₂— CH₃ CH₂CH₃ CH₃CH₃ CH₃ C-273 CH(CH₃)₂ —CH₂CH₂CH₂CH₂CH₂— CH₃ CH₂CH₃ CH₃ CH₃ CH₃ C-274CH₂CH₂CH₂CH₃ —CH₂CH₂CH₂CH₂CH₂— CH₃ CH₂CH₃ CH₃ CH₃ CH₃ C-275 C(CH₃)₃—CH₂CH₂CH₂CH₂CH₂— CH₃ CH₂CH₃ CH₃ CH₃ CH₃ C-276 E-3-chloroallyl—CH₂CH₂CH₂CH₂CH₂— CH₃ CH₂CH₃ CH₃ CH₃ CH₃ C-277 benzyl —CH₂CH₂CH₂CH₂CH₂—CH₃ CH₂CH₃ CH₃ CH₃ CH₃ C-278 phenyl —CH₂CH₂CH₂CH₂CH₂— CH₃ CH₂CH₃ CH₃ CH₃CH₃ C-279 CH₂OCH₃ —CH₂CH₂CH₂CH₂CH₂— CH₃ CH₂CH₃ CH₃ CH₃ CH₃ C-280 CH₂CF₃—CH₂CH₂CH₂CH₂CH₂— CH₃ CH₂CH₃ CH₃ CH₃ CH₃ C-281 CH₃*—(CH)[O-(3,4-dichlorophenyl)]-(CH₂)₂— CH₃ CH₂CH₃ CH₃ CH₃ CH₃ C-282 CH₃*—(CH)[O-(3-bromophenyl)]-(CH₂)₂— CH₃ CH₂CH₃ CH₃ CH₃ CH₃ C-283 CH₃*—(CH)[O-(3-trifluoromethylphenyl)]-(CH₂)₂— CH₃ CH₂CH₃ CH₃ CH₃ CH₃ C-284CH₃ *—(CH)[O-(3,4-dichlorophenyl)]-(CH₂)₃— CH₃ CH₂CH₃ CH₃ CH₃ CH₃ C-285CH₃ *—(CH)[O-(3-bromophenyl)]-(CH₂)₃— CH₃ CH₂CH₃ CH₃ CH₃ CH₃ C-286 CH₃*—(CH)[O-3-(trifluoromethylphenyl)]-(CH₂)₃— CH₃ CH₂CH₃ CH₃ CH₃ CH₃ C-287—CH-(4-chlorophenyl)-(CH₂)₂—* H CH₃ CH₂CH₃ CH₃ CH₃ CH₃ C-288—CH-((R)-4-chlorophenyl)-(CH₂)₂—* H CH₃ CH₂CH₃ CH₃ CH₃ CH₃ C-289—CH-((S)-4-chlorophenyl)-(CH₂)₂—* H CH₃ CH₂CH₃ CH₃ CH₃ CH₃ C-290—CH-(3-trifluoromethylphenyl)-(CH₂)₂—* H CH₃ CH₂CH₃ CH₃ CH₃ CH₃ C-291—CH(-3,4-dimethoxyphenyl)-(CH₂)₂—* H CH₃ CH₂CH₃ CH₃ CH₃ CH₃ C-292

C-293

C-294

C-295 —CO—CH₂—* H CH₃ CH₂CH₃ CH₃ CH₃ H C-296 —CO—CH₂—* CH₃ CH₃ CH₂CH₃CH₃ CH₃ H C-297 —CO—CH-(4-chlorobenzyl)-* H CH₃ CH₂CH₃ CH₃ CH₃ H C-298—CO—CH-(4-chlorobenzyl)-* CH₃ CH₃ CH₂CH₃ CH₃ CH₃ H C-299 CH₃4-fluoro-2-chlorophenoxymethyl H CH₃ CH₂CH₃ CH₃ H CH₃ C-300 CH₃

H CH₃ CH₂CH₃ CH₃ H CH₃ C-301 CH₃ 2,4,5-trifluorophenoxymethyl H CH₃CH₂CH₃ CH₃ H CH₃ C-302 CH₃ 4,6-dimethyl-2-(1-oxo-1-ethyl)- H CH₃ CH₂CH₃CH₃ H CH₃ phenoxymethyl C-303 CH₃ 2,6-difluorophenoxymethyl H CH₃ CH₂CH₃CH₃ H CH₃ C-304 CH₃ 4-fluoro-2-trifluoromethylphenoxy- H CH₃ CH₂CH₃ CH₃H CH₃ methyl C-305 CH₃ 2,4-difluorophenoxymethyl H CH₃ CH₂CH₃ CH₃ H CH₃C-306 CH₃ 3-chloro-4-fluorophenoxymethyl H CH₃ CH₂CH₃ CH₃ H CH₃ C-307CH₃ 4-fluoro-2-methylphenoxymethyl H CH₃ CH₂CH₃ CH₃ H CH₃ C-308 CH₃2,3,4-trifluorophenoxymethyl H CH₃ CH₂CH₃ CH₃ H CH₃ C-309 CH₃2,6-dimethylphenoxymethyl H CH₃ CH₂CH₃ CH₃ H CH₃ C-310 CH₃4,5-difluoro-2-methylphenoxymethyl H CH₃ CH₂CH₃ CH₃ H CH₃ C-311 CH₃3-bromo-4-fluorophenoxymethyl H CH₃ CH₂CH₃ CH₃ H CH₃ C-312 CH₃2-bromo-4,5-difluorophenoxymethyl H CH₃ CH₂CH₃ CH₃ H CH₃ C-313 CH₃2,4,6-trifluorophenoxymethyl H CH₃ CH₂CH₃ CH₃ H CH₃ C-314 CH₃3,4,5-trifluorophenoxymethyl H CH₃ CH₂CH₃ CH₃ H CH₃ C-315 CH₃4-fluoro-3-methylphenoxymethyl H CH₃ CH₂CH₃ CH₃ H CH₃ C-316 CH₃2,6-dichloro-4-fluorophenoxymethyl H CH₃ CH₂CH₃ CH₃ H CH₃ C-317 CH₃2,6-dichloro-4-methylphenoxymethyl H CH₃ CH₂CH₃ CH₃ H CH₃ C-318 CH₂CH₃2-fluoro-5-trifluoromethylphenoxy- H CH₃ CH₂CH₃ CH₃ H CH₃ methyl C-319CH₂CH₃ 4-fluoro-3-trifluoromethylphenoxy- H CH₃ CH₂CH₃ CH₃ H CH₃ methylC-320 CH₂CH₃ 3-bromophenoxymethyl H CH₃ CH₂CH₃ CH₃ H CH₃ C-321 CH₂CH₃2,3,6-trichlorophenoxymethyl H CH₃ CH₂CH₃ CH₃ H CH₃ C-322 CH₂CH₃2-chloro-6-fluorophenoxymethyl H CH₃ CH₂CH₃ CH₃ H CH₃ C-323 CH₂CH₃3,4-difluorophenoxymethyl H CH₃ CH₂CH₃ CH₃ H CH₃ C-324 CH₂CH₃3,4-dichlorophenyl CH₃ CH₃ CH₂CH₃ CH₃ H CH₃ C-325 CH₂CH₃2,4-dichlorophenyl H CH₃ CH₂CH₃ CH₃ H CH₃ C-326 4-Methoxybenzyl3,4-dichlorophenyl CH₃ CH₃ CH₂CH₃ CH₃ H CH₃ C-327 4-Methoxybenzyl3,4-dichlorophenyl H CH₃ CH₂CH₃ CH₃ H CH₃ C-328 CH₃ CH═NOCH₃ H CH₃CH₂CH₃ CH₃ H CH₃ C-329 CH₃ 3-methylpyrazol-1-ylmethyl H CH₃ CH₂CH₃ CH₃ HCH₃ C-330 CH₃ 4-phenylpyrazol-1-ylmethyl H CH₃ CH₂CH₃ CH₃ H CH₃ C-331Cyclopropylmethyl CH₃ 3-Trifluoro- CH₃ CH₂CH₃ CH₃ H CH₃ methyl- phenylC-332 Cyclopropylmethyl CH₃ H CH₃ CH₂CH₃ CH₃ H CH₃ C-333 CH₃methoxycarbonylmethyl H CH₃ CH₂CH₃ CH₃ H CH₃ C-334 4-Chlorobenzyl CH₃COOCH₃ CH₃ CH₂CH₃ CH₃ H CH₃ C-335 CH₃4-(4-fluorophenyl)pyrazol-1-ylmethyl H CH₃ CH₂CH₃ CH₃ H CH₃ C-336 CH₃CH₂CH₃ H CH₃ CH₂CH₃ CH₃ H CH₃ C-337 Cyclopropylmethyl C(CH₃)₃ H CH₃CH₂CH₃ CH₃ H CH₃ C-338 CH₃ CH₂CH₃ COOCH₃ CH₃ CH₂CH₃ CH₃ H CH₃ C-339CH₂CH₃ CH₃ COOCH₃ CH₃ CH₂CH₃ CH₃ H CH₃ C-340 CH₃ CH₃ COOCH₃ CH₃ CH₂CH₃CH₃ H CH₃ C-341 CH₃ CH₃ CH₃ CH₃ CH₂CH₃ CH₃ H CH₃ C-342 CH₃3,5-bis(2-methylphenyl)pyrazol-1-ylmethyl H CH₃ CH₂CH₃ CH₃ H CH₃ C-343CH₃

H CH₃ CH₂CH₃ CH₃ H CH₃ C-344 CH₃

CH₃ CH₃ CH₂CH₃ CH₃ H CH₃ C-345 CH₃3-(2,4-dichlorophenyl)pyrazol-1-ylmethyl H CH₃ CH₂CH₃ CH₃ H CH₃ C-346CH₃ 4-chloropyrazol-1-ylmethyl H CH₃ CH₂CH₃ CH₃ H CH₃ C-347 CH₃4-methyl-3-phenylpyrazol-1-ylmethyl H CH₃ CH₂CH₃ CH₃ H CH₃ C-348 CH₃3,4,5-trimethylpyrazol-1-ylmethyl H CH₃ CH₂CH₃ CH₃ H CH₃ C-349 CH₃

H CH₃ CH₂CH₃ CH₃ H CH₃ C-350 CH₃ 3-methyl-4-phenylpyrazol-1-ylmethyl HCH₃ CH₂CH₃ CH₃ H CH₃ C-351 CH₃ 3,5-dimethylpyrazol-1-ylmethyl H CH₃CH₂CH₃ CH₃ H CH₃ C-352 CH₃ 3-isopropylpyrazol-1-ylmethyl H CH₃ CH₂CH₃CH₃ H CH₃ C-353 Allyl CH₃ H CH₃ CH₂CH₃ CH₃ H CH₃ C-354

CH₃ H CH₃ CH₂CH₃ CH₃ H CH₃ C-355 CH₂CH₃ CH₃ H CH₃ CH₂CH₃ CH₃ H CH₃ C-356CH₂CH(CH₃) CH₃ H CH₃ CH₂CH₃ CH₃ H CH₃ C-357 2-Chlorobenzyl CH₃ H CH₃CH₂CH₃ CH₃ H CH₃ C-358 3-Chlorobenzyl CH₃ H CH₃ CH₂CH₃ CH₃ H CH₃ C-359

CH₃ H CH₃ CH₂CH₃ CH₃ H CH₃ C-360 Benzyl CH₃ H CH₃ CH₂CH₃ CH₃ H CH₃ C-3614-Cyanobenzyl CH₃ H CH₃ CH₂CH₃ CH₃ H CH₃ C-362 3-Ethoxybenzyl CH₃ H CH₃CH₂CH₃ CH₃ H CH₃ C-363 3-Fluorobenzyl CH₃ H CH₃ CH₂CH₃ CH₃ H CH₃ C-3642-Chloro-2-propen-1-yl CH₃ H CH₃ CH₂CH₃ CH₃ H CH₃ C-365 2-Buten-1-yl CH₃H CH₃ CH₂CH₃ CH₃ H CH₃ C-366

CH₃ H CH₃ CH₂CH₃ CH₃ H CH₃ C-367

CH₃ H CH₃ CH₂CH₃ CH₃ H CH₃ C-368

CH₃ H CH₃ CH₂CH₃ CH₃ H CH₃ C-369

CH₃ H CH₃ CH₂CH₃ CH₃ H CH₃ C-370

CH₃ H CH₃ CH₂CH₃ CH₃ H CH₃ C-371 3-trifluoromethylbenzyl CH₃ H CH₃CH₂CH₃ CH₃ H CH₃ C-372 3,4-dichlorobenzyl CH₃ H CH₃ CH₂CH₃ CH₃ H CH₃C-373 4-methylbenzyl CH₃ H CH₃ CH₂CH₃ CH₃ H CH₃ C-374 2-phenylbenzyl CH₃H CH₃ CH₂CH₃ CH₃ H CH₃ C-375 3-methyl-2-buten-1-yl CH₃ H CH₃ CH₂CH₃ CH₃H CH₃ C-376 CH(CH₃)₂ CH₃ H CH₃ CH₂CH₃ CH₃ H CH₃ C-377 (CH₂)₂CH₃ CH₃ HCH₃ CH₂CH₃ CH₃ H CH₃ C-378 4-tert-butylbenzyl CH₃ H CH₃ CH₂CH₃ CH₃ H CH₃C-379 2,4-difluorobenzyl CH₃ H CH₃ CH₂CH₃ CH₃ H CH₃ C-380 (CH₂)₃CH₃ CH₃H CH₃ CH₂CH₃ CH₃ H CH₃ C-381 cyclohexylmethyl CH₃ H CH₃ CH₂CH₃ CH₃ H CH₃C-382 propargyl CH₃ H CH₃ CH₂CH₃ CH₃ H CH₃ C-383 (CH₂)₅CH₃ CH₃ H CH₃CH₂CH₃ CH₃ H CH₃ C-384 2-ethoxyethyl CH₃ H CH₃ CH₂CH₃ CH₃ H CH₃ C-3851-butyn-3-yl CH₃ H CH₃ CH₂CH₃ CH₃ H CH₃ C-386 5-methyl-3-hexen-1-yl CH₃H CH₃ CH₂CH₃ CH₃ H CH₃ C-387 CH₂CH₃ CH₃ 3-Trifluor- CH₃ CH₂CH₃ CH₃ H CH₃methylphenyl C-388 CH₃ CH₃ 3-Trifluor- CH₃ CH₂CH₃ CH₃ H CH₃ methylphenylC-389 2-phenoxyethyl CH₂CH₃ H CH₃ CH₂CH₃ CH₃ H CH₃ C-390 4-chlorobenzylCH₂CH₃ H CH₃ CH₂CH₃ CH₃ H CH₃ C-391 CH₂CH₃ CH₂CH₃ H CH₃ CH₂CH₃ CH₃ H CH₃C-392 CH₃ CH(CH₃)₃ H CH₃ CH₂CH₃ CH₃ H CH₃ C-393 cyclopropylmethyl CH₃CH₃ CH₃ CH₂CH₃ CH₃ H CH₃ C-394 2-phenoxyethyl CH₃ CH₃ CH₃ CH₂CH₃ CH₃ HCH₃ C-395 4-chlorobenzyl CH₃ CH₃ CH₃ CH₂CH₃ CH₃ H CH₃ C-396 CH₂CH₃ CH₃CH₃ CH₃ CH₂CH₃ CH₃ H CH₃ C-397 2,4-difluorobenzyl 3,4-dichlorophenyl CH₃CH₃ CH₂CH₃ CH₃ H CH₃ C-398 2,4-difluorobenzyl 2,4-dichlorophenyl H CH₃CH₂CH₃ CH₃ H CH₃ C-399

3,4-dichlorophenyl CH₃ CH₃ CH₂CH₃ CH₃ H CH₃ C-400

2,4-dichlorophenyl H CH₃ CH₂CH₃ CH₃ H CH₃ C-401

3,4-dichlorophenyl CH₃ CH₃ CH₂CH₃ CH₃ H CH₃ C-402

2,4-dichlorophenyl H CH₃ CH₂CH₃ CH₃ H CH₃ C-403

3,4-dichlorophenyl CH₃ CH₃ CH₂CH₃ CH₃ H CH₃ C-404

2,4-dichlorophenyl H CH₃ CH₂CH₃ CH₃ H CH₃ C-405 2-chlorobenzyl2,4-dichlorophenyl H CH₃ CH₂CH₃ CH₃ H CH₃ C-406 CH₃ 2,4-difluorophenylCH₃ CH₃ CH₂CH₃ CH₃ H CH₃ C-407 CH₃ 4-bromophenyl CH₃ CH₃ CH₂CH₃ CH₃ HCH₃ C-408 CH₃ 3,4-difluorophenyl H CH₃ CH₂CH₃ CH₃ H CH₃ C-409 CH₃ phenylCH₃ CH₃ CH₂CH₃ CH₃ H CH₃ C-410 CH₃ 4-methoxyphenyl H CH₃ CH₂CH₃ CH₃ HCH₃ C-411 CH₃

H CH₃ CH₂CH₃ CH₃ H CH₃ C-412 CH₃ 4-bromophenyl H CH₃ CH₂CH₃ CH₃ H CH₃C-413 CH₃ 4-phenylphenyl H CH₃ CH₂CH₃ CH₃ H CH₃ C-414 CH₃ 4-chlorophenylH CH₃ CH₂CH₃ CH₃ H CH₃ C-415 CH₃ 2,4-difluorophenyl H CH₃ CH₂CH₃ CH₃ HCH₃ C-416 CH₃ 4-fluorophenyl H CH₃ CH₂CH₃ CH₃ H CH₃ C-417 CH₃ phenyl HCH₃ CH₂CH₃ CH₃ H CH₃ C-418 CH₃

H CH₃ CH₂CH₃ CH₃ H CH₃ C-419 CH₃ 4-chloro-2-fluoro-5-methylphenyl H CH₃CH₂CH₃ CH₃ H CH₃ C-420 CH₃ 5-chloro-2-methoxyphenyl H CH₃ CH₂CH₃ CH₃ HCH₃ C-421 CH₃ 4-phenylphenyl CH₃ CH₃ CH₂CH₃ CH₃ H CH₃ C-422 CH₃3-acetamino-2,4-dimethylphenyl H CH₃ CH₂CH₃ CH₃ H CH₃ C-423 CH₃2,5-dichlorophenyl H CH₃ CH₂CH₃ CH₃ H CH₃ C-424 CH₃ 3-acetaminophenylCH₃ CH₃ CH₂CH₃ CH₃ H CH₃ C-425 CH₃ 2,4-dichloro-3-methylphenyl H CH₃CH₂CH₃ CH₃ H CH₃ C-426 CH₃ 4-fluorophenyl CH₃ CH₃ CH₂CH₃ CH₃ H CH₃ C-427CH₃ 4-tert-butylphenyl CH₃ CH₃ CH₂CH₃ CH₃ H CH₃ C-428 CH₃2,3,4-trichlorophenyl H CH₃ CH₂CH₃ CH₃ H CH₃ C-429 CH₃ 4-chlorophenylCH₃ CH₃ CH₂CH₃ CH₃ H CH₃ C-430 CH₃ 3,4-dichlorophenyl CH₃—CH₂CH₂CH₂CH—(CH₃)— CH₃ CH₃ H C-431 2-chlorobenzyl 3,4-dichlorophenylCH₃ CH₃ CH₂CH₃ CH₃ H CH₃ C-432 3-trifluoromethylbenzyl3,4-dichlorophenyl CH₃ CH₃ CH₂CH₃ CH₃ H CH₃ C-433

2,4-dichlorophenyl H CH₃ CH₂CH₃ CH₃ H CH₃ C-434 CH₃ 3,4-dichlorophenylCH₃ CH₃ CH₂CH₃ CH₃ H CH₃ C-435 CH₃ 3-trifluoromethylphenoxymethyl H CH₃CH₂CH₃ H H H C-436 CH₃ 3-bromophenoxymethyl H CH₃ CH₂CH₃ H H H C-437 CH₃3-trifluoromethylphenoxymethyl H CH₃ CH₂CH₃ CH₃ H H C-438 CH₃3-bromophenoxymethyl H CH₃ CH₂CH₃ CH₃ H H C-439 CH₃3-trifluoromethylphenoxymethyl H CH₃ CH₂CH₃ F H H C-440 CH₃3-bromophenoxymethyl H CH₃ CH₂CH₃ F H H C-441 CH₃3,4-dichlorophenoxymethyl H CH₃ CH₂CH₃ F H H C-4423-trifluoromethylbenzyl 2,4-dichlorophenyl H CH₃ CH₂CH₃ CH₃ H CH₃ C-4434-chlorobenzyl 2,4-dichlorophenyl H CH₃ CH₂CH₃ CH₃ H CH₃ C-444E-3-chloro-2-propen-1-yl 2,4-dichlorophenyl H CH₃ CH₂CH₃ CH₃ H CH₃ C-445CH₃ hydroxymethyl H CH₃ CH₂CH₃ CH₃ H CH₃ C-446 E-3-chloro-2-propen-1-yl3,4-dichlorophenyl CH₃ CH₃ CH₂CH₃ CH₃ H CH₃ C-447 benzyl3,4-dichlorophenyl CH₃ CH₃ CH₂CH₃ CH₃ H CH₃ C-448 4-chlorobenzyl3,4-dichlorophenyl CH₃ CH₃ CH₂CH₃ CH₃ H CH₃ C-449 CH₃4-cyano-3-trifluoromethyl- H CH₃ CH₂CH₃ CH₃ H CH₃ phenoxymethyl C-450CH₃ *—CH═CHCH₂CH₂— CH₃ CH₂CH₃ CH₃ CH₃ H C-451 CH₃4-fluoro-3-trifluoromethyl- H CH₃ CH₂CH₃ H H H phenoxymethyl C-452 CH₃4-fluoro-3-trifluoromethyl- H CH₃ CH₂CH₃ F H H phenoxymethyl C-453CH₂CH₂CH₃ 4-fluoro-3-trifluoromethyl- H CH₃ CH₂CH₃ F H H phenoxymethylC-454 CH₃ 4-fluoro-3-trifluoromethyl- H CH₃ CH₂CH₃ Cl H H phenoxymethylC-455 CH₂CH₂CH₃ 4-fluoro-3-trifluoromethyl- H CH₃ CH₂CH₃ Cl H Hphenoxymethyl C-456 CH₃ 4-fluoro-3-trifluoromethyl- H CH₃ CH₂CH₃ H H CF₃phenoxymethyl *In asymmetric divalent groups, the symbol (*) denotes thebond to position R².

TABLE D Physical data for compounds of the formula I.9 according toTable C No. in Table C Phys. data (¹H-NMR (CDCl₃, δ [ppm]); Mp [° C.];HPLC/MS (R_(t) [min])) C-2 ¹H-NMR (CDCl₃): δ = 1.20 (t); 2.10 (s); 2.23(s); 2.97 (s); 3.30 (br.); 3.45 (s); 3.55 (s); 3.97 (s); 4.60 (s); 4.75(s); 4.90 (s); 4.99 (s); 5.55 (s); 5.60 (s); 6.50-6.70 (m); 7.30 (s);7.40 (s). C-3 ¹H-NMR (CDCl₃): δ = 1.20 (t); 2.10 (s); 2.20 (s); 3.00(s); 3.37 (br.); 4.00 (s); 4.50 (s); 4.80 (s); 5.10 (s); 5.20 (s);6.50-6.65 (m); 7.40 (s); 7.97 (s); 8.15. C-4 ¹H-NMR (CDCl₃): δ = 1.15(t); 1.30 (t); 2.10 (s); 2.20 (s); 3.00 (s); 3.37 (br.); 4.10 (s); 4.35(q); 4.87 (s); 6.53 (s); 6.70 (s); 7.40 (s). C-5 ¹H-NMR (CDCl₃); δ =1.20 (t); 2.15 (s); 2.20 (s); 2.98 (s); 3.35 (br.); 3.37 (s); 3.40 (s);3.90 (s); 3.95 (s); 4.17 (s); 4.32 (s); 4.57 (s); 4.85 (s); 6.50-6.70(m); 7.40 (s). C-6 ¹H-NMR (CDCl₃): δ = 1.15 (t); 2.10 (s); 2.20 (s);3.00 (s); 3.35 (br.); 3.87 (s); 4.10 (s); 4.90 (s); 6.53 (s); 6.70 (s);7.40 (s). C-7 ¹H-NMR (CDCl₃): δ = 1.20 (t); 2.05 (s); 2.10 (s); 2.20(s); 2.98 (s); 3.33 (br.); 3.98 (s); 4.63 (s); 4.70 (s); 4.90 (s); 4.93(s); 6.55-7.15 (m); 7.40 (s). C-8 HPLC/MS: R_(t) = 3.280 C-9 ¹H-NMR(CDCl₃): δ = 1.20 (t); 2.05 (s); 2.10 (s); 2.23 (s); 2.95 (s); 3.33(br.); 3.95 (s); 4.60 (s); 4.70 (s); 4.85 (s); 4.87 (s); 6.53 (s); 6.60(s); 6.70-7.35 (m); 7.37 (s). C-10 ¹H-NMR (CDCl₃): δ = 1.20 (t); 2.05(s); 2.10 (s); 2.20 (s); 2.97 (s); 3.35 (br.); 3.98 (s); 4.64 (s); 4.80(s); 4.90 (s); 4.97 (s); 6.53 (s); 6.63 (s); 7.00-7.40 (m). C-13HPLC/MS: R_(t) = 3.161 C-14 HPLC/MS: R_(t) = 3.574 C-15 HPLC/MS: R_(t) =3.328 C-16 HPLC/MS: R_(t) = 3.098 C-18 HPLC/MS: R_(t) = 3.028 C-19HPLC/MS: R_(t) = 2.825 C-20 HPLC/MS: R_(t) = 3.731 C-21 HPLC/MS: R_(t) =3.320 C-23 HPLC/MS: R_(t) = 3.703 C-24 HPLC/MS: R_(t) = 3.380 C-25HPLC/MS: R_(t) = 3.650 C-26 HPLC/MS: R_(t) = 3.447 C-29 HPLC/MS: R_(t) =3.660 C-30 HPLC/MS: R_(t) = 3.796 C-31 HPLC/MS: R_(t) = 2.477 C-33HPLC/MS: R_(t) = 2.157 C-34 HPLC/MS: R_(t) = 1.818 C-35 HPLC/MS: R_(t) =2.434 C-36 HPLC/MS: R_(t) = 1.865 C-37 HPLC/MS: R_(t) = 2.032 C-38HPLC/MS: R_(t) = 2.872 C-42 HPLC/MS: R_(t) = 3.188 C-43 HPLC/MS: R_(t) =3.465 C-44 HPLC/MS: R_(t) = 2.605 C-45 HPLC/MS: R_(t) = 3.668 C-46HPLC/MS: R_(t) = 3.077 C-47 HPLC/MS: R_(t) = 3.026 C-53 HPLC/MS: R_(t) =3.374 C-56 HPLC/MS: R_(t) = 3.021 C-57 HPLC/MS: R_(t) = 2.168 C-59¹H-NMR (CDCl₃): δ = 1.23 (t); 3.01 (s); 3.23-3.60 (m); 3.96 (s);4.65-4.78 (m); 4.91-5.05 (m); 6.78 (s); 6.81-6.91 (m); 7.01-7.20 (m).7.35-7.58 (m); HPLC/MS: R_(t) = 3.454 C-61 ¹H-NMR (CDCl₃): δ = 1.20 (t);1.32 (t); 2.09 (s); 2.20 (s); 2.98 (s); 3.33 (br.); 4.33 (q); 4.80 (m);4.92 (s); 5.30 (m); 6.00 (m); 6.53 (s); 6.68 (s); 7.38 (s). C-63 ¹H-NMR(CDCl₃): δ = 1.18 (t); 1.29 (t); 1.98 (s); 2.20 (s); 2.24 (s); 2.97 (s);3.35 (br.); 3.92 (s); 4.27 (m); 5.13 (s); 6.54 (s); 6.62 (s); 7.38 (s).C-64 ¹H-NMR (CDCl₃): δ = 1.20 (t); 2.00 (s); 2.15 (s); 2.20 (s); 2.98(s); 3.33 (br.); 4.50 (s); 4.63 (d); 4.90 (s); 5.30-5.35 (m); 6.00 (m);6.55 (s); 6.68 (s); 7.38 (s). C-66 ¹H-NMR (CDCl₃): δ = 1.17 (t); 2.00(s); 2.15 (s); 2.23 (s); 2.98 (s); 3.35 (br.); 4.50 (s); 4.57 (m); 6.10(m); 6.27 (m); 6.55 (s); 6.68 (s); 7.38 (s). C-67 ¹H-NMR (CDCl₃): δ =1.22 (t); 1.98 (s); 2.16 (s); 2.19 (s); 2.98 (s); 3.35 (br.); 4.49 (s);5.08 (s); 6.55 (s); 6.63 (s); 7.25-7.43 (m). C-68 ¹H-NMR (CDCl₃): δ =1.22 (t); 1.34 (t); 2.13 (s); 2.24 (s); 3.00 (s); 3.35 (br.); 4.35 (m);4.40 (s); 6.53 (s); 6.72 (s); 7.38 (s). C-69 ¹H-NMR (CDCl₃): δ = 1.22(t); 1.32 (t); 2.06 (s); 2.25 (s); 2.98 (s); 3.35 (br.); 4.24 (q); 4.78(s); 4.92 (s); 6.53 (s); 6.64 (s); 6.95-7.45 (m). C-78 ¹H-NMR (CDCl₃): δ= 1.22 (t); 1.33 (f); 2.05 (s); 2.21 (s); 2.98 (s); 3.35 (br.); 4.22(q); 4.72 (s); 4.90 (s); 6.55-7.40 (m). C-82 ¹H-NMR (CDCl₃): δ = 1.22(t); 1.30 (d); 2.06 (s); 2.22 (s); 3.02 (s); 3.35 (br.); 4.43 (m); 4.70(s); 4.89 (s); 6.55-7.40 (m). C-96 ¹H-NMR (CDCl₃): δ = 1.22 (t); 1.78(s); 2.24 (s); 3.02 (s); 3.35 (br.); 4.03 (sw); 5.13 (s); 6.49 (s); 6.60(s); 7.10-7.45 (m). C-97 ¹H-NMR (CDCl₃): δ = 1.20 (t); 1.43 (d); 2.08(s); 2.23 (s); 3.00 (s); 3.33 (br.); 3.87 (s); 5.10 (q); 6.50 (s); 6.55(s); 6.87 (s); 7.10-7.40 (m). C-101 HPLC/MS: R_(t) = 3.323 C-105 ¹H-NMR(CDCl₃): δ = 1.20 (t); 2.03 (s); 2.22 (s); 2.98 (s); 3.33 (br.); 3.98(s); 4.65 (s); 4.78 (s); 4.90 (s); 4.98 (s); 6.52 (s); 6.62 (s); 7.00(d); 7.38 (s); 7.54 (d). C-107 HPLC/MS: R_(t) = 3.407 C-109 ¹H-NMR(CDCl₃): δ = 1.20 (t); 2.00 (s); 2.20 (s); 2.98 (s); 3.35 (br.); 3.97(s); 4.70 (s); 4.90 (s); 6.48 (s); 6.70 (s); 7.35 (s); 7.80 (s); 8.30(s). C-115 HPLC/MS: R_(t) = 3.421 C-117 ¹H-NMR (CDCl₃): δ = 1.20 (t);2.05 (s); 2.23 (s); 2.98 (s); 3.35 (br.); 3.98 (s); 4.63 (s); 4.73 (s);4.88 (s); 4.98 (s); 6.55 (s); 6.60 (s); 7.00 (m); 7.20-7.40 (m). C-118¹H-NMR (CDCl₃): δ = 1.20 (t); 2.05 (s); 2.24 (s); 2.98 (s); 3.35 (br.);3.98 (s); 4.63 (s); 4.75 (s); 4.90 (s); 4.95 (s); 6.55 (s); 6.62 (s);7.00-7.20 (m); 7.38 (s). C-119 ¹H-NMR (CDCl₃): δ = 1.20 (t); 2.07 (s);2.22 (s); 2.98 (s); 3.33 (br.); 3.98 (s); 4.01 (s); 4.63 (s); 4.83 (s);4.90 (s); 5.03 (s); 6.52 (s); 6.62 (s); 7.35 (s); 7.38 (s); 7.47 (s).C-120 ¹H-NMR (CDCl₃): δ = 1.20 (t); 2.05 (s); 2.22 (s); 2.98 (s); 3.33(br.); 3.98 (s); 4.67 (s); 4.85 (s); 4.92 (s); 5.05 (s); 6.53 (s); 6.62(s); 7.10-7.45 (m). C-121 ¹H-NMR (CDCl₃): δ = 1.20 (t); 2.03 (s); 2.22(s); 2.98 (s); 3.33 (br.); 3.98 (s); 4.67 (s); 4.87 (s); 4.92 (s); 5.05(s); 6.52 (s); 6.62 (s); 7.10-7.40 (m). C-122 ¹H-NMR (CDCl₃): δ = 1.20(t); 2.05 (s); 2.22 (s); 2.98 (s); 3.33 (br.); 3.98 (s); 4.63 (s); 4.75(s); 4.88 (s); 4.97 (s); 6.52 (s); 6.62 (s); 6.70-7.00 (m); 7.37 (s).C-123 ¹H-NMR (CDCl₃): δ = 1.20 (t); 2.03 (s); 2.22 (s); 2.98 (s); 3.33(br.); 3.98 (s); 4.67 (s); 4.85 (s); 4.92 (s); 5.05 (s); 6.52 (s); 6.62(s); 7.10-7.30 (m); 7.38 (s). C-124 ¹H-NMR (CDCl₃): δ = 1.20 (t); 2.03(s); 2.20 (s); 2.98 (s); 3.33 (br.); 3.98 (s); 4.72 (s); 4.83 (s); 4.92(s); 5.05 (s); 6.52 (s); 6.62 (s); 7.10-7.30 (m); 7.38 (s). C-125 ¹H-NMR(CDCl₃): δ = 1.20 (t); 2.05 (s); 2.22 (s); 2.98 (s); 3.33 (br.); 3.98(s); 4.67 (s); 4.89 (s); 4.92 (s); 5.05 (s); 6.52 (s); 6.60 (s);7.10-7.30 (m); 7.38 (s). C-128 ¹H-NMR (CDCl₃): δ = 1.20 (t); 2.05 (s);2.10 (s); 2.20 (s); 2.98 (s); 3.33 (br.); 3.98 (s); 4.70 (s); 4.78 (s);4.92 (s); 5.00 (s); 6.52 (s); 6.63 (s); 6.75 (s); 6.90-7.25 (m); 7.38(s). C-129 ¹H-NMR (CDCl₃): δ = 1.20 (t); 2.07 (s); 2.24 (s); 2.98 (s);3.33 (br.); 3.97 (s); 4.80 (s); 4.97 (s); 6.55 (s); 6.62 (s); 7.10-7.25(m); 7.38 (s). C-130 ¹H-NMR (CDCl₃): δ = 1.20 (t); 2.08 (s); 2.24 (s);2.99 (s); 3.35 (br.); 3.98 (s); 4.72 (s); 4.90 (s); 6.53 (s); 6.59 (s);6.95-7.45 (m). C-132 ¹H-NMR (CDCl₃): δ = 1.20 (t); 2.05 (s); 2.22 (s);2.98 (s); 3.33 (br.); 3.98 (s); 4.70 (s); 4.80 (s); 4.92 (s); 5.00 (s);6.52 (s); 6.62 (s); 6.83 (m); 7.30 (m); 7.38 (s). C-133 ¹H-NMR (CDCl₃):δ = 1.20 (t); 1.46 (s); 2.08 (s); 2.24 (s); 2.98 (s); 3.05 (s); 3.35(br.); 3.93 (s); 4.80 (s); 4.85 (s); 4.95 (s); 5.05 (s); 6.55 (s); 6.62(s); 7.38 (s). C-134 ¹H-NMR (CDCl₃): δ = 1.20 (t); 2.08 (s); 2.22 (s);2.98 (s); 3.35 (br.); 3.98 (s); 4.72 (s); 4.83 (s); 4.92 (s); 5.04 (s);6.52 (s); 6.62 (s); 7.00-7.25 (m); 7.38 (s); 8.00 (s); 8.28 (s). C-136¹H-NMR (CDCl₃): δ = 1.20 (t); 2.05 (s); 2.10 (s); 2.20 (s); 2.27 (s);2.98 (s); 3.33 (br.); 3.97 (s); 4.62 (s); 4.70 (s); 4.90 (s); 6.54 (s);6.62 (s); 6.70-7.10 (m); 7.38 (s). C-137 ¹H-NMR (CDCl₃): δ = 1.22 (t);2.06 (s); 2.24 (s); 2.97 (s); 3.35 (br.); 3.97 (s); 4.87 (s); 4.90 (s);6.52 (s); 6.63 (s); 6.90-7.60 (m). C-139 ¹H-NMR (CDCl₃): δ = 1.32 (t);2.07 (s); 2.33 (s); 3.28 (s); 3.50 (br.); 3.98 (s); 4.75 (s); 4.93 (s);5.00 (s); 5.20 (s); 6.60 (s); 6.72 (s); 7.37 (s). C-142 ¹H-NMR (CDCl₃):δ = 1.20 (t); 1.98 (s); 2.22 (s); 2.98 (s); 3.33 (br.); 3.94 (s); 4.68(s); 4.76 (s); 4.93 (s); 4.95 (s); 6.52 (m); 6.90-7.50 (m). C-143 ¹H-NMR(CDCl₃): δ = 1.20 (t); 2.08 (s); 2.20 (s); 2.32 (s); 2.98 (s); 3.33(br.); 3.98 (s); 4.62 (s); 4.68 (s); 4.90 (s); 6.52 (s); 6.55 (s); 6.62(s); 6.69 (s); 7.38 (s). C-144 ¹H-NMR (CDCl₃): δ = 1.20 (t); 2.03 (s);2.22 (s); 2.32 (s); 2.98 (s); 3.33 (br.); 3.98 (s); 4.62 (s); 4.69 (s);4.90 (s); 6.52 (s); 6.62 (s); 6.65-6.80 (m); 7.18 (d); 7.38 (s). C-145¹H-NMR (CDCl₃): δ = 1.20 (t); 2.03 (s); 2.09 (s); 2.20 (s); 2.67 (q);2.98 (s); 3.33 (br.); 3.96 (s); 4.63 (s); 4.69 (s); 4.90 (s); 4.92 (s);6.52 (s); 6.60-6.85 (m); 7.20 (d); 7.38 (s). C-146 ¹H-NMR (CDCl₃): δ =1.20 (t); 2.05 (s); 2.20 (s); 2.98 (s); 3.33 (br.); 3.85 (s); 3.98 (s);4.65 (s); 4.80 (s); 4.90 (s); 5.02 (s); 6.50-6.75 (m); 7.33 (s); 7.38(s). C-147 ¹H-NMR (CDCl₃): δ = 1.20 (t); 1.99 (s); 2.08 (s); 2.18 (s);2.98 (s); 3.33 (br.); 4.01 (s); 4.75 (s); 4.90 (s); 4.99 (s); 5.13 (s);6.50 (s); 6.64 (s); 6.80 (m); 7.30-7.60 (m); 8.20 (m). C-148 ¹H-NMR(CDCl₃): δ = 1.20 (t); 2.00 (s); 2.03 (s); 2.05 (s); 2.20 (s); 2.30 (s);2.98 (s); 3.33 (br.); 3.98 (s); 4.65 (s); 4.70 (s); 4.90 (s); 4.92 (s);6.52-6.74 (m); 7.38 (s). C-149 ¹H-NMR (CDCl₃): δ = 1.20 (t); 2.08 (s);2.26 (s); 2.97 (s); 3.35 (br.); 3.98 (s); 4.68 (s); 4.90 (s); 6.53 (s);6.63 (s); 6.70-7.45 (m). C-151 ¹H-NMR (CDCl₃): δ = 1.20 (t); 2.03 (s);2.22 (s); 2.98 (s); 3.33 (br.); 3.55 (s); 4.35 (m); 4.84 (m); 6.29 (s);6.52 (s); 6.60 (s); 7.09 (d); 7.36 (s). C-152 ¹H-NMR (CDCl₃): δ = 1.20(t); 2.08 (s); 2.22 (s); 2.97 (s); 3.35 (br.); 3.96 (s); 4.72 (s); 4.90(s); 6.55-7.45 (m). C-154 ¹H-NMR (CDCl₃): δ = 1.26 (d); 1.60-2.10 (m);2.25 (s); 3.55 (m); 3.85 (br.); 3.98 (s); 4.63 (s); 4.70 (s); 4.90 (s);6.55 (s); 6.62 (s); 6.65-7.30 (m); 7.57 (s). C-155 ¹H-NMR (CDCl₃): δ =1.05 (t); 1.28 (d); 1.55-2.30 (m); 2.50 (q); 3.20 (s); 3.55 (m); 3.85(br.); 3.95 (s); 4.60 (s); 4.80 (s); 6.55 (s); 6.62 (s); 7.60 (s). C-156¹H-NMR (CDCl₃): δ = 1.26 (d); 1.55-2.10 (m); 2.18 (s); 2.24 (s); 3.42(s); 3.55 (m); 3.85 (br.); 3.98 (s); 4.20 (s); 4.32 (s); 4.59 (s); 4.85(s); 6.55 (s); 6.62 (s); 7.60 (s). C-157 ¹H-NMR (CDCl₃): δ = 1.20 (t);2.18 (s); 2.22 (s); 2.98 (s); 3.33 (br.); 3.80 (s); 4.48 (s); 4.80(br.); 6.55 (s); 6.70 (s); 7.38 (s). C-158 ¹H-NMR (CDCl₃): δ = 1.20 (t);1.28 (s); 1.40-1.70 (m); 2.05 (m); 2.07 (s); 2.22 (s); 2.98 (s); 3.33(br.); 3.98 (s); 4.67 (s); 4.78 (s); 4.90 (s); 5.01 (s); 6.52 (s); 6.62(s); 6.97 (d); 7.38 (s); 7.88 (s); 8.23 (d). C-159 ¹H-NMR (CDCl₃): δ =1.20 (d); 2.05 (s); 2.22 (s); 2.90 (s); 3.70 (br.); 3.98 (s); 4.72 (s);4.90 (s); 6.53 (s); 6.62 (s); 6.80-7.50 (m). C-160 ¹H-NMR (CDCl₃): δ =1.22 (d); 2.05 (s); 2.22 (s); 2.90 (s); 3.70 (br.); 3.98 (s); 4.72 (s);4.90 (s); 6.53 (s); 6.62 (s); 6.70-7.50 (m). C-161 ¹H-NMR (CDCl₃): δ =1.22 (d); 2.05 (s); 2.22 (s); 2.90 (s); 3.70 (br.); 3.98 (s); 4.78 (s);4.90 (s); 6.55 (s); 6.62 (s); 7.05-7.50 (m). C-162 ¹H-NMR (CDCl₃): δ =0.95 (t); 1.60 (m); 2.07 (s); 2.22 (s); 2.98 (s); 3.25 (br.); 3.98 (s);4.70 (s); 4.92 (s); 6.53 (s); 6.62 (s); 6.80-7.40 (m). C-163 ¹H-NMR(CDCl₃): δ = 0.93 (t); 1.60 (m); 2.07 (s); 2.22 (s); 2.98 (s); 3.23(br.); 3.98 (s); 4.70 (s); 4.90 (s); 6.53 (s); 6.65 (s); 6.80-7.40 (m).C-164 ¹H-NMR (CDCl₃): δ = 0.95 (t); 1.60 (m); 2.07 (s); 2.22 (s); 2.98(s); 3.25 (br.); 3.98 (s); 4.78 (s); 4.90 (s); 6.53 (s); 6.62 (s);7.00-7.40 (m). C-165 ¹H-NMR (CDCl₃): δ = 0.90 (t); 1.20 (d); 1.55 (m);2.05 (s); 2.22 (s); 2.87 (s); 3.25 (br.); 3.98 (s); 4.72 (s); 4.90 (s);6.55 (s); 6.62 (s); 6.80-7.45 (m). C-166 ¹H-NMR (CDCl₃): δ = 0.90 (t);1.20 (d); 1.55 (m); 2.07 (s); 2.22 (s); 2.87 (s); 3.25 (br.); 3.98 (s);4.72 (s); 4.90 (s); 6.55 (s); 6.62 (s); 6.70-7.45 (m). C-167 ¹H-NMR(CDCl₃): δ = 0.90 (t); 1.20 (d); 1.55 (m); 2.05 (s); 2.22 (s); 2.87 (s);3.25 (br.); 3.98 (s); 4.78 (s); 4.92 (s); 6.55 (s); 6.62 (s); 7.00-7.45(m). C-168 ¹H-NMR (CDCl₃): δ = 2.07 (s); 2.22 (s); 2.96 (s); 3.90 (br.);3.98 (s); 4.74 (s); 4.90 (s); 5.20 (m); 5.83 (m); 6.55 (s); 6.62 (s);6.80-7.45 (m). C-169 ¹H-NMR (CDCl₃): δ = 2.07 (s); 2.22 (s); 2.96 (s);3.90 (br.); 3.98 (s); 4.70 (s); 4.90 (s); 5.20 (m); 5.83 (m); 6.55 (s);6.62 (s); 6.70-7.45 (m). C-170 ¹H-NMR (CDCl₃): δ = 2.07 (s); 2.22 (s);2.96 (s); 3.90 (br.); 3.98 (s); 4.78 (s); 4.90 (s); 5.23 (m); 5.83 (m);6.55 (s); 6.62 (s); 6.99-7.45 (m). C-177 ¹H-NMR (CDCl₃): δ = 1.95 (m);2.07 (s); 2.23 (s); 3.50 (m); 3.98 (s); 4.73 (s); 4.88 (s); 6.55 (s);6.60 (s); 6.85-7.20 (m); 7.60 (s). C-178 ¹H-NMR (CDCl₃): δ = 1.95 (m);2.05 (s); 2.24 (s); 3.50 (m); 3.98 (s); 4.70 (s); 4.90 (s); 6.54 (s);6.60 (s); 6.75-7.35 (m); 7.60 (s). C-179 ¹H-NMR (CDCl₃): δ = 1.95 (m);2.05 (s); 2.24 (s); 3.50 (m); 3.98 (s); 4.78 (s); 4.90 (s); 6.54 (s);6.63 (s); 7.10-7.60 (m). C-180 ¹H-NMR (CDCl₃): δ = 1.60 (m); 2.08 (s);2.22 (s); 3.43 (br.); 3.98 (s); 4.70 (s); 4.90 (s); 6.54 (s); 6.62 (s);6.75-7.35 (m). C-181 ¹H-NMR (CDCl₃): δ = 1.60 (m); 2.06 (s); 2.22 (s);3.43 (br.); 3.98 (s); 4.70 (s); 4.90 (s); 6.54 (s); 6.61 (s); 6.65-7.35(m). C-182 ¹H-NMR (CDCl₃): δ = 1.60 (m); 2.08 (s); 2.24 (s); 3.43 (br.);3.98 (s); 4.78 (s); 4.92 (s); 6.54 (s); 6.62 (s); 6.99-7.40 (m). C-183¹H-NMR (CDCl₃): δ = 1.23 (d); 1.47-1.49 (m); 1.62-1.71 (m); 2.05 (s);2.10 (s); 2.22 (s); 3.27 (dtr); 3.53 (br.); 3.945 (s); 3.954 (s); 4.08(br.); 4.61 (s); 4.69 (s); 4.88 (s); 4.90 (s); 6.53 (s); 6.61 (s); 6.70(s); 6.78-6.85 (m); 7.05-7.10 (rn); 7.34 (s). C-184 ¹H-NMR (CDCl₃): δ =1.25 (d); 1.49-1.51 (m); 1.64-1.73 (m); 2.06 (s); 2.09 (s); 2.21 (s);3.31 (dtr); 3.56 (br.); 3.96 (s); 3.97 (s); 4.09 (br.); 4.61 (s); 4.69(s); 4.88 (s); 4.90 (s); 6.53 (d); 6.60 (s); 6.69 (s); 6.70-6.79 (m);6.98 (d); 7.04 (d); 7.28 (d); 7.35 (d). C-185 ¹H-NMR (CDCl₃): δ = 1.24(d); 1.48-1.50 (m); 1.63-1.72 (m); 2.05 (s); 2.10 (s); 2.22 (s); 3.30(dtr); 3.53 (br.); 3.96 (s); 3.97 (s); 4.09 (br.); 4.63 (s); 4.77 (s);4.90 (s); 4.97 (s); 6.53 (s); 6.62 (s); 6.71 (s); 7.02-7.10 (m);7.15-7.22 (m); 7.32-7.35 (m). C-189 ¹H-NMR (CDCl₃): δ = 2.05 (s); 2.10(s); 2.21 (s); 3.48 (br.); 3.72 (tr); 3.965 (s); 3.974 (s); 4.62 (s);4.71 (s); 4.89 (s); 4.92 (s); 6.54 (s); 6.62 (s); 6.71 (s); 6.79-6.87(m); 7.05-7.13 (m); 7.25 (s); 7.37 (s). C-190 ¹H-NMR (CDCl₃): δ = 2.06(s); 2.09 (s); 2.21 (s); 3.49 (br.); 3.73 (tr); 3.96 (s); 4.62 (s); 4.70(5); 4.89 (s); 4.90 (s); 6.55 (s); 6.61 (s); 6.70 (s); 6.71-6.79 (m);6.98-7.04 (m); 7.28 (s); 7.30 (s); 7.37 (s). C-191 ¹H-NMR (CDCl₃): δ =2.07 (s); 2.22 (s); 3.50 (br.); 3.77 (m); 3.98 (s); 4.80 (s); 4.93 (s);6.55 (s); 6.63 (s); 7.00-7.40 (m). C-195 ¹H-NMR (CDCl₃): δ = 1.21 (t);2.99 (s); 3.35 (br.); 3.98 (s); 4.70 (s); 4.90 (s); 6.70-7.55 (m). C-196¹H-NMR (CDCl₃): δ = 1.21 (t); 2.23 (s); 2.97 (s); 3.35 (br.); 3.98 (s);4.67 (s); 4.87 (s); 6.60-7.40 (m). C-248 ¹H-NMR (CDCl₃): δ = 1.19 (t);1.66-1.91 (m); 1.99-2.16 (m); 2.14 (s); 2.22 (s); 2.38-2.43 (m); 2.98(s); 3.33 (br.); 3.98 (s); 4.88 (m); 6.52 (s); 6.85 (s); 7.41 (s); C-251¹H-NMR (CDCl₃): δ = 1.19 (t); 1.21 (d); 1.76-1.92 (m); 2.01-2.18 (m);2.14 (s); 2.22 (s); 2.38-2.44 (m); 2.54-2.63 (m); 2.98 (s); 3.34 (br.);4.32 (sept); 4.87 (m); 6.52 (s); 6.83 (s); 7.39 (s); C-252 ¹H-NMR(CDCl₃): δ = 0.93 (t); 1.19 (t); 1.18 (m); 1.61 (m); 1.76-1.91 (m);1.99-2.16 (m); 2.14 (s); 2.22 (s); 2.38-2.43 (m); 2.54-2.63 (m); 2.98(s); 3.33 (br.); 4.04 (t); 4.87 (m); 6.52 (s); 6.85 (s); 7.41 (s); C-259¹H-NMR (CDCl₃): δ = 1.19 (t); 1.38-1.51 (m); 1.57-1.79 (m); 1.81-2.38(m); 2.19 (s); 2.21 (s); 2.98 (s); 3.00-3.09 (m); 3.34 (br.); 3.82 (s);4.72 (m); 6.54 (s); 6.81 (s); 7.39 (s); C-262 ¹H-NMR (CDCl₃): δ = 1.19(t); 1.21 (d); 1.38-1.51 (m); 1.57-1.79 (m); 1.81-2.38 (m); 2.20 (s);2.21 (s); 2.20-2.31 (m); 2.98 (s); 3.00-3.09 (m); 3.34 (br.); 4.28 (m);4.72 (m); 6.52 (s); 6.83 (s); 7.39 (s); C-263 ¹H-NMR (CDCl₃): δ = 0.91(t); 1.19 (t); 1.18 (m); 1.38-1.49 (m); 1.61 (m); 1.61-1.71 (m);1.83-2.09 (m); 2.14 (s); 2.20-2.31 (m); 2.22 (s); 2.98 (s); 3.00-3.09(m); 3.353 (br.); 4.02 (t); 4.72 (m); 6.52 (s); 6.81 (s); 7.39 (s).C-270 ¹H-NMR (CDCl₃): δ = 1.19 (t); 1.37-1.56 (m); 1.61-1.92 (m);2.09-2.27 (m); 2.19 (s); 2.21 (s); 2.68-2.79 (m); 2.98 (s); 3.34 (br.);3.82 (s); 4.87 (m); 6.55 (s); 6.82 (s); 7.39 (s); HPLC/MS: R_(t) = 3.110C-299 HPLC/MS: R_(t) = 3.331 C-300 HPLC/MS: R_(t) = 3.716 C-301 HPLC/MS:R_(t) = 3.280 C-302 HPLC/MS: R_(t) = 3.342 C-303 HPLC/MS: R_(t) = 3.185C-304 HPLC/MS: R_(t) = 3.424 C-305 HPLC/MS: R_(t) = 3.193 C-306 HPLC/MS:R_(t) = 3.376 C-307 HPLC/MS: R_(t) = 3.344 C-308 HPLC/MS: R_(t) = 3.290C-309 HPLC/MS: R_(t) = 3.408 C-310 HPLC/MS: R_(t) = 3.423 C-311 HPLC/MS:R_(t) = 3.558 C-312 HPLC/MS: R_(t) = 3.445 C-313 HPLC/MS: R_(t) = 3.258C-314 HPLC/MS: R_(t) = 3.365 C-315 HPLC/MS: R_(t) = 3.297 C-316 HPLC/MS:R_(t) = 3.483 C-317 HPLC/MS: R_(t) = 3.619 C-318 ¹H-NMR (CDCl₃): δ =1.22 (t); 1.35 (t); 2.07 (s); 2.23 (s); 2.97 (s); 3.35 (br.); 4.22 (m);4.85 (s); 4.92 (s); 6.53 (s); 6.73 (s); 7.10-7.45 (m). C-319 ¹H-NMR(CDCl₃): δ = 1.22 (t); 1.32 (t); 2.07 (s); 2.23 (s); 3.03 (s); 3.37(br.); 4.22 (q); 4.74 (s); 4.92 (s); 6.58 (s); 6.63 (s); 6.85-7.45 (m).C-320 ¹H-NMR (CDCl₃): δ = 1.22 (t); 1.32 (t); 2.07 (s); 2.23 (s); 3.01(s); 3.35 (br.); 4.21 (q); 4.72 (s); 4.90 (s); 6.59 (s); 6.63 (s);6.70-7.45 (m). C-321 ¹H-NMR (CDCl₃): δ = 1.27 (m); 2.10 (s); 2.28 (s);3.10 (br.); 3.40 (br.); 4.20 (m); 4.82 (s); 4.99 (s); 6.62 (s); 6.66(s); 7.15-7.45 (m). C-322 ¹H-NMR (CDCl₃): δ = 1.22 (t); 1.28 (t); 2.05(s); 2.24 (s); 3.02 (s); 3.38 (br.); 4.18 (q); 4.83 (s); 4.98 (s); 6.57(s); 6.63 (s); 6.90-7.45 (m). C-323 ¹H-NMR (CDCl₃): δ = 1.20 (t); 1.30(t); 2.05 (s); 2.23 (s); 3.00 (s); 3.35 (br.); 4.22 (q); 4.68 (s); 4.90(s); 6.54 (s); 6.60-7.40 (m). C-325 ¹H-NMR (CDCl₃): δ = 1.18 (t); 1.37(t); 1.78 (s); 2.23 (s); 2.98 (s); 3.35 (br.); 4.27 (q); 5.13 (s); 6.47(s); 6.60 (s); 7.10-7.45 (m). C-327 ¹H-NMR (CDCl₃): δ = 1.20 (t); 1.75(s); 2.20 (s); 3.00 (s); 3.35 (br.); 3.85 (s); 5.15 (s); 5.20 (s); 6.45(s); 6.55 (s); 6.85-7.45 (m). C-328 Mp. 61-63° C. C-329 HPLC/MS: R_(t) =2.414 C-330 HPLC/MS: R_(t) = 2.933 C-335 HPLC/MS: R_(t) = 3.207 C-336¹H-NMR (CDCl₃): δ = 1.18 (m); 2.24 (m); 2.43 (m); 2.98 (s); 3.35 (br.);3.90 (s); 4.49 (s); 6.61 (s); 6.69 (s); 7.28 (s). C-337 ¹H-NMR (CDCl₃):δ = 0.33 (m); 0.57 (m); 1.21 (m); 2.18 (s); 2.23 (s); 3.02 (s); 3.40(br.); 3.92 (s); 4.80 (s); 6.62 (s); 6.81 (s); 7.44 (s). C-338 ¹H-NMR(CDCl₃): δ = 1.06 (t); 1.21 (t); 2.13 (s); 2.18 (s); 2.40 (m); 2.96 (s);3.35 (br.); 3.75 (s); 3.87 (s); 6.57 (s); 7.42 (s). C-339 ¹H-NMR(CDCl₃): δ = 1.19 (t); 1.26 (t); 1.93 (s); 2.19 (s); 2.22 (s); 2.96 (s);3.35 (br.); 3.79 (s); 4.16 (q); 5.16 (s); 6.54 (s); 6.63 (s); 7.38 (s).C-340 ¹H-NMR (CDCl₃): δ = 1.24 (t); 1.93 (s); 2.19 (s); 2.23 (s); 3.01(s); 3.35 (br.); 3.81 (s); 3.93 (s); 5.23 (s); 6.62 (s); 6.67 (s); 7.45(s). C-341 ¹H-NMR (CDCl₃): δ = 1.18 (t); 1.45 (d); 1.82 (s); 2.17 (s);2.21 (s); 2.98 (s); 3.35 (br.); 3.86 (s); 4.81 (q); 6.53 (s); 6.73 (s);7.39 (s). C-342 HPLC/MS: R_(t) = 3.727 C-343 HPLC/MS: R_(t) = 2.909C-344 HPLC/MS: R_(t) = 4.034 C-345 HPLC/MS: R_(t) = 2.489 C-346 HPLC/MS:R_(t) = 2.733 C-347 HPLC/MS: R_(t) = 3.150 C-348 HPLC/MS: R_(t) = 2.319C-349 HPLC/MS: R_(t) = 2.883 C-350 HPLC/MS: R_(t) = 3.058 C-351 HPLC/MS:R_(t) = 2.347 C-352 HPLC/MS: R_(t) = 2.833 C-353 HPLC/MS: R_(t) = 3.027C-354 HPLC/MS: R_(t) = 3.277 C-355 HPLC/MS: R_(t) = 2.645 C-356 HPLC/MS:R_(t) = 3.128 C-357 HPLC/MS: R_(t) = 3.257 C-358 HPLC/MS: R_(t) = 3.258C-359 HPLC/MS: R_(t) = 3.329 C-360 HPLC/MS: R_(t) = 3.094 C-361 HPLC/MS:R_(t) = 2.912 C-362 HPLC/MS: R_(t) = 3.216 C-363 HPLC/MS: R_(t) = 3.140C-364 HPLC/MS: R_(t) = 3.200 C-365 HPLC/MS: R_(t) = 3.221 C-366 HPLC/MS:R_(t) = 3.937 C-367 HPLC/MS: R_(t) = 3.575 C-368 HPLC/MS: R_(t) = 3.555C-369 HPLC/MS: R_(t) = 3.783 C-370 HPLC/MS: R_(t) = 3.462 C-371 HPLC/MS:R_(t) = 3.618 C-372 HPLC/MS: R_(t) = 3.702 C-373 HPLC/MS: R_(t) = 3.513C-374 HPLC/MS: R_(t) = 3.792 C-375 HPLC/MS: R_(t) = 3.377 C-376 HPLC/MS:R_(t) = 3.166 C-377 HPLC/MS: R_(t) = 3.167 C-378 HPLC/MS: R_(t) = 3.907C-379 HPLC/MS: R_(t) = 3.414 C-380 HPLC/MS: R_(t) = 3.388 C-381 HPLC/MS:R_(t) = 3.827 C-382 HPLC/MS: R_(t) = 2.858 C-383 HPLC/MS: R_(t) = 3.793C-384 HPLC/MS: R_(t) = 2.824 C-385 HPLC/MS: R_(t) = 3.054 C-386 HPLC/MS:R_(t) = 3.810 C-387 ¹H-NMR (CDCl₃): δ = 1.20 (t); 1.31 (t); 1.68 (s);2.20 (s); 2.29 (s); 3.01 (s); 3.37 (br.); 4.17 (q); 5.81 (s); 6.60 (s);6.76 (s); 7.20-7.83 (m). C-388 ¹H-NMR (CDCl₃): δ = 1.31 (t); 1.68 (s);2.24 (s); 2.30 (s); 2.23 (s); 3.48 (s); 3.93 (s); 5.83 (s); 6.77 (s);6.83 (s); 7.00-7.80 (m); 8.38 (s). C-389 ¹H-NMR (CDCl₃): δ = 1.15 (m);2.17 (s); 2.22 (s); 2.45 (q); 2.97 (s); 3.35 (br.); 4.22 (m); 4.40 (m);4.47 (s); 6.50-7.40 (m). C-390 ¹H-NMR (CDCl₃): δ = 1.15 (t); 1.22 (t);2.14 (s); 2.17 (s); 2.37 (q); 2.99 (s); 3.38 (br.); 4.86 (s); 4.92 (s);5.10 (s); 6.57 (s); 6.60 (s); 7.30-7.45 (m). C-391 ¹H-NMR (CDCl₃): δ =1.20 (m); 2.17 (s); 2.24 (s); 2.43 (q); 2.98 (s); 3.34 (br.); 4.13 (q);4.83 (s); 6.55 (s); 6.62 (s); 7.39 (s). C-392 ¹H-NMR (CDCl₃): δ = 1.18(m); 2.10 (s); 2.16 (s); 2.94 (s); 3.35 (br.); 3.82 (s); 4.58 (s); 6.54(s); 6.70 (s); 7.37 (s). C-393 ¹H-NMR (CDCl₃): δ = 0.30 (m); 0.53 (m);1.15 (t); 1.43 (m); 1.85 (s); 2.20 (m); 2.97 (s); 3.35 (br.); 3.85 (m);4.80 (m); 6.52 (s); 6.73 (s); 7.38 (s). C-394 ¹H-NMR (CDCl₃): δ = 1.17(t); 1.44 (d); 1.82 (s); 2.17 (m); 2.97 (s); 3.35 (br.); 4.15 (m); 4.40(m); 4.82 (q); 6.50 (s); 6.70 (s); 6.80-7.40 (m). C-395 ¹H-NMR (CDCl₃):δ = 1.19 (t); 1.45 (d); 1.85 (s); 2.12 (s); 2.17 (s); 2.97 (s); 3.33(br.); 4.78 (q); 5.06 (s); 6.52 (s); 6.64 (s); 7.20-7.450 (m). C-396¹H-NMR (CDCl₃): δ = 1.22 (m); 1.46 (d); 1.80 (s); 2.16 (m); 2.99 (s);3.37 (br.); 4.09 (q); 4.82 (q); 6.58 (s); 6.74 (s); 7.42 (s). C-397¹H-NMR (CDCl₃): δ = 1.22 (t); 1.62 (d); 2.07 (s); 2.12 (s); 2.97 (s);3.35 (br.); 5.30 (s); 5.83 (q); 6.43 (s); 6.48 (s); 6.80-7.50 (m). C-398¹H-NMR (CDCl₃): δ = 1.22 (t); 1.75 (s); 2.20 (s); 2.98 (s); 3.35 (br.);5.15 (s); 5.28 (s); 6.45 (s); 6.57 (s); 6.80-7.45 (m). C-400 ¹H-NMR(CDCl₃): δ = 0.98 (t); 1.20 (t); 1.77 (s); 1.80-2.15 (m); 2.24 (s); 2.97(s); 3.35 (br.); 5.13 (t); 5.21 (s); 6.47 (s); 6.60 (s); 6.97-7.40 (m).C-402 ¹H-NMR (CDCl₃): δ = 1.25 (t); 1.62 (d); 1.80 (s); 2.25 (s); 3.05(br.); 3.38 (br.); 4.78 (s); 5.67 (q); 6.55 (s); 6.63 (s); 6.99-7.45(m). C-404 ¹H-NMR (CDCl₃): δ = 1.23 (t); 1.65 (d); 1.77 (s); 2.27 (s);3.05 (br.); 3.38 (br.); 5.18 (s); 5.38 (q); 6.53 (s); 6.62 (s);6.99-7.45 (m). C-405 ¹H-NMR (CDCl₃): δ = 1.20 (t); 1.75 (s); 2.22 (s);2.98 (s); 3.35 (br.); 5.22 (s); 5.38 (s); 6.46 (s); 6.60 (s); 7.10-7.50(m). C-406 HPLC/MS: R_(t) = 3.006 C-407 HPLC/MS: R_(t) = 3.294 C-408HPLC/MS: R_(t) = 3.014 C-409 HPLC/MS: R_(t) = 3.000 C-410 HPLC/MS: R_(t)= 2.846 C-411 HPLC/MS: R_(t) = 2.962 C-412 HPLC/MS: R_(t) = 3.251 C-413HPLC/MS: R_(t) = 3.539 C-414 HPLC/MS: R_(t) = 3.275 C-415 HPLC/MS: R_(t)= 3.032 C-416 HPLC/MS: R_(t) = 3.061 C-417 HPLC/MS: R_(t) = 2.934 C-418HPLC/MS: R_(t) = 2.561 C-419 HPLC/MS: R_(t) = 3.378 C-420 HPLC/MS: R_(t)= 3.071 C-421 HPLC/MS: R_(t) = 3.582 C-422 HPLC/MS: R_(t) = 2.451 C-423HPLC/MS: R_(t) = 3.275 C-424 HPLC/MS: R_(t) = 2.627 C-425 HPLC/MS: R_(t)= 3.430 C-426 HPLC/MS: R_(t) = 2.985 C-427 HPLC/MS: R_(t) = 3.574 C-428HPLC/MS: R_(t) = 3.422 C-429 HPLC/MS: R_(t) = 3.196 C-433 ¹H-NMR(CDCl₃): δ = 1.18 (t); 1.35 (s); 1.65 (d); 1.76 (s); 2.23 (s); 2.98 (s);3.35 (br.); 5.20 (s); 5.37 (q); 6.46 (s); 6.60 (s); 6.99-7.45 (m). C-435¹H-NMR (CDCl₃): δ = 1.20 (t); 2.99 (s); 3.35 (br.); 3.98 (s); 4.75 (s);4.90 (s); 6.70-7.60 (m). C-436 ¹H-NMR (CDCl₃): δ = 1.21 (t); 2.99 (s);3.35 (br.); 3.98 (s); 4.70 (s); 4.90 (s); 6.70-7.50 (m). C-437 ¹H-NMR(CDCl₃): δ = 1.18 (t); 2.25 (s); 2.95 (s); 3.30 (br.); 3.98 (s); 4.75(s); 4.90 (s); 6.70-7.40 (m). C-438 ¹H-NMR (CDCl₃): δ = 1.18 (t); 2.25(s); 2.95 (s); 3.30 (br.); 3.98 (s); 4.69 (s); 4.88 (s); 6.60-7.40 (m).C-434 ¹H-NMR (CDCl₃): δ = 1.18 (t); 1.62 (d); 2.09 (s); 2.19 (s); 2.97(s); 3.33 (br.); 4.07 (s); 5.83 (q); 6.48 (s); 6.53 (s); 7.30-7.60 (m);7.83 (s). C-439 ¹H-NMR (CDCl₃): δ = 1.22 (t); 3.00 (s); 3.30 (br.); 3.98(s); 4.68 (s); 4.90 (s); 6.50-7.60 (m). C-440 ¹H-NMR (CDCl₃): δ = 1.22(t); 3.00 (s); 3.30 (br.); 3.98 (s); 4.75 (s); 4.90 (s); 6.50-7.60 (m).C-441 ¹H-NMR (CDCl₃): δ = 1.22 (t); 3.00 (s); 3.30 (br.); 3.98 (s); 4.66(s); 4.90 (s); 6.50-7.60 (m). C-442 ¹H-NMR (CDCl₃): δ = 1.18 (t); 1.75(s); 2.20 (s); 2.99 (s); 3.35 (br.); 5.18 (s); 5.30 (s); 6.45 (s); 6.55(s); 7.00-7.70 (m). C-443 ¹H-NMR (CDCl₃): δ = 1.18 (t); 1.77 (s); 2.22(s); 3.00 (s); 3.35 (br.); 5.16 (s); 5.23 (s); 6.45 (s); 6.55 (s);7.00-7.45 (m). C-444 ¹H-NMR (CDCl₃): δ = 1.18 (t); 1.75 (s); 2.25 (s);3.00 (s); 3.35 (br.); 4.71 (d); 5.13 (s); 6.15 (m); 6.35 (d); 6.48 (s);6.58 (s); 7.10-7.45 (m). C-445 ¹H-NMR (CDCl₃): δ = 1.20 (t); 2.17 (s);2.22 (s); 2.98 (s); 3.35 (br.); 3.90 (s); 4.53 (s); 4.62 (s); 6.53 (s);6.70 (s); 7.38 (s). C-446 ¹H-NMR (CDCl₃): δ = 1.18 (t); 1.62 (d); 2.08(s); 2.17 (s); 2.98 (s); 3.35 (br.); 4.75 (d); 5.81 (q); 6.20 (m); 6.35(d); 6.50 (s); 7.25-7.60 (m); 7.53 (s). C-447 ¹H-NMR (CDCl₃): δ = 1.18(t); 1.62 (d); 2.07 (s); 2.10 (s); 2.98 (s); 3.35 (br.); 5.30 (s); 5.87(q); 6.45 (s); 6.50 (s); 7.20-7.85 (m). C-448 ¹H-NMR (CDCl₃): δ = 1.20(t); 1.62 (d); 2.08 (s); 2.12 (s); 2.98 (s); 3.35 (br.); 5.08 (q); 5.25(s); 6.42 (s); 6.74 (s); 7.10-7.80 (m). C-449 ¹H-NMR (CDCl₃): δ = 1.22(t); 2.08 (s); 2.23 (s); 2.98 (s); 3.35 (br.); 3.98 (s); 4.85 (s); 4.90(s); 6.53 (s); 6.60 (s); 7.10-7.80 (m). C-450 ¹H-NMR (CDCl₃): δ = 1.19(t); 1.82-2.13 (m); 2.14 (s); 2.20 (s); 2.35 (m); 2.59 (m); 2.98 (s);3.34 (br.); 3.83 (s); 4.80 (m); 6.32 (m); 6.52 (s); 6.61 (d); 6.90 (s);7.39 (s); HPLC/MS: R_(t) = 2.688 C-451 ¹H-NMR (CDCl₃): δ = 1.20 (t);3.05 (s); 3.38 (m); 3.96 (m); 4.68 (m); 4.93 (m); 6.75-6.93 (m);7.00-7.21 (m); 7.45-7.59 (m); HPLC/MS: R_(t) = 3.257 C-452 ¹H-NMR(CDCl₃): δ = 1.20 (t); 2.97 (s); 3.25-3.57 (m); 3.92 (m); 4.56-4.71 (m);4.85-4.93 (m); 6.55-6.88 (m); 6.95-7.18 (m); 7.45-7.61 (m); HPLC/MS:R_(t) = 3.334 C-453 ¹H-NMR (CDCl₃): δ = 0.94 (t). 1.21 (t); 1.73 (m);2.97 (s); 3.25-3.57 (m); 4.11 (t); 4.60-4.71 (m); 4.89-4.96 (m);6.55-6.71 (m); 6.82-6.89 (m); 7.00-7.16 (m); 7.45-7.61 (m); HPLC/MS:R_(t) = 3.607 C-454 ¹H-NMR (CDCl₃): δ = 1.22 (t); 2.95 (s); 3.23-3.57(m); 3.96 (s); 4.60-4.75 (m); 4.85-4.97 (m); 6.65-7.18 (m); 7.35-7.55(m); HPLC/MS: R_(t) = 3.397 C-455 ¹H-NMR (CDCl₃): δ = 0.94 (t). 1.21(t); 1.76 (m); 3.05 (s); 3.25-3.71 (m); 4.15 (t); 4.62-4.75 (m);4.91-4.98 (m); 6.70-7.23 (m); 7.45-7.61 (m); HPLC/MS: R_(t) = 3.738C-456 ¹H-NMR (CDCl₃): δ = 1.45 (t); 3.39 (s); 3.61-3.85 (m); 3.99 (s);4.79 (m); 4.95 (m); 7.01-7.19 (m); 78.47 (s). 7.68 (s). 7.81-7.9 (m);HPLC/MS: R_(t) = 3.516

HPLC column: RP-18 column (Chromolith Speed ROD from Merck KgaA,Germany)

Mobile phase: acetonitrile+0.1% trifluoroacetic acid (TFA)/water+0.1%TFA (gradient 5:95 to 95:5 over 5 min, 40° C.

MS: quadrupole electrospray ionization, 80 V (positive mode)

The abbreviation (br.) denotes broad NMR signals.

In the case of the oximes, E- and Z-isomers are frequently discerniblenext to one another. In these cases, the NMR signals of the main isomerwere specified.

The abbreviation Mp. denotes the melting point.

Examples of the Action Against Harmful Fungi

The fungicidal action of the compounds of the formula I was demonstratedby the following tests:

Microtiter Tests

The compounds and active compounds were formulated separately as a stocksolution having a concentration of 10 000 ppm in DMSO.

The measured parameters were compared to the growth of the activecompound-free control variant (100%) and the fungus- and activecompound-free blank value to determine the relative growth in % of thepathogens in the individual active compounds.

Use Example 1 Activity Against the Gray Mold Pathogen Bottytis Cinerea

The stock solution was pipetted into a microtiter plate (MTP) anddiluted to the stated active compound concentration using a malt-basedaqueous nutrient medium for fungi. An aqueous spore suspension ofBotrytis cinerea was then added. The plates were placed in a watervapor-saturated chamber at temperatures of 18° C. Using an absorptionphotometer, the MTPs were measured at 405 nm on day 7 after theinoculation.

In this test, the pathogens which had been treated with 125 ppm of theactive compound I-7, I-9, I-10, I-15, I-24, I-25, I-26, I-29, I-43,I-53, I-59, I-66, I-97 or 1-154 showed a growth of at most 10%.

Use Example 2 Activity Against the Late Blight Pathogen Phytophthorainfestans

The stock solution was pipetted into a microtiter plate (MTP) anddiluted to the stated active compound concentration using a peajuice-based aqueous nutrient medium for fungi. An aqueous zoo sporesuspension of Phytophthora infestans was then added. The plates wereplaced in a water vapor-saturated chamber at temperatures of 18° C.Using an absorption photometer, the MTPs were measured at 405 nm on day7 after the inoculation.

In this test, the pathogens which had been treated with 125 ppm of theactive compound I-7, I-9, I-10, I-97 or 1-154 showed a growth of at most10%.

Use Example 3 Activity Against the Rice Blast Pathogen PyriculariaOryzae

The stock solution was pipetted into an MTP and diluted to the statedactive compound concentration using a malt-based aqueous nutrient mediumfor fungi. An aqueous spore suspension of Pyricularia oryzae was thenadded. The plates were placed in a water vapor-saturated chamber attemperatures of 18° C. Using an absorption photometer, the MTPs weremeasured at 405 nm on day 7 after the inoculation.

In this test, the pathogens which had been treated with 125 ppm of theactive compound I-7, I-9, I-10, I-15, I-24, I-25, I-26, I-29, I-47,I-53, I-59, I-64, I-66, I-9.7 or I-154 showed a growth of at most 10%.

Use Example 4 Activity Against the Septoria Leaf Spot Pathogen Septoriatritici

The stock solution was pipetted into an MTP and diluted to the statedactive compound concentration using a malt-based aqueous nutrient mediumfor fungi. An aqueous spore suspension of Septoria tritici was thenadded. The plates were placed in a water vapor-saturated chamber attemperatures of 18° C. Using an absorption photometer, the MTPs weremeasured at 405 nm on day 7 after the inoculation.

In this test, the pathogens which had been treated with 125 ppm of theactive compound I-5, I-7, I-9, I-10, I-15, I-24, I-25, I-26, I-29, I-43,I-47, I-59, I-97 or I-154 showed a growth of at most 10%.

Greenhouse Tests

The active compounds were prepared separately as a stock solutioncomprising 19.6 mg of active compound which was made up to 10 ml using amixture of acetone and/or DMSO, cyclohexanone and the emulsifier Wettol®EM 31 (wetting agent having emulsifying and dispersing action based onethoxylated castor oil) in a volume ratio of solvent/emulsifier of 99/1.The mixture was then made up to 32 ml with water. This stock solutionwas diluted with the solvent/emulsifier/water mixture described to theconcentration of active compound stated below.

Use Example 5 Activity Against Brown Rust of Wheat Caused by PucciniaRecondita on Wheat, Protective Application

Leaves of potted wheat seedlings Were sprayed with an aqueous suspensionhaving the active compound concentration stated below. The next day, thetreated plants were inoculated with a spore-suspension of brown rust ofwheat (Puccinia recondita). The plants were then placed in a chamberwith high atmospheric humidity (90 to 95%) at 20 to 22° C. for 24 hours.During this time, the spores germinated and the germ tubes penetratedinto the leaf tissue. The next day, the test plants were returned to thegreenhouse and cultivated at temperatures between 20 and 22° C. and 65to 70% relative atmospheric humidity for a further 7 days. The extent ofthe rust fungus development on the leaves was then determined visuallyin %.

In this test, the plants which had been treated with 600 ppm of theactive compound I-2, I-5 to I-10, I-15, I-17, I-21, I-22, I-24, I-31,I-33, I-35, I-37, I-38, I-42, I-43, I-44, I-53, I-59, I-64, I-66, I-97,I-105, I-117 to I-125, I-128 to I-134, I-136, I-139, I-142 to I-149,I-151, I-154 to I-158, I-182, I-252, I-437 or I-450 showed an infectionof at most 15%, whereas the untreated plants were 80 to 90% infected.

Use Example 6 Activity Against Brown Rust of Wheat Caused by PucciniaRecondita on Wheat, Curative Application

Leaves of potted wheat seedlings were inoculated with a spore suspensionof brown rust of wheat (Puccinia recondita). The pots were then placedin a chamber with high atmospheric humidity (90 to 95%) at 20 to 22° C.for 24 hours. During this time, the spores germinated and the germ tubespenetrated into the leaf tissue. The next day, the infected plants weresprayed to run off point with the active compound solution describedabove having the active compound concentration stated below. After thespray coating had dried on, the test plants were cultiviated in agreenhouse at temperatures between 20 and 22° C. and 65 to 70% relativeatmospheric humidity for 7 days. The extent of the rust fungusdevelopment was then determined visually in % infection of the leafarea.

In this test, the plants which had been treated with 600 ppm of theactive compound I-2, I-5 to I-10, I-15, I-17, I-21, I-22, I-24, I-31,I-35, I-37, I-38, I-42, I-43, I-44, I-53, I-59, I-64, I-66, I-97, I-105,I-117, I-118, I-120 to I-125, I-128 to I-134, I-136, I-139, I-142 toI-149, I-151, I-156 to I-158, I-182 or 1-450 showed an infection of atmost 15%, whereas the untreated plants were 80 to 90% infected.

Use Example 7 Activity Against Gray Mold on Bell Pepper Leaves Caused byBotrytis Cinerea 1 Day Protective Application

Bell pepper seedlings were, after 2-3 leaves were well-developed,sprayed to runoff point with an aqueous suspension having theconcentration of active compounds stated below. After one day, thetreated plants were inoculated with a spore suspension of Botrytiscinerea in a 2% biomalt solution. The test plants were then placed in adark climatized chamber at 22 to 24° C. and high atmospheric humidity.After 5 days, the extent of the fungal infection on the leaves could bedetermined visually in %.

In this test, the plants which had been treated with 600 ppm of theactive compounds I-10, I-121, I-131, I-142, I-144, I-146, I-148, I-449,I-151 or I-182 showed an infection of at most 15%, whereas the untreatedplants were 80 to 90% infected.

Use Example 8 Activity Against Gray Mold on Bell Pepper Leaves Caused byBotrytis Cinerea 7 Days Protective Application

Bell pepper seedlings were, after 2-3 leaves were well-developed,sprayed to runoff point with an aqueous suspension having theconcentration of active compounds stated below. After 7 days, thetreated plants were inoculated with a spore suspension of Botrytiscinerea in a 2% biomalt solution. The test plants were then placed in adark climatized chamber at 22 to 24° C. and high atmospheric humidity.After 5 days, the extent of the fungal infection on the leaves could bedetermined visually in %.

In this test, the plants which had been treated with 250 ppm of theactive compounds I-66 or I-97 showed an infection of at most 15%,whereas the untreated plants were 80 to 90% infected.

Use Example 9 Activity Against Mildew of Wheat Caused by Erysiphe [Syn.Blumeria] Graminis f. sp. Tritici

Leaves of potted wheat seedlings were sprayed to runoff point with anaqueous suspension having the concentration of active compounds statedbelow. The suspension or emulsion was prepared as described above. 24hours after the spray coating had dried on, the plants were dusted withspores of mildew of wheat (Erysiphe [syn. Blumeria] graminis f. sp.tritici). The test plants were then placed in a greenhouse attemperatures between 20 and 24° C. and 60 to 90% relative atmospherichumidity. After 7 days, the extent of the mildew development wasdetermined visually in % infection of the entire leaf area.

In this test, the plants which had been treated with 600 ppm of theactive compounds I-2, I-10, I-66, I-121, I-131, I-142, I-144, I-146,I-148, I-149, I-151, I-182, I-437 or I-450, the plants which had beentreated with 500 ppm of the active compound I-252 and the plants whichhad been treated with 300 ppm of the active compound I-97 showed aninfection of at most 15%, whereas the untreated plants were 80 to 90%infected.

Use Example 10 Curative Activity Against Soybean Rust Caused byPhakopsora Pachyrhizi

Leaves of potted soybean seedlings were inoculated with a sporesuspension of soybean rust (Phakpsora pachyrhizi). The pots were thenplaced in a chamber of high atmospheric humidity (90 to 95%) at 23 to27° C. for 24 hours. During this time, the spores germinated and thegerm tubes penetrated into the leaf tissue. The infected plants werethen sprayed to runoff point with the solution of active compounddescribed above at the active compound concentration stated below. Afterthe spray coating had dried on, the test plants were cultivated in agreenhouse at temperatures between 23 and 27° C. and 60 to 80% relativeatmospheric humidity for 14 days. The extent of the rust fungusdevelopment on the leaves was then determined visually in % infection.

In this test, the plants which had been treated with 600 ppm of theactive compounds I-2, I-8, I-10, I-66, I-97, I-121, I-131, I-144, I-146,I-148, I-149, I-151, I-182, I-437 or I-450 and the plants which had beentreated with 500 ppm of the active compound I-252 showed an infection ofat most 15%, whereas the untreated plants were 80 to 90% infected.

Use Example 11 Activity Against Net Blotch of Barley Caused byPyrenophora teres 1 Day Protective Application

Leaves of potted barley seedlings were sprayed to runoff point with anaqueous suspension having the concentration of active compounds statedbelow. 24 hours after the spray coating had dried on, the test plantswere inoculated with an aqueous spore suspension of Pyrenophora [syn.Drechslera] teres, the net blotch pathogen. The test plants were thenplaced in a greenhouse at temperatures between 20 and 24° C. and 70%relative atmospheric humidity. After 6 days, the extent of the diseasedevelopment was determined visually in % infection of the entire leafarea.

In this test, the plants which had been treated with 600 ppm of theactive compounds I-10, I-131, I-144, I-146, I-149 or I-182 and theplants which had been treated with 250 ppm of the active compounds I-10,I-121, I-142 or I-149 showed an infection of at most 15%, whereas theuntreated plants were 80 to 90% infected.

Use Example 12 Curative Activity Against Septoria Leaf Spot of WheatCaused by Septoria Tritici

Leaves of potted wheat seedlings were inoculated with a spore suspensionof the leaf spot pathogen Septoria tritici. The test plants were thenplaced in a greenhouse at temperatures between 20 and 24° C. and arelative atmospheric humidity close to 100% for 4 days and then attemperatures between 16 and 18° C. and a relative atmospheric humidityof about 70%. Six days after the inoculation, the plants were sprayed torunoff point with an aqueous active compound solution having theconcentration stated below. After the spray coating had dried on, theplants were replaced. After 21 days, the extent of the development ofthe disease was determined visually in % infection of the entire leafarea.

In this test, the plants which had been treated with 250 ppm of theactive compounds I-121, I-131, I-142, I-144, I-148 or I-149 showed aninfection of at most 15%, whereas the untreated plants were 80 to 90%infected.

The invention claimed is:
 1. A compound of the formula I

in which the substituents have the following meaning: R¹ is C₁-C₈-alkyl,C₂-C₈-alkenyl, C₂-C₈-alkynyl, C₃-C₈-cycloalkyl, C₃-C₈-cyclo-alkenyl,phenyl or a three- to ten-membered saturated, partially unsaturated oraromatic mono- or bicyclic heterocyclyl which, in addition to carbonatoms, contains one to four heteroatoms from the group consisting of O,N and S as ring members; R² is amino, C₁-C₈-alkyl, C₂-C₈-alkenyl,C₂-C₈-alkynyl, C₁-C₈-alkoxy, C₃-C₈-cycloalkyl, C₃-C_(s)-cycloalkenyl,phenyl or a three- to ten-membered saturated, partially unsaturated oraromatic mono- or bicyclic heterocyclyl which, in addition to carbonatoms, contains one to four heteroatoms from the group consisting of O,N and S as ring members, where the groups R² may be attached directly orvia a carbonyl group; R³ and R⁴ independently of one another arehydrogen, C₁-C₈-alkyl, C₁-C₈-haloalkyl, C₁-C₈-alkylcarbonyl orC₁-C₈-alkoxycarbonyl; R⁵ and R⁶ independently of one another areC₁-C₈-alkyl, C₁-C₈-haloalkyl, C₁-C₄-alkoxy or C₃-C_(s)-cycloalkyl; R⁷ ishydrogen, C₁-C₈-alkyl, C₁-C₈-haloalkyl, C₁-C₄-alkoxy orC₁-C₈-haloalkoxy; and aliphatic and cyclic groups R¹ to R⁶ may carryone, two, three or up to the maximum possible number of identical ordifferent groups R^(a) which independently of one another are selectedfrom: R^(a) is halogen, hydroxyl, oxo, nitro, cyano, carboxyl,C₁-C₄-alkyl, C₂-C₄-alkenyl, C₂-C₄-alkynyl, C₁-C₄-haloalkyl,C₁-C₄-alkoxy, C₁-C₄-haloalkoxy, C₃-C₆-cycloalkyl, C₃-C₈-cycloalkenyl,C₂-C₆-alkenyloxy, C₃-C₆-alkynyloxy, C₁-C₄-alkoxyimino, C₂-C₈-alkylidene,C₃-C₈-cycloalkylidene, C₁-C₁₂-alkylamino, C₁-C₄-alkoxycarbonyl,C₁-C₄-alkylcarbonyloxy, NR^(A)R^(B), C₂-C₈-alkylene, C₂-C₈-oxyalkylene,C₁-C₈-oxyalkyleneoxy, phenyl, naphthyl or a three- to ten-memberedsaturated, partially unsaturated or aromatic mono- or bicyclicheterocyclyl which, in addition to carbon atoms, contains one to fourheteroatoms from the group consisting of O, N and S as ring members;where the cyclic groups R^(a) may be attached directly or via a nitrogenor oxygen atom; where in the divalent groups R^(a) the carbon chains maybe interrupted by one to four heteroatoms from the group consisting ofO, N and S and the free valencies may be attached to the same atom or totwo adjacent atoms; where the aliphatic or cyclic groups R^(a) for theirpart may be partially or fully halogenated and/or may carry one, two,three or up to the maximum possible number of identical or differentgroups R^(b): R^(b) is halogen, hydroxyl, nitro, cyano, carboxyl,C₁-C₄-alkyl, C₂-C₄-alkenyl, C₂-C₈-alkynyl, C₁-C₄-haloalkyl,C₁-C₄-alkoxy, C₁-C₄-haloalkoxy, C₁-C₈-alkylcarbonylamino, phenyl,phenoxy, pyridyl, pyridyloxy or C₃-C₈-cycloalkylcarbonylamino; where thecyclic groups R^(b) for their part may be partially or fully halogenatedand/or may carry one, two, three or up to the maximum possible number ofidentical or different groups R^(c): R^(c) is halogen, hydroxyl, nitro,cyano, carboxyl, C₁-C₄-alkyl, C₂-C₄-alkenyl, C₂-C₄-alkynyl,C₁-C₄-haloalkyl, C₁-C₄-alkoxy or C₁-C_(t)-haloalkoxy; R^(A) and R^(B)independently of one another are hydrogen, C₁-C₈-alkyl, C₁-C₈-halo-alkylor C₁-C₈-alkylcarbonyl; L¹, L², L³ and L⁴ independently of one anotherare hydrogen, halogen, C₁-C₄-alkyl, C₁-C₄-haloalkyl, C₁-C₄-alkoxy orC₁-C₄-haloalkoxy; where R¹ and R² or R¹ and R³ or R² and R³ or R³ and R⁴and/or R⁵ and R⁶ in each case together with the atoms linking them mayform a five- to ten-membered saturated or partially unsaturated cyclicgroup which, in addition to the carbon atoms, may contain one to threeheteroatoms from the group consisting of N, O and S and/or may bepartially or fully halogenated and/or may carry one, two, three or up tothe maximum possible number of identical or different groups R^(a); X isoxygen or sulfur; or an agriculturally acceptable salt of the compoundsof the formula I.
 2. The compound of the formula I according to claim 1in which R¹ is C₁-C₈-alkyl, C₂-C₈-alkenyl, C₂-C₈-alkynyl,C₃-C₈-cycloalkyl, phenyl or a five- or six-membered saturated, partiallyunsaturated or aromatic heterocyclyl which, in addition to carbon atoms,contains one to three heteroatoms from the group consisting of O, N andS as ring members; and R² is amino, C₁-C₈-alkyl, C₂-C₈-alkenyl,C₂-C₈-alkynyl, C₁-C₈-alkylcarbonyl, C₁-C₈-alkoxycarbonyl,C₃-C₈-cycloalkyl, phenyl or a five- or six-membered saturated, partiallyunsaturated or aromatic heterocyclyl which, in addition to carbon atoms,contains one to three heteroatoms from the group consisting of O, N andS as ring members; where aliphatic and cyclic groups R¹ to R⁶ may carryone, two, three or up to the maximum possible number of identical ordifferent groups R^(a) which independently of one another are selectedfrom: R^(a) is halogen, C₁-C₄-alkyl, C₁-C₄-haloalkyl, oxo,C₁-C₄-alkoxyimino, C₁-C₁₂-alkylamino, C₁-C₄-alkoxycarbonyl,C₁-C₄-alkylcarbonyloxy, C₁-C₄-alkoxy, C₁-C₄-haloalkoxy, NR^(A)R^(B),phenyl or a five- or six-membered saturated, partially unsaturated oraromatic heterocyclyl which, in addition to carbon atoms, contains oneto three heteroatoms from the group consisting of O, N and S as ringmembers, where the cyclic groups R^(a) may be attached directly or via anitrogen or oxygen atom; where the aliphatic and cyclic groups R^(a) fortheir part may be partially or fully halogenated and/or may carry one,two, three or up to the maximum possible number of identical ordifferent groups R^(b); where R¹ and R² or R¹ and R³ or R² and R³ and/orR⁵ and R⁶ also in each case together with the atoms linking them mayform cyclic groups according to claim 1; and X is oxygen; where R¹ maynot be substituted by heterocyclic groups R^(a).
 3. The compound of theformula I according to claim 1 in which R¹ and R²; R¹ and R³, R² and R³and also R³ and R⁴ are in each case not able to form a cyclic group. 4.The compound of the formula I according to claim 3 where R³ isoptionally R^(a)-substituted C₁-C₈-alkyl or C₁-C₈-haloalkyl.
 5. Thecompound of the formula I according to claim 4 where the α carbon atomin R¹ does not carry a cyclic group.
 6. The compound of the formula Iaccording to claim 5 in which R² is substituted C₁-C₈-alkyl whichcarries a phenyl or heterocyclyl group attached via oxygen andoptionally a further one, two, three or four identical of differentgroups R^(a).
 7. The compound of the formula I according to claim 1 inwhich R² is substituted C₁-C₈-alkyl which carries a phenyl orheterocyclyl group and optionally a further one, two, three or fouridentical of different groups R^(a).
 8. The compound of the formula Iaccording to claim 1 in which R² is optionally R^(a)-substituted phenylor heterocyclyl.
 9. A process for preparing a compound of the formula Iaccording to claim 1 wherein a compound of the formula II

in which Y is a nucleophilically replaceable group, is condensed with acompound of the formula III

and the resulting compound of the formula IV

is converted under basic conditions with a compound of the formula V

into a compound of the formula I.
 10. A process for preparing a compoundof the formula I according to claim 1 in which R² is CH₂—R^(2a), whereR^(2a) is a group R^(a) attached via oxygen, wherein a compound of theformula II.1

in which Y are each independently of one another nucleophilicallyreplaceable groups, is condensed with a compound of the formula III,

the resulting compound of the formula IV.1

is reacted under basic conditions with a compound of the formula V

and the resulting compound of the formula VI

in which Y has the meaning given above is reacted with a compound of theformula VIIH—R^(2a)  VII, where R^(2a) has the meaning given above under basicconditions to give a compound of the formula I.1,


11. The compound of the formula VI according to claim 10 in which Y isC₁-C₈-alkylsulfonyloxy or arylsulfonyloxy.
 12. A composition comprisinga solvent or solid carrier and a compound of the formula I according toclaim
 1. 13. The composition according to claim 12, comprising a furtheractive compound.
 14. A seed, comprising a compound of the formula Iaccording to claim 1 in an amount of from 1 to 1000 g per 100 kg.
 15. Amethod for controlling phytopathogenic harmful fungi wherein the fungior the materials, plants, the soil or seed to be protected from fungalattack are treated with an effective amount of a compound of the formulaI according to claim
 1. 16. The method of claim 15, wherein R¹ and R²;R¹ and R³, R² and R³ and also R³ and R⁴ are in each case not able toform a cyclic group.
 17. The method of claim 16, wherein R³ isoptionally R^(a)-substituted C₁-C₈-alkyl or C₁-C₈-haloalkyl.
 18. Themethod of claim 17, wherein the α carbon atom in R¹ does not carry acyclic group.
 19. The method of claim 18, wherein R² is substitutedC₁-C₈-alkyl which carries a phenyl or heterocyclyl group attached viaoxygen and optionally a further one, two, three or four identical ofdifferent groups R^(a).
 20. The method of claim 15, wherein R² issubstituted C₁-C₈-alkyl which carries a phenyl or heterocyclyl group andoptionally a further one, two, three or four identical of differentgroups R^(a).